'^^^B ^ Otljp i. 1. HtU iCtbrarg 5JortI| (Earolina g>tatp IninerHity SPECIAL COLLECTIONS TP897 / THIS BOOK MUST NOT BE TAKEN FROM THE LIBRARY BUILDING. JZLAy'^^-^^ 20M- 10/72 -D THE A R O F DYING WOOL, AND K, COTTON, 'f>£-.-. TRANSLATID FROM THX TRENCH 0» Q^ \< ^'X» M. HELLOT, M. MACQUER, and M. LE PILEUR D'APLIGNY. LONDON: Printed for R. Baldwin, Pater-noster-Row, M DCC LXXXIX, TO THE SOCIETY O F ARTS, MANUFACTURES, 6? COMMERCE, THIS VOLUME IS HUMBLY INSCRIBED, BY THEIR FAITHFUL SERVANT, THE TRANSLATOR, 87817 PREFACE. THE great importance of the Art of Dying Wool, Silk, Cotton and Thread, in a country whofe prin- cipal exports arc indnufa(flured from thefe materials is felf-evident. Whether our good neighbours the French be our natural enemies or not, certainly they are our moft powerful rivals in commerce and manufac- tures ; in this fenfe they are our enemies ; let us not therefore, from pride or ill- humour, fpurn their inftrudlions. ^as e/i, et ab hojle doceri. The Art of Dying is a branch, and by no means the leaft confequential branch of chemiftry; confequential in its influence on the fale of all ftufFs ufed for furniture or apparel : few people can eftimate the in- trinfic value of manufadured woolens, filks or cottons, but men, women and children can judge of their colours, on the beauty of which, therefore, the firft fale of a new manufadure mud depend ; and the con- tinuance of that fale will alfo depend more A3 on vi PREFACE. on the permanency of the colours, than on the flrength of the ftufF; a faded gown is given to Mrs. Betty, long before it is worn out. The government in France, aware of the importance of colours in their various ma- nufad:ures, hath confidcrcd the Art of Dying as an objedt deferving peculiar atten- tion. Thofe who pradice this art in that kingdom are fubjecft to certain regulations, and frequent infpedion. The Dyers of the true^ and of the falfe dye, are diflindt occupations, and fome of their beil chemifts have been employed in experiments partly defigned to diftinguifh precifely the true from the falfe dye, but with the general intention of improving the art. A circumftantial detail of thefe experi- ments, with their various refults, are in this volume prefented to the Englifli Dyers, in what I believe to be a faithful tranflation. I am not a Dyer by profeflion ; probably therefore, I have not always expre/Ted myfelf in the language of an Englifh Dye- houfe ; but I flatter myfelf neverthelefs that the terms I have ufed, though not ilridly technical, are never un-intelligible, 6 Men PREFACE. vii Men of fcience, who are young in the pradice of any art, are naturally deluded, by a propenfity to fpeculation, into theories, which a little more experience would have ftifled in the birth. Of thefe theories the intelligent reader will find fome examples in this volume; but, like many other theories, they are perfectly harmlefs ; be- iides, it is more than probable that the moft extravagant fpeculations of a fenfible man may prove a ftep towards a more rational future inveftigation of the fubje(5l. But, be the theories of thefe philofophical Dyers what they may, their experiments can- not fail to be ufeful to a rational artift. Several years have illapfed fince thefe three books on the Art of Dying were pub- liftied in France ; and yet thofe on t&e Art of Dymg Silk and of Cottony are not at all known by our Englifli Dyers : that on tbt Art of Dying Wool by Ij^ellot, was partly and poorly tranllated by a country Dyer, who knew but little French and no Che- mifcry. The fecond part of this volume on the Art of Dying Silky is the work of the celebrated authour of the Chemical Dic- tionary^ and muft therefore be a very A 4 valuable Vlll PREFACE. valuable performance; and highly accep- table to every artift in that branch of Dying. Part the 'Third, is alfo the work of a very ingenious Chemift. His theory is much more rational than that of M. Hellot i and feveral of his hints may, by a fenfible artift, be improved into fadts of importance. M. Adanfon, of the Academy of Sciences at Paris, and of the Royal Society of London, gives the following tefti- mony of this Treatife on the Art of Dying Cotton. " I have read, by order of my Lord the Keeper of the Great Seal, a manufcript ntituled, 7he Art of Dying Cotton, &c* by M. P. De'Apligny : this work feems replete with new objefts and enquiries likely to lead to new difcoveries in the important Art of Dying; therefore it merits the attention of thofe who wi(h to aflift in bringing this art to perfedticn." Having, whilft employed in this tranlla- tion, frequently laid down my pen to con- fider the operation of the Dyer as a chemical procefs, I am convinced, that the prefent roz///W of pradiice might in many inftances be much abridged and improved by a phi- lofophical Dyer. An illiterate pradical Dyer PREFACE. IX Dyer may accidentally flumble on an ufeful improvement in his art : a Chemift unac- quainted with the pradical part of Dying, may alfo, whilft in purfuit of other matters difcover refults, from new combinations, that are applicable to the art in queflionj but the important Art of Dying will never approach the perfedlion of which it is capable, until our Dyers by profefiion can be perfuaded to make themfelves acquainted with the chemical theory of the art they profefs. Thefe three books which I have tranf- lated for the ufe of Englifh Dyers, are an excellent introdudion to the ftudy which I recommend ; though written fome time ago, they exhibit a faithful difplay of the prefent pradtice in France, no improvement having been made in that country lince they were written. I recommend this publication to the perufal of Englifh Dyers with great con- fidence, becaufelam totally uninterefted in the fale of the book, and am the reader's Faithful Servant, THE TRANSLATOR, CONTENTS. PART I. ^e Art of Dying Wool and fVooIen Clothe Siufs, Tarn, Wcrfted^ &c, INTRODUCTION - . „ Page i CHAPTER I. Of the Veflels and Utenfils ufed in Dying 4 CHAPTER II. Of the fixed and fugitive, commonly called Great and Little Dye - - _ J2 CHAPTER III. Of Colours In Grain - « 18 DYING WOOL. CHAPTER IV. Of Blue - - - 21 CHAPTER V. Of the Paftel Vat . _ . 2$ Diredions for the proper management of the Vat 29 Indications when the vat has fufFered by too much or too little lime ; the two extremes which ought carefully to be avoided _ _ _ /^j^. The preparations of Indigo for the Paftel Vat 36 CHAPTER VI. Of the Woad Vat - - 49 CHAPTER CONTENTS. CHAPTER. VII. Of the Indigo Vat - - Page 53 CHAPTER VIII. Of the cold Indigo Vat with Urine - 60 A Hot Indigo Vat with Urine - - 61 To re-heat a Urine Vat - - 65 CHAPTER IX. A cold Indigo Vat without Urine - ' 67 CHAPTER X. Of the method of Dying Blue - - 72 CHAPTER XI. Of Red - - - - 105 CHAPTER XII. Of Scarlet in Grain, or Venetian Scarlet 106 CHAPTER XIII. Of Fire Scarlet - - - 123 CHAPTER XIV. Of Crimfon - - - 146 CHAPTER XV. Of Gum-lac Scarlet - _ . 1^2 CHAPTER XVI. Of the Coccus Polonicus, a colouring Infeil 156 CHAPTER XVII. Of Madder Red - - - 158 CHAPTER XVIII. Of Yellow - - - - lyj, CHAPTER XIX. Of Brown or Fawn colour - - 175 CHAPTER XX. Of Black - - - . ,81 CHAPTER XXI. Of the colours obtained from a mixture of Blue and Red 192 CHAPTER .CONTENTS. CHAPTER XXII. Of the mixture of Blue and Yellow - Page 193 CHAPTER XXIII. Of the mixture of Blue and Fawn colour 198 CHAPTER XXIV. Of the mixture of Blue and Black - 199 CHAPTER XXV. 0[ the mixture of Red and Yellow - 200 CHAPTER XXVI. Of the mixture of Red and Fawn - 203 CHAPTER XXVII. Of the mixture of Red and Black - - 204 CHAPTER XXVIir. Of the mixture of Yellow and Fawn colours 205 CHAPTER XXIX. Of the mixture of Yellow and Black - 206 CHAPTER XXX. Of the mixture of Fawn colour and Black ibid. CHAPTER XXXI. Pf the principal mixtures of the primitive Colours by three and three - _ - 210 CHAPTER XXXir. The method of blending Wool of different colours, for mixed Cloth or Stuffs - - 214 CHAPTER XXXIII. The method of preparing Felts for trial 216 CHAPTER XXXrV. The Method of Dying Woolens falfe Colours 219 CHAPTER XXXV. Of Fbck or Goats Hair - - 220 CHAPTER XXXVI. Of ArchiLj and the method of ufing it 230 CHAPTER CONTENTS. CHAPTER XXXVn. Of Logwood _ . - Page 240 CHAPTER XXXVIII. OfBrafilWood - - - 045 CHAPTER XXXIX. OfFuftic _ - . - 250 C H A P T E R XL. OfRocou _ - - . 251 CHAPTER XLI. Of French Berries _ . - 253 CHAPTER XLn. Of Turmeric _ - - /^/V. JnJiruSfions. The proof Liquor for Wool and Woolen fluffs 254 PART IL The Art of Dying Silk. Ungumming and boiling for white • 267 For boiling of filks intended to be Dyed 269 Ohfervations on ungumming and boiling - 271 Of White - - - 273 Of Whitening _ - _ 275 Sulphuring _ _ _ _ 276 Ohfervations on Whitening and fulphuring 277 Of Aluming _ _ _ 280 Remarks on aluming - - - 283 Of Blue - - - - 284 Remarks on the Blue of Indigo - - 288 Of Yellow - - - - 295 Remarks on Yellow - - 2q8 Aurora, Orange, Mordore, Gold colour and Chamois 299 Red and Crimibn - - _ 004 Remarks on Crimfon - - 307 Of Falfe Crimfon or the Red of Brafil - 312 Remarks on the red, or Crimfon of Brafil wood 314 Of Scaiict, Orange, Red, and Cherry colour 317 Preparatioft CONTENTS. Preparation of the Carthamus or Baftard fafFron Page 318 Remarks on the Dye of Carthamus or Baftard fafFron 324 Of the Falfe Poppy or Fire colour produced with Brafil Wood - - - - 326 Falfe Rofe colour - . - - 328 Of Green . - _ . 329 Remaks - - - . 333 Of Olives - - - ibid. Remarks _ _ - - 334 Of Violet - - - 335 Of fine Violet, or Violet in grain - - ibid. Of Falfe or common Violets or Lilac - 338 Of the Violet of Logwood - - 341 Violet of Logwood and Verdigris - - 343 Violets of Brafil and Logwood - 344 Remarks - - - ibid. Violets from Brafil wood and Archil - 345 Of Purple, Gilly-flower, and of fine Cochineal or Purple 346 Of Falfe Purple - - . - 347 Of Marones, Cinnamons and white Lees - 348 Remarks _ _ _ 34^ Of Nut Greys, Thorn Greys, Black and Iron Greys, and others of the fame fpecies - - 351 Of Black - - _ 356 Softening of Black - - 364 Black in the raw - - - ibid. Remarks on Black - - 368 Particular Process Communicated hy M. Hellot 369 Genoa Crimfon, a procefs proved in May, 1743 372 Violet Crimfon of Italy - 377 Half Violet - - _ ibid. Genoa Black for Velvets - ibid. PART lU. The Art of Dying Cotton and Linen Thread together with the method of Jiamping Silks Cottons, is'c. Of Dying in general - - 385 Enquiry concerning Wool, Silk, Cotton and Flax 387 Of Wool - - 388 Of Silk - - - 389 Of Cotton . _ . 290 Of Flax - - « 391 Conclufion CONTENTS. ConcliiHon from the examination of fubftances commonly dved - - - 394 Of Bleaching _ _ _ ^96 Preparation for fluff to be dyed - 4.02 Aflringents _ - _ 405 Theory of dying fluffs prepared with alum 408 Of colouring fubdances - - 410 Of Cochineal and cohouring infeiSls - 417 Of Madder _ _ - 423 Of Vegetables furnifhing a yellow Dye - 430 Of the colouring Drugs ufed in Dying without aflringents Of Indigo _ _ _ 439 Of fubftances ufed in dying Fawn and root colour 442 Of Carthamus, Rocou &c. - 443 Of Black - - 445 Of Dying of Cotton TJjread. OrCleanfing - - 449 Of the Colours employed for the Dying of Cotton Thread 450 Of Blue - - - ibid. Of Red - - 455 Adrianople Red - 465 Of Yellow - - 471 Of Green - - 473 Of Violet - - 47s Of Red Cinnamon - - 478 Of Black - - ibid. Black for Linen and Cotton Thread by a Combination of Colours _ _ _ 4g^ Of more durable Grays - - 484 Of A'lufk colour - - - 485 Olive and Duck Greens - - ibid. Of Browns, Marones, CcfFee colours, &c. 486 Of fiik fluffs dyed of feveral colours - ibid. The manner of flamping filks,&c. in Europe 494 Of a Linen with a Blue Ground and White Pattern 497 Of Saxon Blue , - - 502 THE TH E ART OF DYING WOOL. INTRODUCTION. EFORE we proceed to the Art of Dying Wool, it is necellliry to give fome idea of the primitive colours, or rather of thofe which are fo called by the Dyers ; for they have no affinity with thofe properly fo denominated by Sir Ifaac Newton. The Dyers call them primitive, becaufe, from the nature of the in- gredients by which they are produced, they become the bafis of every other colour. This divifion of colours is not peculiar to the Art of Dying Wool ; it is common to the Dyers of Silk, Thread, &c. The primitive colours are five, viz. blue, red, yello'-ju, fawn or raot-colour, and hlack\ each of which furnifhes a great number of Ihades, and from the combination of thefe fhades are pro- duced all the colours in nature. Confiderabic changes in thefe feveral colours are produced by ingredients which are themfelves colourlefs, juch as acid, alkaline and neutral falts, lime, urine, arfenic, alum, &c. Wool and Woolen B % Stuffs, D. H. H\Ul- UBRARY North Carokina State College j^ THE ART OF Stuffs are generally prepared for dying by means of fome of thefe. Hence it is evident that an infinite variety of effefls muft neceifarily refult from a mixture of thefe feveral chemical fub- fiances, and from the various methods of ufing them J hence it is alfo obvious, that the Art of Dying requires fome knowledge, fcrupulous ac- curacy, and great attention. C H A P. I. Of the Vejfels and Utenftls lijed. in Dying, YOUR Dye-houfe muft be fpacious and lightfome, and as near as pofTible to a running ftream, water being abfolutely necef- fary for preparing your Woolens, and for rincing them after they are dyed. Your floor ihould be a mixture of lime and cement, and in- clining, fo that the water and old vats, which are thrown over it in great abundance, may run off cafily. The moft commodious method, is, to fix two or more Vats, according to your quantity of work, about eight or ten feet from your coppers. Thefe Woad Vats are of the greateft impor- tance, as the fetting and heating, that is to fay, preparing and properly regulating them, for the blue colour, is the greateft difficulty in the Art of Dying. Thefe vefTels are from ten to twelve feet in dia- meter, and fix or feven feet high j they are made of ftave^ DYING WOOL. 5 ftaves fix Inches broad, and two inches thick; are bound with iron hoopsabouttwoor threefeetafun- der,andarefunkintheground,fortheconveniency of managing their contents ; which is done by means of hooks faftened to the end of a ftafF, of a proper length according to the diameter o/your Vat. The bottom of thefe veflels is made with lime and cement; but this however is not efTen- tial, and is pradifed only becaufe it would be difficult to make a wooden bottom llrong enouo-h to fiipport the contents-of fo large a veflel. "" When you mean to dye Wool or Stuff", pre- pared according to my diredions in Chap. IV you fufpend within the veffel an iron hoop, with a net faftened to it, the melhes about an inch fquare. This is called a crofs, and is ufed to prevent the Wool or Stuff" from falling and mixing with the grounds at the bottom. You ti-iay fufpend this machine to what height you pleale, by means of threeor four cords faftened to the edge of the Vat. There is another utenfil called a Rake, which IS a ftrong femicircular piece of wood, with a long wooden handle. This Rake is ufed for ftirnng the Vat; that is to fay, for mixing the grounds with the liquor, and for raifing the fedimcnt from the bottom of the Vat. It is alfa " "fed for daffiing or plunging the Vat, that is, to puOi the furface quick and forcibly towards the bottom, which by introducing the Air, forms little bubbles, or a kind of froth, by which you may judge of the ftateof your Vat, as I fhall ex- plain hereafter. B 3 You 6 THEARTOF You mufl alfo have a T^ranchoir which is a kind of wooden fhovel, ufcd for meafuring the lime, into the Vatj but I fhall dcfcribe this utenfil in my direftions for fetting the Vat, and will, as I proceed, give an explanation of fuch tech- nical terms, as I fhall be obliged to ufe. The fize of thefe Vats, as it depends upon choice or ncceflity, is undetermined. Vats con- taining CO, or even 15 Gallons, are frequently prepared with fuccefs; but thefe fmall Veflels fhould be furrounded with dung or brick work, or fome other means fhould be ufed to prevent them from cooling too fall, elfc they are liable to fail. There is alfo a different kind of Vat prepared for blue, called an ladigo Vat, becaufe it is coloured with Indigo only. But the Dyers, who life the Woad Vats, are not, in general, provided with this. Neverthelefs as it requires a different VefTel, a defcription of it may be ufcful. This VefTel is generally five ittt high, and at the top, two feet in diameter. It grows narrower downwards, and meafures only 8 or 10 inches at the bottom. It is funk a foot, or a foot and half, for the convenicncy of working. There mufl be a cylindrical wall built round it, as high as the Vat, upon which the edge of the Vat is fupported. This wall being perpen- dicular, and quite flraight at the infide, con- fequently cylindrical, and the VefTel which it furrounds of a conic form, it is evident there mufl be fome fpace at the bottom. In this fpace the coal and cinders, requifite for keep- ing the Vat properly heated, are depofired, and for DYING WOOL. 7 for this purpofe there is a little door or opening to put in the coal which is pufhed round the Vat, to preferve, as much as poflible, an equal degree of heat. The Indigo immediately falls to the bottom of this copper Vatj but by this method of fetting the Vat, the fire is above the Indigo, confequently it can neither burn nor lofe -any of its quality. The fame precaution fhould be obferved with regard to the Dutch P^^/ Vats, as Ihall be mentioned hereafter. You muft be careful, not to extinguifh your fire too fuddenly, and fhould therefore fix an iron or ftone funnel, from the bottom, where the coal is depofited, to the top of the Vat. This funnel, for the greater conveniency, fhould be carried along the wall, againft which the Vat is commonly fupported. For flirring the liquor of this Vat, you muft have a Rake, but of alrnaller fize than that ufed with the pafiel Vat. You may alfo ufe a Crofs; but this however is not neceffary, becaufe thefe fmall Vats are feldom ufed but for hanks of filk, or worfled, and thefe are not left intirely loofe, left they fhould burn; confequently, as they are not long enough to reach to the bottom, they cannot touch the ground or fediment. I have already obferved, that it is pofTible to fet a fmall /^/^/ Vat, but you may, with much lefs difHculty, fet an Indigo Vat as fmall as you pleafe. I have myfelf prepared one in a cryftal cucurbite containing one gallon, and another of one pint only, in a fmaller cucurbite. But when I defcribe the Indigo Vat, I will mention the neceflary precautions to be taken for its fuccefs. B 4 Befides 8 TH E A RT OF Befides thefe Vats, it is neceflary to have feverai coppers of different fizes, according to what quantity of work you mean to do at one tinne. They may be either copper or brafs; but the copper is better, being lefs apt to fpot where it touches, or when the wool or ftuff is fuffered to . remain in it for any time. It were alfo adrifable to have a pewter vefTel for fcarlet, becaufe in pewter, the worded or fluffs never fpot, whereas the contrary is much to be dreaded from a copper cauldron. The Dyers who make ufe of the latter for fcarlet, take care to have a net of cords or an open wic\«r-bafket at- the infide, to prevent the fluffs from touching the copper. The diameter of the net or bafket, being much fmaller than the diameter of the caul- dron, there confequently remains a confiderabie diflance between them. But notwithftanding all thefe precautions, many are of opinion, that fcar- let dyed in copper, is neither fo bright, nor fo lively as when dyed in a pewter veffel. But this fhall be the fubjedl of my chapter upon Scar- let. Thefe feverai cauldrons fhould be fixed con- tigiousto each other, and, as nearly as poffible, of the fame height, fo that the deepefl veffel fhould be funk the lowed. They fhould be furrounded by a wall made of brick and clay, the outfide of which fhould have a coat of plaifler j and, to pre- ferve the whole, the wall fhould be coped with wheel-felloes, held together by iron cramps! The flat edge of the cauldron fhould be nailed to the felloes with brafs nails, becaufe iron nails w*ould fpot the fluffs. Thefe felloes ferve alfo to prevent DYING WOOL. g prevent the water, when it boils over, from car- rying dirt into the copper. For the fame reafon a plank fhould be fixt between the coppers, that, when two are employed at the fame time^ the liquor of the one may not fall into the other. But this caution will be needlefs, if there be room enough to place thefc coppers at a tolerable dif- tance from each other. Thefe cauldrons are heated underneath; and for the greater conveniency, the hearths of all the <;op^ers,. as well as the flues are inclofed under the fame chi'mpey. Thefeflues are openings, by which the-lfrf^aK-and partof the flame is carried off; the fize of thefe openings, that of the hearth, and the depth of the furnace (w'z .the diftance of the bottom of the copper from the hearth where the fire is made) are determined by the fize of the cop- pers j but the mantle-piece of the chimney fliould always cover every opening, and fhould project to the edge of the copper, in order to receive all the fmoak, fo that none may remain in the dye-houfe. It is fcarce poflible to give any determined plan with regard to the fixing of thefe coppers in a dye-houfe, as that depends, in a great meafure, oa your quantity of work. There fliould be holes made in the mantle-piece over each of the coppers, capable of admitting poles about as thick as youf arm, and about five feet and half above the coppers. Thefe poles are ufed for draining the hanks of worflied or filk, and forfmall pieces of fl:uff, fo that the liquor may fall into the copper. For this purpofe, you pafs fmall rods, through all the hanks, which rods reft upon the poles, ^ When 10 THE ART OF When you dye a whole piece of fluff, or feveral pieces at a time, you make ufe of aWince. This Wince is a wooden axis with a handle, upon which axis are faftened, four fiat pieces of wood, at equal diftances. You turn this machine with the hand, refting the two extremes of its axis on two iron forks, fixed into holes in the wooden felloes by which the edge of the copper is fupported. You roll one end of the fluff round this Wince or Reel, and, by- turning it quick, wind the whole onto itj youthen turn it the contrary way, rolling on the other end ofthcfluff firfl,andby continuing in this manner, you dye the whole as even aspoffible. If your piece of fluff be rather long, or if you have many pieces to die of the fame colour, you few the ends together; the Reel is then put through the middle, and turned in the manner above mentioned. If you want to die Wool before it be fpun, you mufl have a kind of Wooden Ladder, or Barrow, very broad, and as long as the diameter of the copper. The crofs laths of this utenfil Ihould be very near each other. On this Barrow, placed upon the copper, you put your Wool, in order ta drain, or to change the liquor. It were needlefs to mention the neceffity of keeping this Barrow and Reel very clean. The fame attention fhould be obferved with regard to the coppers, and to all the different utenfils, ufed in the Art of Dying. It is evident, that without this attention your work will be conllantly foiled, and the brightnefs of the colour tarnifhed. Hence it is impoffible to fay too much on the necefTity of cleanlinefs, in the feveral operations of this art. I fhall DYING WOOL. XI I fhall not defcribe the other furniture of the Dye-houfe comnnonly ufed: they are univerfally known; fuch as Cauldrons, Skellets,Buckets,Cafks, Barrels, Shovels, Wooden-Covers for the Coppers, Tubs, Foot-Boards, Mortars, VefTels of Stone or Glafs, for metallic folutions. Pokers, befidesmany other .utenfils, which need no defcription. It is neceOary to have a copper -ladle for emptying the liquor out of the cauldron after it has yielded all its colour. This ladle has a wooden handle, and contains about two gallons. Wooden bowls are alfo ufed for emptying the copper, which is then cleaned with a rufh befom and fand, and afterwards wiped and dryed with a fpunge. In large Dye-houfes, they folder to the bottom of the largeft cauldrons, a brafs pipe with a cock at the out-fide, in order to empty the coppen This cock difcharges itfelf into a chan- nel which paffing under the floor, runs off into the neareft drain. Thefe, I think, are all the inflruftlons that can be given, concerning the tools and utenfils com- monly ufed in dying. If there be any omitted, I fhall recoiled them as occafion may offer to dired their ufe. C H A P. la THE ART OF CHAP. n. ^ Of theYiymn and Fugitive commonly called Gkilkt and Little Dye. WOOL may be dyed either true or falfe. The firft is done by ufing fuch drugs or ingredients, as to produce a colour fo permanent, that it is neither affected by the air, nor liable to fpotj the falfe colour, on the contrary, foon fades, efpecially if expofed to the fun, and almolt any liquid will fpot it in fuch a manner that it is fcarce ever poffible to reilore it to its original brightnefs. It may perhaps fecm aftonifhing that having it in our power to dye all colours true, we Ihould be permitted to make ufe of an inferior method j but it is difficult I may fay, almofl: impofTiblc, to abolilh the cuftom, for the tliree following reafons: Firft, becaufethis method is in general much lefs difficult: Secondly, the falfe colours are generally the moil bright and lively : The third and doubt- lefs tlie moft prevalent reafon of all is, that the Fugitive Colour is dyed at a much cheaper rate. Were there no other motive, the Dyers would en- deavour to avail themfelves of the cheapeft me- thod; government, for this reafon, hath prefcribed certain regulations. Thefe regulations fpecify what kind of Woolens and Stuffs fhall be dyed true; and this it deter- mined by the deftination of the vvorfted, and the price of the fluffs. Worfled for working canvas, tapeftry, and for all ftuffs exceeding forty DYI-NG WOOL. 13 ^orty Sols an ell, muft be dyed true; but coarfe worded, defignedfor thetapeftry called 5(?;-^^/;z^" and ^oint de Hongrie^ may be dyed falfe. Such is the purport of M. Colbert's regulations, and thofe of M. Orry, comptroller-general of the finances in 1-733, are grounded upon the fame principles. Thefe lail: have removed a number of difficulties which prevented the execution of the former, with fuch additions as were neceffary for prevent- ing, or difcovering all poffible evafions. For this purpofe, the Dyers of the Great Dye compofe a feparate body, and are not permitted to employ, or even to keep fuch ingredients as are appropriated to the inferior Dyers. As it was impoffible, either from the information of the different Dyers, or from the fludy of the Regulations^ to difcover any pofitive diflindion between the true and falfe, or great and lejler dye, it was nccefTary in order to afcertain this matter, to take the following method ; which, though the longeft and mofl difficult, is the moft certain, ormore properly fpeaking, the only method, which could be relied on. The late M.du Fay of the Royal Academy of Sciences, was chofen by the mini- fter to make thefe necelTary experiments, con- cerning this art. For this purpofe, he dyed, at his own houfe. Woolens of all colours, with every ingredient ufed in dying, whether true or falfe. He had even brought from different provinces, fome which were not ufed in Paris. In fhort he €ollefted every drug which he thought mighc poiTibly be ufed for dying, and tryed them without any regard to the prejudices of the Dyers^ con- |:erning their good or bad qnalities, He 14 THEARTOF He began his experiments on worfleds; but he found afterwards that bits of white cloth were more convenient. In order to difcover which of the colours were permanent, and which not, he had patterns of all the colours, which had been dyed under his own infpedion, expofed to the fun and air, during twelve days. This tryal was evidently decifive, the true colours being not at all, or but very little, the worfe; whereas the falfe were almoft intirely faded j fo that, after twelve days expofition to the fummer's fun and night air, there remained very little doubt concerning the clafs in which the different colours fhould be ranged. Neverthelefs, as feveral of thefe colours had not been expofed to the fun precifely at the fame time, nor in the fame feafon, there ftill remained a doubt; for fome of them, having had more of the fun than others, were more faded, in the fame number of days. This inconvenience, however, he remedied in fuch a manner that there remained no longer, either doubt or difficulty, with regard to the fufficiency of his tryals. He pitched upon one of the worft colours, that is to fay, the colour upon which the fun had had the moft fenfible effedl in the fpace of twelve days. This colour ferved him as a ftandard through the whole courfe of his experiments; for whenever he expofed his patterns, he alfo expofed a pattern of this piece of fluff at the fame time, no longer attending to the number of days, but to the colour of his ftandard, which he left out, 'till it became as much faded, as thofe which had been expofed for twelve fummer I days. DYING WOOL. 15 days. As he conftantly made a memorandum of the day, when he expofed his patterns, he found that, in winter, four or five days were fufficient to bring them to his ftandard. By purfuing this method, there remained no longer any doubt con- cerning the accuracy of his experiments. But in thefe experiments, he had flill another objed: in view, viz. to find a proof liquor for every colour : that is, a liquor in which the fluffs are boiled, in order to difcover whether the dye be true or falfe. He boiled his patterns, in a folution of alum, of tartar, of foap, in vinegar, in lemon juice, &c. and by their effed on the colour, he was enabled to judge of its quality. The feveral liquors ufed till the year 1733, were not dccifive. They fometimes difcharged a good colour, without doing much damage to a bad one. He was therefore obliged to ellablifh feveral, each of them ferving for a certain number of colours, as will be feen at the conclufion of this treatife : it may be neceflary however to add a few words, to fhew the method he purfued in the difcovery of thefe proof liquors. Having perceived the effe6t of the air upon each colour, he tryed different kinds of folutious on the fame pattern, and fixed upon that which had made a change in the colour equal to what the air had produced. By afcertaining the weight of the matter diffolved, the quantity of water, and the time of tryal, he was certain of producing the fame efFe till I treat of the particular colours, in the compofition of which they may be introduced. Thofe who would choofe to fee a catalogue of thefe ingredients, collefted under one view, and ranged in their proper clafles, according to their good or bad qualities, need only confult the Regulaticns. I now proceed to examine the five primitive colours above-mentioned, and will give the different methods of preparing them, inafolid and permanent manner, conformable to the Regulations for Dyers in Grain, CHAP D Y I N G W O O L. Jl C H A P. IV. Of Blue. 1T700L, or Woolens to be dyed Blue, ' ^ require no other preparation than that of foaking them well in common warm water, and then fqueezing or draining. This precau- tion is necelTary in order to facilitate an equal introduction of the colour into the body of the Wool. The fame preparation is neceflary for colours of every kind, and requifite both for Worfted and Woolen Stuffs. Wool in the fleece, for the fabrication of cloth, either to be mixed, or otherwife, and which, for this reafon, is obliged to be dyed, before it be fpun, requires a different prepara- tion, in order to take out the greafe, viz. to deprive it of the natural fat which it has imbibed from the animal, and which is never extra6ted, till prepared for being dyed \the natural fat adher- ing to the Wool prejerues it from being fretted by the moth.'l This operation being the bufinefs of the Dyers, and indifpenfably neceffary for all Woolens which are to be dyed before they are fpun, be the colour what it may, I fhall now defcribe. The procefs is not, however, always exadly the famej but the following is the method ufed in the manufadory at Andely in Normandy, where cloth is remarkably well fabricated : They put twelve buckets of water ^nd four of fermented urine into a large copper, capable of holding twenty buckets. The copper is then C 3 heated t2 THEARTOF heated, till you can bear your finger in the liquor, into which they throw ten or twelve pounds of Wool in its natural ftate, viz. before it is cleanfed. They fuffer it to remain in the copper about a quarter of an hour, ftirring it with a ftick fiom time to time : it is then taken out, and fet, for a moment, to drain on the barrow or ladder (mentioned in the defcription of the dying uten- fils) from whence it is carried in a large fquare baflcet, which bafket is put into a running water, where two men keep moving it for a confiderable time from one to the other, with long flicks, till the fat is entirely extracted. While any of this fat remains in the Wool the water is whitifli and muddy, confequently, when the water is clear it is a fign that the Wool is fufficiently clean ; you then take it out, and put it in a hamper to drain. While the firft Wool is in the bafket, you put into the copper a fecond parcel of an equal quantity, and fo on, till your wool is all clean. If the liquor diminiflies too faft, the copper mufl be repieniflied with the fame compofition of one part urine, to three parts water. They generally fcour a bale of Wool at the fame tim.e. If it weighs 250 pounds while fat, it generally diminifhes fi.xty pounds, and when clean and dry, weighs no more than 190 pounds. It is evident that this diminution mufl vary according to the quantity of fat contained in the Wool, or in proportion to the accuracy of its extradlion. But it is impofTible to be too urgent upon the fubjeft of cleanfing the Wool, becaufe it is thereby better difpofed to receive the colour. This D Y I N G W O O L. 23 This fweat, or fat, is, in fome degree, a uri- nous perfpiration of the flieep, which is pre- vented from flying off by the thicknefs of the fleece, where it is retained, being indiflbluble in water; hence water alone cannot fcour it; a fourth part urine is therefore added to the copper; but this urine fhould be kept till it begins to fmell, in order to develope the vola- tile falts by fermentation. Thefe volatile falts, being an alkali, form, with the greafe, a kind of foap, which is always produced by the union of an oily fubftance, with any alkali what- foever. As foon as the foap is formed by the combination of thefe two fubft:ances, it is folu- able in water, and therefore eafily waflied out. Soap is evidently formed by this operation, becaufe the water which carries it ofi^ becomes milky. If the copper has been fupplied with enough of the fermented urine, for the quan- tity of the greafe adhering to the Wool, it will be perfeftly cleanfed; if deficient, the whole of the fat, not being converted into foap, the Wool will remain greafy. - The fame operation may be performed with fixed alkali, as a lye of pot-afli ; but bcfides that this lye is much more expenfive than the urine, there is fome danger, if you fail in the exa6t pro- portion, that it nriay injure the Wool. For I recoiled from various experiments, that thefe kind of cauftic falts, foon deftroy all animal fubftances, as Wool, Goats Hair, Silk, &c. I muft intreat the reader to remember, though I fhould make no further mention of this ope- ration of fcouring, that it is neverthelefs ne- C 4 ceflliry 24 THEARTOF ceflary for all Wool which is to be dyed before it is fpun ; and even when fpun : alfo fluffs of all kinds, Ihould be foaked, in order to prepare them for receiving the colour more equally. Of the five primitive colours already men- tioned, tv/o of them fhould be prepared with ingredients that furnifh no colour, but which, by their acidity, and the finenefs of their earth, dif- pofe the pores of the Wool to receive the colour. This preparation is called the Bouillon. It varies in proportion to the nature and fliade of the colour. The colours which more particu- larly require it are the Red, the Yellow, and the colours derived from them. Black requires ^ particular preparation. Blue and Fawn colour none; it is fpfficient that the Wool be well fcoured and foaked, and even for the Blue, there is nothing more required than plunging it into the vat, ftirring it well, and letting it remain for a longer or fiiorter time, according as you would have the colour, more or lefs deep. This reafon, and the necefilty of prcvioufiy giving Wool a tinge for many colours, has determined me to begin with the moft exadt rules for this colour. Notwichftanding the very great facility of dying Wool Blue, when ;:he Blue vat is once prepared, it is far otherv/ife with regard to the preparation of this vat, which is adlually the moft difficult operation in the whole art of .dying. The reft require nothing more than a fimple procefs, tranfmitted from mafters to their apprentices. There DYING WOOL. 25 There are three ingredients ufed in Blue, viz. Pafiel, JVoadi and Indigo, I mean to treat of the preparation of each, and fhall begin with the Paftel Vat. C H A P. V. Of the Paftel Vat, PASTEL is a plant cultivated in Languedoc, and in other parts of the kingdom. It is imported in balls, generally weighing, from 150 to 200 pound j and refembles a colledtion .of little lumps of dry earth, intermixed with the fibres of plants. It is called in Latin IJatis or Glaftum^ which, being gathered at a certain degree of maturity, is fuffered to rot, and then made into balls for drying. Various are the precautions to be obferved in this preparation, upon which M. Colbert, in his Regulations for the Art of Dying, has given feveral articles. The beft prepared Paftel comes from the Diocefs of Alby. To extrad the Blue colour, it is npcefiary to have large wooden Vats, fuch as I have men- tioned in the beginning of this workj the larger the better. You generally take three or four balls of the Paftel, ^nd, having well cleaned the Vat, you proceed in the following manner: Your copper cauldron fliould be placed as near as poflible to the Vat, and then filled with pond water J if the water be not fufficiently pu- trid^ yow put in a handful of hay, viz. about two t>. H. HILL LIBRARY •North Carolina State College 26 THEARTOF two or three pound, with eight pound of brown madder, or the bark of the root. If you could have the old liquor of a naadder vat, it would fave frefli madder, and have a better effect. When the copper is full, the fire fhould be lighted under it at three o'clock in the morning. It Ihould boil an hour and a quarter, fome Dyers let it boil two hours and a half or three hours. It is then, by means of a fpout, conveyed into the Vat, which fliould be very clean, and have at the bottom, a hat full of wheaten bran. While the boiling liquor is running into the Vat, you put in your Paftel balls, one after another, in order that they may be more eafily broken, mixed, and flirred with the rake. It fliould indeed be continually flirred till all the hot liquor is emptied out of tbe copper into the Vat, and when the Vat is rather better than half full, it fnould be covered with a lid, a little larger than the circumference: befides this, there fhould be a cloth over it, to confine the heat as clofe as poffible, and then it fhould fland for four hours. About four hours after the Vat is fee, it fhould be uncovered, in order to mix it well and to give it air. For every ball of Pailel, you throw into it a full meafure of warCi a falfe name which the Dyers give to flaked lime. This meafure is a kind of wooden fiice, ufed for mea- furing the lime into the Vat. It is five inches broad, and three and a half long, and contains about a handful of lime. After fcattering; in the lime, the Vat fhould be well mJxed and covered as before, except a little fpace, about the breadth of your hand, to let in the air. Four DYING WOOL. 27 Four hours afterwards it fhould be ftirred again, without fupplying it with any more lime, then covered, and fufFcred to ftand for three hours longer, leaving, as before, a fmall open- ing to let in the air. At the expiration of three hours, it may be again uncovered and well ftirred, and if it be not yet ready, and come to^ according to the language of the Dyers, that is, if the Blue does not rife to the furface, and that it flill foams, which may be known by ftriking with the flat of the rake, it will be necef- fary, after ftirring it well, to let it ftand an hour and half longer, watching -it carefully during that time, in cafe it fliould caft Blue. You tlien fupply it with more water, till the Vat is full, putting in as much indigo, as you think proper, the Dyers, at prefent being at liberty to ufe as much as they pleafe. Of this foJution of indigo, which fhall be hereafter explained, they generally allow one common Dye-houfe kettle, for every ball of Paftel. Hay- ing filled the Vat, within fix fingers of the edge, you mix it well, and cover it as before. An hour after it has been fupplied with water, you give it two meafures of lime, for every ball of Paftel, or in proportion to the quality of the Paftel, according as you think it will ufe the lime. The reader will, I hope, pardon thefe exprefiions : tliis treatife being written for Dyers, I am therefore obliged to fpeak their language. The philofopher will have no difficulty in fubftituting proper terms, which ^he workmen would probably not iinderftand, I ' Some 28 THE ART OF Some kind of Paftel, requiring much lefs pre- paration than others, it is therefore impoflibic to give rules, that would be accurate, and at the fame time, general. It is however neceflary to obferve, that the lime fhould not be fcattered in, till the Vat be well ftirred. Having again covered your Vat, at the expira- tion of three hours, you put in a pattern, which Ihould remain im.m.erfed in the liquor for three hours. You then take it out, in order to exa- mine the ftate of your Vat. If ready, your pattern fhould be green when taken out; but, by being expofed to the air, Ihould become in- flantly Blue. If it be of a good green, you ftir the Vat, adding one or two more meafures of lime and then cover it. You ftir it again, three hours afterwards, add- ing more lime, if neceflary. You then cover it, for an hour and half longer, and then, the Vat being fettled, you immerle a pattern, which, at the expiration of an hour, you take out again, in order to fee the effeft of the Paftel. If the pattern be a good green when taken out, and becomes a deep Blue, by being expofed to the air, you put in another pattern, in order to afcertain the effecft of the Vat. If the colour of your pattern be fufRciently high,' you fill your Vat with hot water, or, if pofiible, with the liquor of an old madder vat, and then ftir it again. If you think the Vat wants lime, you add a fuf- ficient quantity, according to the fmell, and as, by the working you may find it neceflary. This done, you cover it again, and an hour after- wards, if your Vat be in a proper ftate, you immerfe DYING WOOL. 29 Immerfe your fluffs. This is, to open ahe Vat, as the Dyers call it. 'DiRECTiovis for ibe proper management of the Vat. "VTOUR Vat is ready for working, that is to fay, in a proper ftate for Dying Blue, when the fediment, or grounds, at the bottom, is of a fine brown green, when it changes, upon being taken out of the Vat, when the froth, which rifes in great bubbles on the furface, is of a fine Perfian Blue, and when the pattern, which had been fteeped an hour, is of a fine dark grafs green colour. When in a proper flate for working, the liquor will be clear and reddiiTi, and the drops which ftick to the rake, brown. When the fediment, or grounds, as I have already faid, change colour, when taken out of the brevety or liquor, and becomes brown, when cxpofed to the open air. When the liquor is neither harlh, nor too greafy to the feel; when it neither fmells of lime, nor of lixivium. Thefe are, as near as poffiblc, the marks, which denote that your Vat is in a proper ftate for working. Indications, when a Vat has fuffered by too mmb or too little limey the two extreams which ought carefully to he avoided. VX^HEN a Vat is too plentifully fupplyed, that is, when it has had more lime, than the Paftei requires, you will eafily difcernit, by putting in 30 THEARTOF in a patern, which inflead of becoming a fine grafs green, is only a dirty Greyifh Blue; when the fediment does not change colour, when there is fcarce any efflorefcence on the Vat, and when the liquor fmells only of lime, or of the lixivium of lime. In order to remedy this evil, it is necefTary to unfurnifh the Vat, for which purpofe, the Dyers have feveral methods. Some ufe tartar, others bran, adding a bulhel of either, more or lefs, ac- cording as the Vat may require. Others throw in a bucket of urine. In fome places they ufe a large iron ftove, long enough to reach from the grounds at the bottom, to the top of the Vat. This machine has a grate, within a foot of its bottom, and an iron funnel, commencing with the bottom of the grate, and communicating with the external air. This furnace is plunged into the Vat as far as the grounds, without forcing it down, and fhould be retained by iron bars, to prevent its rifing. The heat, communicated by this llove, caufes the lime at the bottom of the Vat, to rife to the furfacej by this means, you can eafily take out as much of it as you think proper, with a fieve. But when you have taken it our, you fhould be careful to re fupply the Vat with a fufficient quantity. Some Dyers corredl a Paftel Vat with tartar, and Hale urine, boiled together} but the bcft method is to put into it a fufficient quantity of bran and madder, and iftheexcefs of lime be not great, you may let it ftand four, five, or fix hours, or more, only adding to it, two hats full of bran, and three or four pounds of madder, which fhould be DYING WOOL. 3t be fprinkled lightly on the top; it fhould then be covered. At the expiration of four or five hours, you ftir it with the rake and then put in a pattern, in order to try the efFefb. If it be checked, and that the Blue does not rife 'till it be cold, you fhould leave it to recover, without difturbing the liquor, and fometimes let it (land for whole days without mixing. As foon as it gives you a tolerable pattern, it fhould be re-heated. In general the lime, which feemed to want flrength fufBcient to promote fermenta- tion, revives, and prevents the Vat, for fome time, from yielding any colour. If you would bring it forward, you fhould fprinkle fome bran and madder on the top, befides an addition of two full bafkets of frefh Paftel, which afiifts the liquor, when re-heated, in difTolving the lime. You fhould now try the Vat, by putting in a pattern, from hour to hour, that you may be enabled to judge, by the colour of the green, how far the lime has operated. By thefe experiments you will be direfted to condud it with accuracy, for when the Vat has fufFered, by too much, or too little lime, it is extremely difhcuk to manage. If, during the time you are endeavour- ing to retrieve it, the liquor fhould cool too fail, you fhould preferve the heat, by emptying out fome of the liquor, and replacing it with hot water j for when the hrccet or liquor grows cold, tke Paflel confumes none, or but very little of the lime. An over degree of heat, will aifo retard the a6tion of the lime. In this cafe, therefore, it were better to wait a little rather than be in too great a hurry to reflore theVars, when they have futfered. It 32 THEARTOF It is evident that the Vat has fufFered, by no€ being fufficiently fupplyed with lime, when there is no efflorefcence on the liquor, vi£. no large air bubbles, of a fine blue colour, only a fettled froth of fmall tarniihed bubbles, and when, by dafhing it on the furface with the Rake, it makes a hifling noife, produced by the burfting of an infinite number of thefe fmall air bubbles, as foon as they are formed. The liquor has alfo an ofFenfive fmell, like rotten eggs. It is harfh and dry to the feel, and the fediment does not change colour, when taken out of the liquor. This accident is chiefly to be apprehended when the Overture is made, and you begin to work j for if you do not carefully attend to the ftate of the Vat, by the fmell, when you ftir it, after fixing in the crofs or ret, and imprudently put in the ftufl^s, when the Paftel has fpent the lime, it is to be feared that the Vat will be fpoiled, becaufe if you put in the ftufl^s, when the fmall quantity of lime remaining is in a ftate to afV, it will ftick to them; the liquor becomes impoverifhed, and the Vat only blots the ftufFs; you ihould there- fore take them out immediately, and replenifh as quick as poffible, in order to fave the remainder of the Dye, by adding three or four meafures of* lime, more or lefs, in proportion as the Vat has fufl^ered, and this without ftirring at the bottom. When you ftir the Vat you ftiould attend to the noife, for if the hifling ceafes, and the bad fmell changes, it is to be hoped that the liquor only has fu fleered, and that the pafte is not yet impoveriflied. Wlsen you have ftopped the noife or hifling, at leaft in part, and that the br&vet or liquor fmellsof lime DYING WOOL. J3 lime, and is foft to the feel, you cover the Vat, and let it ftand. If at the expiration of an hour and half, the efflorefcence commences, you put in a pattern which, in an hour afterwards, you take out, and regulate your procefs according to the degree of green which your pattern has imbibed. But, in general, when Vats are thus checked, they do not fo foon recover. The Vat being in a proper ftate, you fufpend the crofs, and begin with thirty ells of cloth, or of fcoured wool, of equal weight, which you defign to prepare for black by firft dying it a blue grey. Having pafled, and repaflcd this quantity, keeping it in the liquor during a full half hour, you wind it round the Reel, which refts on the pods fixed over the Vat. The cloth is then hung by the liftings, in order, by expofing it to the air, to change the colour from green to blue. If it be not fufficiently deep for a blue grey after the firft turn, you give it another, putting in the end that came firft out of the Vat, foremoft ? You give this batch two or three turns according to the ftrength of your Paftel, and ac- cording to the depth of the colour required. If your Paftel be good, as the trueLauragais gene- rally is, you may put into this; Overture, or firft- working, a fecond batch, after the firft is taken out. Having made this Overture, which is likewife called the firft ftirring, you ftir the Vat afrefli, adding lime, but not fo much as to deftroy the abovementioned feel and fmell, obferving thatin proportion as the colour becomes weaker, the fvirtue of the Paftel is alfo diminiftied. D " H 34 THEARTOF If your Vat be in a proper ftate, you fhould, ori the firft day of working, ftir it three or four times. You muft be careful not to overwork it, particu- larly on the fecond day. Concerning the colours; to obtain from this frefh Vat all polTible advantage, you firft dye your ftuffs defigned for black, afterwards the Blues de roy^ and then fuch as are intended for a a brown green. The Violet and Turkey Blues are generally performed in the laft ftirring, on the fecond day of the Overture, If the quantity be too much diminilhed, on the third day the Vat fhould be filled, within four inches of the edgCj with hot Waten Towards the latter end of the week you dye the light blues j and on Saturday night, in order to pre- ferve it 'till Monday, you garnifi with a little more lime than on the day preceding. On Monday morning you reheat, letting the liquor run from the Vat into the copper cauldfon, by means of a fpout or channel, placed from one to the other. The clear liquor runs off, 'till it comes to the fediment or pafte, and when boiling is re- turned into the Vat, ftirring the pafte as the liquor falls on it. You may, at the fame time add a full cauldron of prepared indigo, as ftiall be hereafter mentioned* When the Vat is within four inches full, and well ftirred, you cover it, and at the expiration of two hours, put in a pattern, which ftiould re- main for an hour only. You then add lime ac- cording to the green Ihade of the pattern, and at the expiration of an hour or two, if your Vat has not fufFered, you may venture to put in a batch DYING WOOL. 35 batch of fluff. This Huff having been wafhed in two waters for the fpace of a full half hour, it is wrung; it fhould then have another dip, as diredted, in a frerti Vat. This re-heated Vat fhould be conduced in the fame Manner as at firft, that is to fay, ftirred three times the firflday, examining each time, lefl it fhould require more lime, in which cafe you add the quantity requifite, ac- cording to your Judgement. The blue dye of the Paftel only, is in the opi- nion of thofe prejudiced in favour of old cufloms much fuperior to that obtained from the Paftel and Indigo together: but then it is more expen- five, becaufe the Paflel yields much lefs colour than this foreign drugj repeated experiments fuf- ficientlydemonflrating that four pounds of the fine indigo of Guatimaloy yields as much as a ball of th^Albigois Paflel; and five pounds, as much as a ball of that of the Lauragais which generally weighs 2IO pounds. Hence the ufe of indigo mixed with Paflel is very frugal, as a fingle Vat with the addition of indigo, will dye as much fluff as two Vats, were the indigo omitted. They commonly put diffolved indigo to frefh Vats after the Paflel appears blue, and a quarter, or half a quarter of an hour afterwards, you give it the -pied^ viz. an addition of lime; but as the diffolved indigo is already garnijhed by the lixivium in which it was diffolved, it requires lefs lime than when the Paflel is alone. When you reheat, the indigo is put in on the Saturday night, that it may incorporate with the liquor, and at the fame time ferve to garnijh it, by means of its lime. D 1 ^he THE ART OF 'J'he preparaiions of Indigo for the Paflel Vat. 'T^HE Indigo Gttatimalo, or of Guatimala is the bell: it is brought from America in the form of fmall flint flones, of a deep blue ct>lour. Its goodnefs is determined by its effeft, and alfo by breaking. If good, it will be of a dark violet colour at the infide, and by rubbing it on th« nailj it will appear copperous. That which is the leaft ponderous is the bed. In order to diiTolvc the Indigo, you mufl have in your Dye-houfe, a feparate cauldron and fur- nace. Eighty or an hundred pounds of Indigo require a cauldron containing thirty, or thirty five buckets of hard water. This fhould be made into a lixivium ; by put- ting five and twenty buckets of clear water into tlie copper, with the addition of a hatful of bran, twelve or thirteen pounds of madder, and forty pounds of good pot-aHi : that is, half a pound of alkaline falc, and two ounces and half of madder to each pound of Indigo, thefe quantities being necellary for the folution of eighty pounds of this drug. It fliould boil faft for three quarters of an hour, or thereabouts: the fire fhould then be taken from under the furnace, and the lixivium Ihould (land during half an hour, in order that the lees, or dregSj may fall to the bottom. The clear I'quor is then poured into a clean cafk, placed clofe to the copper. Take out the grounds at the bottom of the copper, wafh it clean; return the clear lixivium into the copper j light a fmall fire under it, and at the fame time put into the D Y I N G W O O L. 37 the copper eighty pounds of Indigo^ reduced to a grofs powder. The liquor fhould bemadev^ryhot; but not fuffered to boil, and to facilitate the folu- tion, you keep continually ftirring it vv'ith a fmall Rake, to prevent it from gathering into lumps, or from burning to the bottom of the copper. You fhould keep the liquor moderately hot, and the degree of heat as equal as poITible, by throw- ing into it, from time to time, fome lixivium of lime, which fliould be at hand, ready prepared, it order to cool it. As foon as you perceive that there is no longer any lumps in the bottom of the copper, and that the Indigo is well diflblved and diluted, you draw the fire from the furnace, leaving only a few hot cinders, to keep it v/arm ; you cover the copper, and then put in a pattern of fluff which fhould be green when taken out, and turn blue immediately, upon being expofed to the air. If this fhould not be the cafe, you muft add fome frelb clear lixivium, prepared in thefamemanner as thepreceding. Of thisfolution of Indigo, one, two, or more buckets are added to the Paftel Vat, when it has fufHciently fermented and begins to yield its colour. This part of the Art of Dying requires an able workman. Having convinced myfelf of the methods necefr fary for the fuccefs of a large Paftel Vat, 1 deter- mined alfo to try if it was not poffible to fet one on a much fmaller plan, by fome Dyers fuppofed. to be impracfticable. I took a little barrel, con- taining about five and twenty gallons; this I put into a copper full of v/ater, which I carefully kept properly heated. I then put into a fmall copper^ twenty gallons of water, with an ounce and a D 3 half 3? THEARTOF half of madder, and a very fmall handful of Dyers Weed : an herb ufed for dying yellow, but which upon the whole feems to be of no ufe in this operation; I was, however, advifed to ufe it as being neceflar)\ I let them boil together, for three full hours, and about nine o'clock in the evening, poured all this liquor into the barrel, which ftood in the copper, having firft put in two fmall handfuls of bran: I added at the fame time, four pounds of Paflel, and having flirred it well for a quarter of an hour, covered it, and took care to have it flirred, in the fame manner, every three hours, even during the night. I put no four water into this little Vat, as is the cuftom, at prefentj but the bran, which I had jufl: put in ferved as a fubftitute, becaufe it foured with the liquor. The next morning about nine o'clock, the Vat began to make a little noife or hiding. It alfo formed a kind of froth like fuds. Having mixed it well, I added an ounce and half of flacked lime, fifted, which increafed the froth. The fmell be- came flrongcr, and therefore I was of opinion tha^ a little more Paftel might be added. At half after ten, the Vat fmelt ftronger of the lime, produced froth, and made a little noife. I immediately put in a pattern, which, at the ex- piration of an hour, I took out green, and which upon being expofed to the air became blue. I ilirred it again, and, an hour afterwards, put in another pattern, which, after remaining an hour alfo, cam^e out green like the firfl, but upon being expofed to the air, was of a deeper blue. By this DYING WOOL. 39 this I concluded it was in a proper ftate for the Indigo. At half after twelve I added two ounces of Indigo, not diflblved, only pounded, fifted, and diluted in warm water, ^yith a lump o( cendres gra- velees as big as a wall-nut (that is, the lees of wine, calcined, which as I have already faid, contains a quantity of alkaline fait.) Every two hours after- wards I put in a pattern, alternately ftirring, that is to fay, an hour after I ftirred the Vat, I put in the pattern which remained another hour, after which I again ftirred, and fo on 'till ten o'clock. Upon comparing the patterns, the l^ft was always evi- dently the darkcft: they alfo became more and more bright, in proportion as the lime was con^ fumed. It ought now to have been replenifhed, becaufe the laft pattern fliewed that the lime was ex- Jiaufted. In that cafe it would have been nccef- fary to have worked at it 'till two oclock in the morning; and therefore, being an inconvenient time, I chofe to dticv gannjhing-y giving it only fufficient to fuftain it 'till the next day j that is to fay, about half an ounce of lime, to ftir it, and an hour afterwards to put in another pattern^ which, at the expiration of an hour, was in faft, more blue than the others, but which, on account of the lime, was lefs lively than the pre- ceding. In this manner the Vat may be retard- ed, or brought into a proper ftate, as moft convenient. Two more patterns were put in during the night, which were ftill darker. That which was ta|cen out at eight o'clock in the morning, P 4 being 4.0 THEARTOF being a little dull, llicwed that the lime, which had been put in the preceding evening, was not yet confumed. Sonne of the pade which I had taken from the bottom with a Rake, in order to examine the flate of the Vat, was of a yellowifii brown; but, when expofed to the air, became of an olive green. It appeared of the fame colour under the furface, if moved with the hand; but inftantly became green. It fmelt rather ftrong, though not fo much of the lime. The liquor was fomething of the colour of beer, and the fkum or froth, produced by ftirring it with the Rake, was blue. By thefe figns you are befl enabled to judge of the Hate of yourVat. I {till continued to put in patterns, and to ftir alternately, 'till two o'clock in the afternoon. The pattern then taken out was of a very fine green, and imm.ediarely afterwards became of a beautiful blue, which fhewed that it was time to fill the Vat. For this purpofe, I put about eight gallons of water into a little copper, with a quar- ter of an ounce of madder, and a handful of bran: when it had boiled half an hgiir, I put the liquor into the little Vat for three hours. It was then ftirred, and an hour afterwards a pattern put in, which at the expiration of an hour was taken out, very beautiful and lively. This little Vat was ready for working at feven o'clock, and might have been ready feventeen or eighteen hours fooner, but was defignedly re- tarded. The C'OjSj or net, fuch as 1 have already defcribed, when fpeaking of the necelTary utenfils for Dying, was let dowpj within three or four fingers DYING WOOL. 4r fingers of the pafte or grounds, and fufpended by means of four pack-threads, faftened to the edge of the calk. An ell of ferge was then immerfed, without any other preparation, than having been pre- vioiifly wet, in order to make it imbibe the colour equally. It was then moved with the hand, and a little iron hook, for about a quarter of an hour, at the expiration of which time, it was taken out very green. It was then wrung or prefTed, and immediately, upon being expofed to the air, became blue. It was again put into the Vat for a quarter of an hour more, in order to give it a deeper colour, when it was taken out much greener than the firft, and upon being again wrung, became a more beautiful blue than I could have expedlcd. A pound of worded was then immerfed, having been previoutly wet with hot water, and ex- prefTed; but the Vat retained fo little of the paftel, that the worded imbibed only a Iky blue colour. It was again immerfed, the day after, for the lad time; and to preferve the Vat, and at the fame time, to redore the colour, I fprinkled into it half an ounce of fifted lime. Before this, it fmelt fomething like road meatj but imme- diately, upon throwing in the lime, there arofe a volatile alkaline, or urinous odour. The Vat was then covered, and the next day the worded was finiflied. It was dill poflible, by replenifliing the Vat to dye a pound or two more; but not to lofe time, I had it thrown out, thefe experi- ments ipeing fufHcientlv ro demondrate the pofTibi- lity 42 THEARTOF lity of fetting a Paftel Vat, in the little, as well as in the great, I fhall, however, add fome necefiary reflec« tions, in order to convey a more perfefl idea of this operation. A Paftel Vat fhould never be re-heated, but when fit for working; that is to fay, when it has neither too much, nor too little lime, and requires heat only, to be in a proper ftate. When it has too much lime, it fmells ofFenfively. On the contrary if it fmells fweetiih, and that the froth, which rifes on the furface when ftirredwith the Rake, is of a pale blue, the quantity of lime is not fufficient. When you would reheat, you fhould be care- ful not to garntjh with lime over night (I mean if it Ihould not require it very much) as you would by fo doing, run a rifle of giving it the coup de pied 3 or kick, as the Dyers term it; for the lime which the Vat had retained, by re-heating, ac- quires more adtion, and is too quickly con- fumed. You generally put frefli Indigo into the Vat, as often as it is re-heated, and that, in propor- tion to your quantity of work; but if you have not much work, and require only light colours^, this addition is unneceflary. The ancient regulations allowed only fix pounds of Indigo to every ball of Paftel, imagining that the colour obtained from the Indigo was not folid, and that to conftitute a permanent colour, it was neceffary to add a great quantity of Paftel; butfrom the late M.Dufay's experiments, andfrom thofe which I have myfelf fince made, it is at prefent DYING WOOL. 43 prefent fully proved, that the colour of the Indigo, even without any addition, is equally good, and as little afFedlcd by the air, the fun, rain, or boiling, as the Paftel. This article there- fore was reformed in the new regulations of 1737, where the Dyers in Grain are permitted to ufe as much Indigo as they plcafe. When aVat has been heated, and well worked, two or three times, the fame liquor is frequently preferved, only taking out a part of the fediment, and replacing it with fome frefh Paftel. It is jmpofTible to afcertain the quantity, as that mull depend on the work to be done, and this pro- portion will be foon learnt by experience. Some Dyers preferve the fame liquor in their Vats for feveral years, replenifliing only with I Paftel and Indigo, in proportion as it has been worked; others empty their Vat intirely, change- ing the liquor when it has been re-heated fix or {tvtn times, and that it no longer yields any colour. Practice only can afcertain which is the beft method. It is howeycr retional to fup- pofe, that by intirely renewing the Vat, from time to time, the colours will be more lively, and much finer. Thofe who pradtice the con- trary method are not the beft Dyers. Their Vats in Holland are of a different con- ftrudion, and do not require fuch frequent heating. They have been ufed for many years in ♦Meflrs. Van Robbais* royal manufactory at Abbeville. The upper three feet of thefe Vats is made of copper. They are moftly furrounded by a brick wall, about feven or eight inches from the copper, Jn this jnteryal, the embers are I depofited. U THE ART OF depofited, which maintain the heat of the Vat, for a confiderable time, fo that it remains for feveral days in a proper ftate for working, with- out the necefTity of re-heating. Thefe Vats arc much more cxpenfive than the others; but they are more convenient, efpecially for light colours j becaufe they are always ready for working, even ^fter they become very weak. This is never the cafe with the others, which frequently give a much deeper colour, than was intended, unlefs you fufFcr them to grow confiderably colder, and then the colour is neither fo good, nor fo lively. In order to dye thefe light colours in the com- mon Vats, it were better to prepare one on pur- pofe, that fhould be ftrong in Paftel and weak in Indigo, becaufe thefe would give their colour more flowly, and the light colours be obtained from them with much more facility. With regard to the Dutch Vats, juft men- tioned, the four conftrudled, by the diredion of MefTrs. Van Robbais in their manufadory, are fix feet deep, the upper three feet and half cop- per, and the lower two feet and half lead. The diameter of the bottom four feet and half j and of the top, five feet four inches. I now return to the neceffary obfervations on re-heating the common Vats. If you heat a Vat, when exhaufted, viz. when it is deficient in lime, it will turn imperceptibly in fuch a man- ner, as to be in danger of being fpoiled, becaufe the lime, already too much diminifhed, will be intirely confumed by the heat. The only remedy, if difcovered in time, is to throw it back into the Vat, DYING WOOL. 4^ Vat, and to replenifli with lime. You fhould then wait 'till it recovers before you re-heat. When re-heating you fhould be careful to put the grounds into the copper with the liquor. You fhould alfo be very careful not to let it boil, elfe thevolatilc parts, neceflary towards the opera- tion, will evaporate. Some Dyers do not put Indigo immediately after the liquor is emptied out of the copper into the Vat; not 'till fome hours afterwards, when they perceive the Vat begin to retrieve. This precaution is taken left the Vat fhould not recover, in which cafe, the Indigo would be lo.ft: but then it does not give its colour fo freely; for being obliged to work at the Vat immediately, left it fhould cool, the Indigo, not being fufficiently difTolved, orintirely incorporated, does not produce its full efFefl. It were therefore befl to put the Indigo into the Vat im.mediately with the liquor, and to flir it well afterwards. When you re-heat a Vat that has not been worked, it fhould not be Ikimmed, as in the com- mon re- heatings, becaufe you would then take out the Indigo ; whereas in a Vat that has been worked, the fkim is formed of the earthy particles of the Indigo andPaflel, joined to a portion of the lime. When you have put too much lime into the Vat, you muft wait 'till it be confumed. It might be accelerated in the re-heating, by the addition of ingredients, which would, in fome degree, deftroy the action of the limej fuch as tartar, vinegar, honey, bran, a mineral acid, or, in fhort any acid matter. But thefe correc5lives would, at 46 THE ART 0"F at the fame time, confume the colour of the Indigo and Paftel. It were therefore beft to let the lime confume, without ufing any method to promote it. Vats are generally not garni/Joed with lime 'till the fecond, or fometimes the third day, and there- fore you fhould by no means immerfe the violets, the purples, or any of the delicate coloured worfted or ftuffs, on the day after you had re- plenifhed, becaufe the lime, being yet tolerably adtive, tarnifhes the firft colour: it fhould there- fore be the fifth or fixth day before you put in your crimfons for violets ; or your yellows for green. By attending to this particular your colour will be always bright. When the Vat has been re-heated, you mufl wait 'till it begins to work, before you garnijh» If it be done too foon, it will become turbid, or if a little of the pafte is put into the copper, it is attended with the fame confequence. In this cafe, your remedy is to let it fland 'till it fettles before you begin to workj which will require two, three, or four hours, or even a whole day. You fometimes make ufe of weak limej but then, if you do not take care, your Vat gets a kick; becaufe this lime remains in the liquor, and does not incorporate fo well with the pafle. When this accident happens, the liquor has a ftrong fmelli and the pafle, on the contrary, a fweetifh fmell, whereas they fhould both fmell alike. Your remedy is to haflen the folution, by flirting it often in order to mix the lime with the DYING WOOL. / 47 the pafte, 'till the proper fmell of the Vat be re- ftored, and 'till the froth or fkim becomes blue. You may, if you pleafe, fet a Paftel Vat with- out Indigo ; but then it would yield very little colour, and dye but a very fmall quantity of ItufFor wool; for one pound of Indigo^ as I have already faid, yields as much colour as fifteen or fixteen pounds of Paftel. I had one of thefe kind prepared, in order to afcertain the power of the Paftel alone, and I have found, notwithftanding what prejudice may urge to the contrary, that the Indigo is, in no refped, inferior in the beauty and folidity of its colour. As lime is conftantly ufed in fetting a Vat, and fometimes four water, I think it is proper in this place to mention their preparation. In order to flack lime, fit for dying, you throw into water feveral pieces, one after another, taking out each piece when it begins to ferment, and putting in another. It is then thrown into a copper, or any other empty vefTel, where it will fall to powder, and confiderably increafe in' bulk. It is afterwards fifted through a canvas bag, and preferved in a very dry cafk or tub. Acid waters arc necelTary, not only in par- ticular circumftances, relative to the fetting of a Paftel Vat, but alfo in fome preparations of woolens, and fluffs for dying. They are made in the following manner. Fill a copper, of any fize, with river water, put fire under it, and, when it boils, throw it into a calk in which you had before put a fufHcient quantity of bran. It Ihould be well ftirred, three or four times a day. The proportion of bran. 48 THE ART OF bran or water, is not very important. For my part, I found, that putting three bufhels of bran into a veflel, containing feventy gallons of water, had the defired efFed. This water, at the ex- piration of four or five days becomes four, and confequently proper to be applyed, in all cafes, where it does not injure the preparation of the worfted. Woolen fleece dyed in liquor containing too . great a quantity of acid water, would in all pro- bability be difficult to fpin, as the fibres of the wool, being glued by the bran, would not pro- duce an even thread. It is alfo neceflary to ob- ferve, that it is a bad cuftom, to leave the acid water to remain in the copper cauldron, as I have feen praftifed by fome eminent Dyers: as it will corrode the copper, and if fuffered to remain long enough to difTolve any part of this metal, it will occafion a defefl, both in the colour and ftuff; in the colour, becaufe the diflblved copper gives a greenifh tinge; in the quality of the ftuff, becaufe it afts as a corrofive on all animal fubftances. To the beft of my knowledge, I have omitted nothing eflential concerning the Paftel Vat. If any difficulties Ihould occur in the praftice, or any accident happen which 1 have not mentioned, they are not very confiderable, and may be'eafily remedied by thofe who are acquainted with this operation. Readers, having no idea of this pro- cefs, will fuppofe me tedious, they will alfo find many repetitions; but thofe who read this chap- ter for the fake of inftruftion, will perhaps blame DYING WOOL. 49 blame me for being too concife. I thought it more neceflary, on account of the difficulty of the operation, to put the obfervations I had made, from my own experience, concerning the government of the fmall Vat, in the form of a memoire, defcribing it, as I have, hour by hour, rather than dwell on the defcription of preparing a Vat in the great as above defcribed becaufe I was not always on the fpot. Thofcj who have read this chapter with attention, will not be furprized that the mafter-piece expefted from apprentices, who would be admitted as Mafter Dyers, either in Grain or not in Grain, is the preparation, and, more efpecially, the workino- of thePaftelVat. "" CHAP. vr. Of the Woad Vat, 'TpHERE is fcarce any difference to be ob- -*- ferved with regard to the Woad and Paftel Vat. The Woad is a plant cultivated in Normandy, and prepared almofl in the fame manner as the Paftel in Languedoc. As to the cultivation of thefe, I muft refer the reader to theG^aeral Inftrudions for Dying, of the i8th of Mfrch, 1 67 1; from the article 259 to the article 288, inclufive. The Woad Vat is pre- pared in the fame manner as the Paftel Vat; it differs only, in being weaker, and yield- ing lefs colour. The following is a defcrip- tion of the Woad Vat, according to an experi- E ment. 50 THE ART OF ment which I made in miniature, fimilar t« that concerning the Paftel in the preceding chapter. My objed was to verify a procefs, an account of which was fent me from Nor- mandy. I placed in a cauldron a fmall calk, containing about twelve gallons, two thirds full of river water, an ounce of madder, and a fmall quantity of weld. At the fame time I put into the calk, a good handful of bran, and five pounds of Woad. At five o'clock in the evening, the Vat was well ftirred and covered. It was again ftirred at feven, at nine> at twelve, at two, and at four. The Woad was then working, a» I have already obferved with regard to the Paftel. Some air bubbles began to rife pretty large, but in a fmall quantity, and of a very faint colour. It was then garnilhed with two ounces of lime, and ftirred. At five o'clock I put in a pattern which I took out at fix, and again ftirred. This pattern had received fome colour. At feven o'clock I put in another, and at eight, ftirred again. This pattern was tolerably bright; I then added an ounce of Indigo; at nine o'clock another pattern; at ten, ftirred again, and put in an ounce of lime, becaufe it began to fmeJl fweetlfti. At eleven another pattern, and at twelve ftirred again. This procefs was con- tinued 'till five o'clock. I then added three ounces of Indigo. At fix I tryed another pattern, and at feven ftirred again. It w^ould have been now time to fill it, being in a proper ftate for working, as the laft pattern which had been taken out very green, became a bright blue. But DYING WOOL. 51 But as I was very much fatigued, having fat up the whole night, I chofe to defer it 'till the next day, in order to fee its effedt by day light, and for this reafon I added an ounce of lime, fuf- ficient to fuftain it till 'nine o'clock in the morn- ing. Patterns were put in from time to time, and the laft being very beautiful, I filled the Vat with a liquor compofed of water, and a fmall handful of bran only. It was then ftirred, and patterns tryed every hour. Being in a pro- per (late at five o'clock, it was immediately worked. It was then garnifhed with lime, and mixed, in order to preferve it, 'till fuch time as it might be convenient to re-heat. Two months afterwards I prepared another Woad Vat, without Indigo, that I might be enabled to judge of the folidity of the dye, and was convinced, by experim.ent, that it was of equal goodnefs with the Paftel. Hence, the Paftel is fuperior to the Woad, only becaufe the latter yields lefs colour than the other. The little variations to be obferved in the method of fetting thefe difierentVats, fufficiently demonftrates that there are many circumftances, in the feveral procefles, not abfolutely neceffary. In my opinion, the only matter of importance, and which demands attention, is to condu»2, which inftead of being acid, is one of the moll cauftic alkalies. In fad, by making ufe of this alkaline lixivium, the opera- tion was attended with immediate fuccefs, and never failed me fince. I tryed feveral of thefe different Vats in miniature, in cucurbits, put into a water or fand bath. Thefe laft are attended with no difficulty J it is only neceffary to diminifh the DYING WOOL. 7t the quantity of the liquor, and of every in- gredient, in proportion to your Vat, and it is fcarce pofTible it Ihould not fucceed. Concerning that which I firft defcribed, and which is fet hot, as it is attended with a little more difficulty, and that feveral perfons may wi(h to try this operation themfelves, being rather curious and requiring neither expence nor preparation, in miniature ; I will give the defcription of a procefs which fucceeded ex- tremely well, and v/hich I purpofely fupplied with much more Jndigo than is generally done in the common method. I boiled two quarts of water with two drachms of madder, and four ounces of pearl afhes. When it had boiled a quarter of an hour, I poured it into a cucurbite, containing about a gallon, which was previouQy heated with hot water, in which I had put a quarter of a handful of bran. The whole being well ftirred with' a deal fpatula, I put my cucurbite into a very moderate fand heat, "fufficient only to keep it warm, or nearly of the fame degree of heat requifitein a common Indigo Vat. I continued the fand heat all night and the next day, without perceiving any alteration. I ftirred it only twice, during the day, with the fpatula. -The day following it produced an efflorefcence, formed a coppery fkum on the furface, and the liquor became a brown green. I then filled it with a mixture compofed of a quart of water, two ounces of pearl afhes, and a little bran. Ic was well mixed, and then left to fettle. It became perfectly well coloured, and the next F 4 day ^2. THE ART OF day I dyed feveral bits of woolen fluffs, Thefe fmall Vats are re-heated and replenifhed, with as mucheafe as a great one. I think I have nothing more to add, concerning the method of fetting the different kind of Vats for dying blue. Neverthelefs I make no doubt, but there are feveraJ other methods, ufed in different places^, and that new ones may be in- vented without any great difficulty, i will only add, that thofc which 1 have defcribed may be depended upon, and that all of them were feveral times tryed with equal fuccefs. CHAP. X. Of the method cf dymg Blue. WHEN the Vat, of whatfoever kind it be, is once prepared, and in a proper ftate, there is no difficulty in dying woolens or ftuffs, 4S it is requifite only to foak them in clean warm water, to wring them, and then to immerfe them in the Vat, for a longer or fhorter time, accord- ing as you would have the colour more or lefs deep. The ftuff fhould be from time to time opened, that is to fay, taken out and wrung over the Vat, and cxpofed to the air for a minute or two, till it becomes Blue. For let your Vat be what it will, the fluff will be green when taken out, and will become Blue, when expofed to the air. In this manner, it is very proper to let the colour change before you immerie your Huffs 4 fecond time, as you are thereby better enabled DYING WOOL. 73 enabled to judge, whether they will require only one, or feveral dips. 'Tis a cuftom with Dyers to enumerate thir- teen Ihades of Blue, from the darkefl to the lighteft. Though their denominations are rather arbitrary, and that it is impoflible to fix their juft gradation, it is, however, necelTary to diftinguiili them by fuch names as are found in the inftrudiion for Dyers, publifhed in 1669, by order of M. Colbert, They are as follow, begining with the ligheft. White Blue J Pearl Bluej Pale Blue, Faint Blue, Delicate Blue, Sky Blue, ^een's Blue, Turkey Blue, King's Blue, Garter Blue, Perjian Blue, Aldego Blue, and Infernal Blue, Thefe diftindtions are not equally received by all Dyers, in every province j but the greater part are acknowledged by them as neceflary to form fome idea of the fame colour, differing only by being more or lefsdark. There is no difficulty in dying dark Blues, it being required only to repeat the dipping at feveral times. But it is different with re- gard to light Blues, it being often dangerous, when the Vat is in a proper ftate, to let the woolens remain long enough to take the fhade you want. It even frequently happens, that when there is a certain quantity of wool to be dyed, and that it is impoffible to put it into the Vat at the fame inftant, the iirfl batch will imbibe the deepeft Ihade. To avoid this incon- venience, fome Dyers in order to procure th« lighteft Blue, which they call bleached, or white Blue, dilute their Indigo Vat with ^ quantity 74 THEARTOF quantity of warm water. But this is a bad method, becaufe the colour obtained from this mixture is nothing like fo permanent as the colour of the original Vat; for the alterant ingredients of the Indigo Vat, ferving as much to open the pores of the fubjeft dipped, as to develope the colouring matter, they are necefiary to the permanency of the colour. The beft me- thod of producing thefe light Blues is to dip them in the Vats, whether Indigo or Paftel, when the colour is exhaufted, and when they begin to grow cold. The Paftel Vat is the beft for this purpofe, becaufe it does not dye quite fo quick as the Indigo 5 but this obfer- vation I have made before. It is very certain that Blues dyed in the exhaufted Vats will be lefs bright; but they may be very fenfibly enlivened, by paiTing the fluffs, or wool, through boiling water. This praftice is even neceftary for the improve- ment of all Blue fhades ; for befides rendering the colour more lively and fixed, it alfo cleanfes the ftufFs from thofe loofe impurities which foil the hands and linen, as is almoft con- flantly the cafe : in order to favc time, the Dyers are too frequently negligent in this par- ticular. When the work is taken out of the hot water it ftiould be rinced in a' running Itream. If a dark Blue, it were ftill more advifeable to full it well in foap and water, and afterwards to rince it at the river. The foap will not, in any relped, injure the Blue; it will on the con- trary make it more bright and lively. Stuffs DYING WOOL. 75 Stuffs, which are dyed Blue, in order to be dyed Black, fhould be cleanfed with equal care, as fliall be fpecifyed in my article upon Black; but for thofe to be dyed Green, it is not quite fo neccffaryj the realbn of which will appear when I come to fpeak of that colour. There remains, I think, no other difficulty with refped to the preparation of Blue, and to the method of dying this colour. Some Dyers, diflioneftly, in order to fave Paftel and Indigo, make ule of Logwood j but this, though fre- quently more lively than a folid and legitimate Blue, fhould be exprefsly prohibited. I Ihall be more explicit in this particular, when treat- ing of colours not in grain. There remains only to explain the invifible mechanifm of the Blue Dye. This colour, con- fidered only with refpedt to its utility in dying all forts of ftufts, has been hitherto obtained from the vegetable kingdom only j nor is there any probability that the painters Blues will ever be employed in the Art of Dying, viz. Priiffian Blue, which is a fpecies of animal and mineral fubftance. [In 1748, M. yi^o^x^x of the Roy.al Aca- demy of Sciences^ dijccvered a inethod of dying filk and cloth with a preparation of Prufjian Blue, Jupe^ rior to all the Blues that had heen hitherto dyed.J Azure, which is a vitrifyd mineral. Ultramarine, which is obtained from a hard ftone, prepared, or the Blue earths, &c. Thefe various fub- flances cannot, without wholly, or in fome degree, lofing their colour, be reduced into atoms, fuf- ficiently minute, to be fufpended in the faline liquid, which Ihould penetrate the fibres of whatever 76 THEARTOF whatever fubftance the ftufF is made, whether animal or vegetable. Under the word ftuff, I comprehend, in this place, as well linen and cotton, as fiik and woolens. Hitherto we know of only two plants capable of dying Blue, viz. J/atis or Glajlum, called Pailel in Languedoc, and Woad in Normandy. It is prepared by fermenting, almoft to putre- fadion, the entire plant, except the root, con- fcquently it confifts in a developement of their principles, in anew combination and arrangement of thefe fame principles ; hence refuks an aifem- blage of particles, infinitely fubtle, which being applyed to any fubjeft, refieft rays of light very different from thofe which they would have refleded, were the fame particles ftill joyned to thofe which had been feparated by fermentation. yinil, the other plant, cultivated in the Eaft and Weft-Indies, is prepared and fent to Eng- land under the name of Indigo. In the prepa- ration of this lad plant, the Indians and Ame- ricans, more induftrious than we are, have difcovered the art of feparating the colouring particles from thofe which are of no ufe ; and the French and SDanifh colonies, after their ex- ampJe, make it a confiderable article of com- merce. The Indigo imported from America, and which transfers its colouring particles, of fo •jBuch confequence in the Art of Dying, to the JTianufaclured ituffs or wool, is infufed in the fevcral ways defcribcd above. Thefe may be reduced to three: The infufion of the cold Indigo Var, ufed for Thread or Cotton; the hot Vats ufed DYING WOOL. 77 ufed for all kinds of ftuff. To the cold Vat is added, befides the Indigo, pearl allies, copperas, or green vitriol, lime, madder, and bran. The hot Vats are prepared with water or urine. If with water, you add fome pearl alh, and a little madder i if with urine, a little alum and tartar. Either of diefe Vats, defigned chiefly for woolens, require a moderate degree of heat, fufficient however to give the wool a permanent colour, that is to fay, as I have already obferved, a colour capable of refilling the dcftrudtive effefta of the air and fun, and of the trials enjoined; a detail of which may be feen in the new Infirm- tions of 1733. I have myfelf prepared, as I obferved, thefe three Vats in mi nature, in cylindrical glafs veflels, expofed to the light, in order to obferveT^ the efFeft before the infufion acquired colour, viz* before it became green under the fcum, or blue on the furface, which is a fign of interior fermentation. This green colour is, as I have already faid, abfolutely eflential to the liquor, and without which, the colour of the ftuff would entirely fade by the fmalleft trials. I will now defcribe the fmall cold Indigo Vat, becaufe in this the variations arc more eafily dif- cernable, and becaufe there is no very eflential difference between it and the two others. It is however neceflary, before I proceed to intimate Ihat by the word part, in this experimental memoire, I mean a meafure weighing four drachms, or half an ounce of any fubilance, whether liquid or folid, and that this is the quantity ^g THEARTOF quantity meant, as often as I make ufe of the term parts in the account of thefe experiments. I have put 300 parts water, in a veflel contain- ing five hundred and twelve of thefe parts, or two gallons, in which I diflblved fix parts of green copperas, which gave the liquor a yellow tinge. I then diflblved fix parts pot-afh, in thirty-fix parts water, feparatelyi when the folution was complete, I digefled, over a very flow fire, for three hours, Cix parts, or three ounces of Indigo of St. Domingo, well bruifed. It fwelled very much-, and rifing from the bottom of this alkaline liquor, formed a kind of fyrup, thick and blue, by which it appeared that the Indigo was only divided, not diflblved j for had the folution been perfedl, this thick liquor would have been green inftead of blue; becaufe all liquor, if coloured blue by any kind of vegetable, becomes green when mixed with an alkali, whether fixed or volatile. Hencewe begin to difcover why Indigo does not dye fluffs a permanent Blue when the li- quor is not green : for, in that cafe, the folution is not complete, and the alkali cannot a6t on the firfl: elementary particles, as, for inftance, it acts on thetincflure of violets, which, being a perfcdt folution of the colouringparticles of ihefe flowers, becomes inftantly green. I poured this thick Blue liquor into a folution of vitriol, and, having ftirred it well, added fix parts of lime, flaked in the air : this experiment was made in cold weather j the ther- mometer was two degrees below the freezing point ; hence this Vat was near four days in conping to its colour j but the fermentation, 5 which DYING WOOL. 79 which neceflarily takes place in all vitriolic liquors, mixed with an alkaline fair, fuch as pot- afh or an alkaline earth, went on fo flowly, that there was but very little appearance of froth, or air bubbles, on the furface of the liquor. In . a warm feafon, and by ufing lime, frefli cal- cined, thefe Vats are fometimes in a proper ftate for dying in the fpace of four hours. As often as this mixture was ftirred with the fpatula, I always remarked that what firit fell to the bottom of the veflel was the iron' of vitriol, or the copperas which had been precipi- tated by the alkaline fait uniting with the acid. Hence, in the operation of the cold Indigo Vat, a vitrioUted tartar is formed, in the man- ner of Techenius ; whereas in the common me- thod of preparing this neutral fait, an acid fpirit of vitriol is poured on a true alkaline fait, as fait of tartar, or pot-afh. This circumftance infenfibly leads to the theory of dying the good dye,! muft intreat the reader to bear this in mind, as I mean to avail myfelf of it in the fequel of this memoire. After the iron is precipitated, you perceive the earth of the lime fall to the bottom: this is eafily perceived by its whitenefs, which does not begin to change to a colour more difficult to diftinguilh, till the colouring particles of the Indigo are, in fome degree, developed.. At laft the dregs of the Indigo depofites on the top of this white earth, which gradually rarefies ia fuch a manner, that the fubftance, which, on the firft day occupies no more than an inch on the top of the precipitated lime, rifcs infenfibly within to THEARTOF within half an inch of the furfaceof the liquor, which, on the third day, becomes fo opaque that nothing more can be diftinguifhed. This rarefaftion of the Indigo, flow in cold weather and quick in fummer, and which in winter may be accelerated by giving it fifteen or eighteen degrees of heat,' is a proof that a real fermentation takes place in this mixture, by which the atoms of the Indigo are opened, and divided into particles of an extreme tenuity. Their furfaces being thus multiplyed, almoil: ad infinitum, they are thus more equally diftri- buted in the liquor, which is thereby rendered more capable of depofiting uniformly the colour- ing atoms, on the fubjed immerfed in order to be dyed. If this fermentation be accelerated by heat, you perceive on the furface of the liquor a great quantity of Blue froth, which has a copperous tinge, becaufe it refledts the colours of ihe rainbow, in which the red and the yellow pre- dominate: this phenomenon is not however pe- culiar to the Indigo, as all mixtures in the aft of fermentation, efpecially thofe which contain oily and faline particles have the fame appearance. Urine, fweat, and many other bodies, when in a fermenting ftate, produce thefe rainbow colours on their furface. The froth of the Indigo Vat appears Blue becaufe it is expofed to the exterior and conti- guous air J but, if you take a little of the liquor from under the froth with a ladle, it will appear more or lefs green in proportion as it is more or Icfs faturated with the colouring particles. Th(? DYING WOOL; 8i The rcafon of this difference will be fhewn in the fequel of this memoir, or at leaft a probable application of this Blue change, which, as I have before obferved, is abfolutely necefiary towards the fuccefs of the operation defcribed. When the Vat is in this ftate, as I have faid before, it is capable of dying cotton, thread, or linen, &c. and the colour taken by thefe bodies is durable, and goodi that is to fay, will keep their colour, though they lliould remain for a confiderable time in a boiling folution of foap fuds. This trial is preferable to all others, becaufe cottons and linens, when, dirty are whit- ened by foap. Though the Indigo Vat, when in this ftate, will dye well without the addition of any other fubftance, the Dyers, who are accuftomed to the cold Vat, add, as in warm Vats, a de- coftion of madder and bran, in common water, and ftrained through 'a fieve* This they call Sever, The madder is added, as they fay, to fix by its tenacity the colour of the Indigo. And the bran to fweeten the water, which, as they imagine, almofl: conftantly contains feme par- ticles of an acid fait, and which in their opinion it is necefTary to counteract, at leaft fuch are the fentiments of thofe whom I have confulted. This is the remains of the ancient prejudice againft Indigo which fubfifted in M. Colbert's - timej and this minifter, whofe great employ- ments prevented him from being a witnefs to the experiments upon which he pronounced judge- ment, prohibited the ufe of Indigo alone. Ne- verthelcfs, fincethe Council, convinced by the ex- G periment;^ 82 THEARTOF perlments of the late M. Dufay, has acknow- ledged the ftability of the Blue dye of this in- o-redient to be equal to their wifh, the new Regulation of 1737 has left the Dyers at liberty to ufe it either alone or mixed with the Paftel. Hence, though they ftill continue to ufe madder, it is only becaufe this root furnifhes rather a deep red, which, mixing with the In- digo, gives a fort of violet tinge, and has a better efFedl: to the eye. With regard to the bran, when ufed, it is not fo much to neutralife the fuppofed acid in the water, as to difFufe a certain quantity of mucilage, or vifcous fubftance; for the fmall quantity of farina, which remains in the liquor of the Vat, diminifhes in fome degree its too great fluidity, and confequently prevents the colouring particles, therein fufpended, from precipitating with fo much velocity as they would otherwife do in a liquor which had not acquired a certain degree of thicknefs. Notwithftandina; this gluten diffufed in the liquor, both from the bran and madder, which alfo furnifhes a glutinous fubftance, the colour- ing particles will fall to the bottom of the vcflel, if fuffered to remain for fome days without flirring. In this cafe the fubjedt dipped in the top of the liquor obtains but a faint tinges and therefore if you would have it take a proper colour, you muft again ftir the mixture, and then let it reft for an hour or two, till the iron of the copperas, and the grofs particles of the lime are, by their own weight, again precipitated; left in mixing with the real colouring particles, they DYING WOOL. .'% they Ihould injure their efFedl, by depofiting on the fubje6t to be dyed certain loofe particles, which in drying would render it powdry, and of which each atom A^ould occupy a fpacc, where the real colouring particle could neither be introduced, nor • depofited in immediate conta(5t with the fubjeft. Purfuing the common method, I boiled one fart of grape-madder and one pari of bran in a hundred and feventy four /)<3r/j of water. This proportion of water is not nccefTary; you may put more or lefsi but I filled my veflel, which contained five hundred and twelve pat'iSy as I have faid above. I drained this Bever through a linen, by expreffion, and then put it, ftill warm, and of a blood red, into the Indigo Vat J obfcrving the neceflary precaution, not to break the cryflal veflel in which it was contained. I flirted the whole, and at the expira- tion of two hours the liquor became green, confequently ready for ufe i and in efFeft it dyed cotton of a folid and more lively Blue than before the addition of the madder. Let us now enquire into the particular caufe of the folidity of this colour, which will pro- bably be the general caufe of the tenacity of all others, for it appears from the above mentioned trials, that this tenacity depends on the choice of the falts, added to the decodlions of the colouring ingredients, when the fame ingredients do not of themfelves contain fomething of the fame nature. If with the confequences Which I deduce from the choice of thefe falts,. of their nature and of G 2 their 94. THE ART OF their properties, we admit, what cannot juftly be objeded to, viz. the greater or lefs degree of tenuity, or homogenioufnefs, of the colouring particles of the ingredients ufed in the Art of Dying, the whole theory of this art will be foon underftood, without the ne- cefllty of fuppofing uncertain or difputable caufes. It may be eafily conceived, that the falts which are added to the Indigo Vat are as neccf- fary for opening the pores of the fubjeft to be dyed, as for developing the colouring atoms of this drug. In other preparations for dying, which fiiall be mentioned in the fequel of this treatife, the fluffs are boiled in a folution of falts, called by the Dyers preparation. In this they generally ufe tartar and alum. At the expiration of fome hours, the fluff is- taken out, lightly fqueezed, and kept moifl, in a cool place, during fome days, that the faline liquor may continue to aft, and pre- pare it to receive the colour of the ingre- dients, in a decoflion of which it is afterwards boiled. Without this preparation, we arc tAught by experience that the colours would not be folid, at leafl, in mofl cafes; it mufl be confefTcd, however, that there are fome in- gredients, which, though the fluffs are not previoufly prepared, give a permanent colour; but that is when the ingredients themfclves contain the preparatory falts. It is therefore ncceffary to enlarge and cleanfe the natural pores of the fibres of the wool, by the afTiflance of tbefe falts, which are in fome de- 2 grec DYING WOOL. 85 grec corrofiTe, and perhaps alfo to open frefli pores, in order to lodge the colouring atoms. Thefe atoms are forced into them by the ebullition of the liquor with repeated ftrokes. The pores, already enlarged by thefe falts, are ftill more dilated by che heat of the boling water, and afterwards contracted by the ex- ternal air, when the ftutf is taken out of the copper, when expofed to the air, or when plunged into cold water. If befides this elafticity of the fides of the pores, we fuppofe that their infides arc lined with a coat of the faline liquor, it is eafy to conceive, that this will be another artificial means of retaining the colouring atoms ; which having entered into the pores, whilft this faline lining was in a ftate of folution, confequently liquid, and this lining being afterwards con- gealed by the external cold, the atoms are re- tained both by the above mentioned elafticity, and by the lining; which, becoming hard by cryftalization, forms a kind of maftick. If moreover the coloured atom be of fuch tCr nuity, that the fmall eminence which remains apparent at the orifice of the pores, and without which the fubjedt would not have the appearance of being dyed, be not fo far elevated as to expofe it to Ihocks fufficiently powerful to overcome the refiftance of the fides, and of the gluten by which it is retained, we may conclude that the colour refulting from thefe atoms, thus properly confined, will be ex- tremely folid, and may be termed good d^e, G 3 provided 86 THEARTOF provided the faline gluten cannot be dcftroyed either by the heat of the fun or moifture of the air. We know of only two falts in chymiftry, which, being once cryftalized, will not diflblve in cold water j for there is fcarce any other fait but will be reduced into meal or white duft, by being for many days expofed to the fun. Xhefe falts are, tartar, either as it comes from the wine cafks or purifyed, and vitriolated tartar. All other falts want one of thefe two properties. Vitriolated tartar may be made by a mixture of any fait, the acid bafis of which is vitriolic, as copperas and alum, and a fait already alkalized, or which, when deprived of its acid, may become alkali, and which m.ay be eafily accomplifhed, provided it be weaker than the acid of vitriol} fuch as the acid of all efiential falts, procured from vege- tables. In the operation of the Blue Vat, which I •worked in miniature, in order to try its effeds, I mixed copperas and pot-aih, which is an alkaline fait ready prepared. As foon as their folutions became united, the iron of the copperas was- immediately precipitated into a blackilh powder by the alkali. The vitriolic acid of the copperas, having no longer a metallic bafis, unites with the alkali, and forms a neutral fait, called vitriolated tartar ; the fame as if it had been made with the oil of vitriol and fait of tartar. The theory of the above procefs is eafily underftoodj but, it is probably not fo with regard to the liquor required for other colours. DYING WOOL. 87 tolours, as red and yellow. It will not be allowed perhaps, that it is poffible to form vitriolated tartar with a mixture of alum and crude tartar boiled together. The theory is how- ever the fame, and 1 cannot fee how it is pof- fible to conceive it otherwife. Alum is a fait in which vitriolic acid is united to art earth: by adding to it an alkaline fait, this earth will be inftantly precipitated, and the vitriolated tartar immediately formed. Now,, inftead of this alkaline fait, you boil alum with crude tartar, which is the efiential fak of wine, viz. . a fait compofed of the acid of wine, which is much more volatile than vitri- olic acid, and an oil, both concentrated in a fmall portion of earth. This fait, as all Chymifts know, becomes an alkali when deprived of the acid. Hence, by boiling alum and crude tar- tar together, befides the. imprelfion which the fibres of the fluff to be dyed receive from the firft of thefe falts, in fome degree corrofive> the tartar is thereby purified ; and from being dirty and impure becomes clean and tranfpa- rent, by means of the earth, which is feparated from the alum, and which has on: the tartar, nearly the fame efi^edt as the earth of Merviels^ ufed at Montpelier in the manufaftory of cream of tartar. It may alfo happen, that the vitri- olic acid of the alum, expelling a part of the vegetable acid from the tartar, forms a vitriolated tartar, as hard and tranfparent as the cryflals of tartar. Letus admit on either fuppofition, the refult will always be, a faline coating in the open pores of the fibres of the wool j which as foon G4 as €8 THEARTOF as the fluff is taken out of the dye, and expofed to the frefh air, cryftalifes, but it neither calcines by the heat, nor difTolves in cold water i which is all I mean to demonftrate by this un- avoidable digreflion. This theory applies alfo to the Indigo Vat, where urine is added inftead of water^ and aJunn and crude tartar in the place of vi- triol and pot-afhes. With urine it cannot give a permanent colour but when it is very hot, and it is even neceflary to leave the wool im- merfed in it for an hour or two, if you would have it equally dyed. As foon as this Vat is again cold, it gives no more colour. The caufe of thefe fads would be difficult to dif- cover in an opaque metal Vatj but in a glafs veflcl may be eafily feen. I fuffered this little experimental Vat to grow cold, and all the green colour therein fufpended fell, by degrees, to the bottom of the veflelj becaufe then the tartar became cryftalizcd, and uniting in heavier maflcs, fell to the bottom, and drew along with it the colouring particles. When I gave this liquor its former degree of heat, ' ftirred it, and afterwards let it ftand a while, I put into it a little bit of cloth, which, at the ex- piration of an hour, was taken out as permanently dyed as at the firft time. Hence when this Vat is ufed, and that it is once in a proper (late, it requires no more than to keep the tartar dif^ folved, which muft be done by a pretty ftrong . heat. The alkali of the urine makes it green j the alum prepares the fibres of the wool ; and the cryftals of tartar confirm the colour, by cementing DYING WOOL. 89 cementing the colouring atoms dcpofited in the pores. There remains a difficulty with regard to the Indigo Vat, in which neither vitriol, alum, nor tartar, are introduced ; in which nothing more is put than pearl-afli, in equal quantity with the Indigo, and which is heated pretty ftrongly, in order to dye the woolen fluffs. Be- fore I can account for the foiidity of this colour, which is equal to any of thofe Blue Vats with the falts I have juft mentioned, it will be necef- fary to examine the pearl-aih. It is well known that pearl- alh is made from the lees of wine dryed, and then calcined. It is therefore an alkali of the fame nature of fait of tartar, but lefs pure, as it proceeds from the heavieft parts of the lees of wine, confequently the moft earthy, Befides the alkali of the pearl-alh is never fo homogeneous as the alkaline fait of tartar, well calcined, and there is fcarce any unpurified pearl-alh* fuch as is generally fold, from which you cannot obtain a confiderable quantity of vitriolated tartar. It is even probable, by an experiment which 1 have related elfewhere, that the whole may at laft be converted into this neutral fait : the fame may be faid with regard to pot-alh, and to all the alkaline falts, which do not contain the bafis of marine fait. The want of homoge- niety is the reafon why pearl-alh is never intirely dcliquefcent in the air, and befides, as we are taught by experience, that there is in pearl-afli a vitriolated tartar already formed, it is clear that this Indigo Vat, which does not dye wool well, tilj after the liquor has been heated fo hot that 90 THE ART OF that you cannot bear your hand in it for any time, without burning, witl diflblve the fnnall portion of vitriolated tartar ; confequently this fait in- troduces itfelf into the pores of the wool in order to cleanfe and coat them, and will coagulate as foon as the wool is taken out of the liquor and expofed to the air. I muft alfo explain, why the Indigo Vat is green under the firll furface of the liquor j why it is neceflary that the liquor ihould be green, in order to make the blue colour durable, and why {luffs, taken out of the Vat green, fhould become blue immediately upon being expofed to the air. Thefe circumftances being necef- farily common to all Indigo Vats, whether hot or cold, the fame explication will ferve for all. I ft. The froth or fkum which rifes on the furface of the Indigo Vat, when in a proper ftate for working, is blue, and underneath the froth the Vat is green. Thefe two circum- ftances prove that the Indigo is perfectly dif- folved, and that the alkaline fait is united to the colouring atoms of this ingredient, elfe inftead of being green it would remain blue. 2d. The fame circumftances prove that the Indigo itfelf contains a volatile alkali, which being developed by the fixed alkali of the pot- afti, or by the terreous alkali of the lime, eva- porates in a very little time after this froth has been expofed to the air. We may be convinced of theexiftence of this volatile fpirit, by attend- ing to the fmell of the Vat, during the time of fermentation i for when heated or ftirred, you DYING WOOL. 91 you will perceive a fmell, like that of tainted meat, in the a6t of roafting, with fomcthing pungent. 3d. The preparation of the Anilj in order to feparate the dregs, is a continued fermentation, even to putrefaflion. Now there is in all putrified plants an urinous volatile alkali j whe- ther this volatile alkali be produced by an inti- mate union of the falts with a vegetable oil, or whether it be owing to the prodigious multitude of infedls, which, being attra6led by the fmel], infeftthe fermenting plant in all parts: they live on them, multiply and dye, confcquently leave an infinite number of dead bodies; Hence there is an animal fubftance added to the vegetable, the fait of which animal fubftance is always a volatile alkali. The fame urinous quality alfo exifts in the Paftel, which is, in the fame manner, prepared by fermentation and putrefa6lion, as you will prefently perceive in the abridged account of its preparation. 4thly and laftly. If Indigo or Paftel be dif- tilled in a retort, whether alone, or, which is ftill better, with the addition of a fixed alkali, cither faline or terreous, you will thereby procure a liquor, which, in all chymical experiments, produces the efFecfl of the volatile fpirit of urine* But it will probably be afked, why this vola- latile alkali, exifting in the Indigo, does not make it green, being equally diftributed in every part? Why Indigo, diflblved in boil- ing water, turns it blue, and not green ? I an- fwer, that this volatile fpirit is fo concentrated that it requires an extraneous body, more pow- erful ^2. THEARTOF crful than that of boiling water, to difengagc it from the particles by which it is enveloped i That the folution of Indigo is never perfedly accomplillied by water alone, be it ever lb hot; that it is only difFufed, and not diiTolvedj that, in fad, the decoflion of Indigo will blue the fluffs i but that the Blue colour will be fo very unequally applied, that other boiling water will immediately wafh it out. Let me alfo beg leave to anfwer by an example deduced from another fubjeft. The fal-ammoniac, from which the chymifts obtain their moft penetrating volatile fpirit, has not, when diflolved and boiled in water, this ftrong urinous fmell: it is therefore neceflary to add either lime or a fixed alkaline fait, in order to difengage the volatile fpirit. Indigo, in the fame manner, requires fixed alka- lies, cither faline or terreous, to be completely decompofed, to render its volatile fpirit percep- tible, and to reduce its colouring atoms to their ■elementary teuity. I now proceed to the fecond condition, viz, that the liquor of the Indigo Vat Ihould necef- farily be green, in order to produce a perma- nent colour. For, as I have already faid, the Indigo would not be quite difTolved unlefs afled upon by an alkali, and, its folution not being fo perfeft as it ought, would dye neither equally nor folidly. As foon, therefore, as the alkaline fait adls upon it, it becomes green; becaufe all alkalies, when mixed with the juice or Blue dye of a plant, or of any fiower whatfoever, when equally diftributed through all its colour- ing particles, become inftantJy green. But, if by DYING WOOL. 93 by evaporation, thefe fame particles, either co- loured or colouring, be colledled into hard com- paa lumps, the alkali cannot change their colour until it has penetrated, divided, and reduced them to their original tenuity. This is the cafe with refpcft to Indigo, which is, properly fpeaking, the infpifiated juice of the A7. With regard to the third and lafl: condition, viz, that the (tuff, when taken out of the liquor, fhould be green, and being expofed to the air Ihould become blue, without which circumftance it would not be permanent, it may be accounted for in the following manner : it is taken out green becaufe the Vat is green ; if it were not green, the alkaline fait which had been put into the Vat would not be equally diflributed, or rather the Indigo would not be entirely diffolved. If the alkali had not been equally diflributed, the liquor of the Vat would not be equally faline. The bottom would have all the fait, and the top would be infipid: in which cafe, the fluff immerfed would neither be prepared to receive or retain the colour. But when, at the expira- tion of a quarter of an hour, it is taken out green, it is then evident that thejiquor is equally faline, and equally impregnated with the colour- ing atoms. It alfo proves that the alkaline fait was capable of penetrating into the pores of the fibres of the ftuff, and of enlarging them, or, as I have already remarked, of forming new ones. It is therefore obvious that an alkaline fait will produce this effed on woolen fluffs, if it be remembered that an alkaline lixivium, when very acrid, will burn and confume a lock of 94 THEARTOF of wool, or a bit of feather, alinoft inflantly. Of this the operation of dying, csWtdi fonte de bourrcy or a folution of cows hair, is another proof. The hair employed for this purpofe is boiled in a folution of pot-afh, with urine, in which folu- tion it is fo perfedlly diflblved, that not the leaft fibre remains. Therefore if a lixivium, ex- tremely acrid, will deftroy the wool, a lixivium containing no more alkaline fait than what is fufficient merely to make it a6t on the wool, without deftroying it, will prepare its pores to receive and preferve the colouring atoms of this ingredient, which is the objed of this diflertation. The fluff is opened, after being taken out of the Vat, and wrung or fqueezed; it then becomes Blue. What is done by opening it ? It is cooled. If it be the volatile alkali that is extricated from the Indigo which has given it this green colour, it evaporates, and the Blue appears. If a fixed alkali occadons this green, befides that the greateft part of it is difcharged by the ftrong expreflion of the ftuff, what re- mains can no longer a6l on the colouring par- ticles; becaufe the minute atom of the vitri- olated tartar, containing a colouring atom, ftill more minute, cryftalifes as foon as expofed to the cold air; and embracing thi$ colouring atom, by means of the elafticity of the fides of the pores, entirely prefles out all that could poffibly remain of the alkali, which does not cryftalize like a mineral fait. This Blue is enlivened, that is to fay, ren- dered more bright and beautiful, by immerfing the ftuff, which had been juft dyed, in hot water. DYING WOOL. 95 water, becaufe then the colouring atoms, which adhered to the fibres of the wool only fuper- ficially, are carried off. Soap is ufcd to try the folidity of the Blue dye, wliich it refifts, becaufe the foap, (of which only a fmall quantity is dif- folved in a large proportion of water, and the pattern remaining in it, for five minutes only, the time required) being an alkali, mitigated by an oil, cannot poflibly aft upon a neutral fait. If it difcharges any part of the colour, the parti- cles difcharged muft have adhered but fu- perficially. Befides the fmall faline cryftals, wedged into the pores, cannot be diffolved in fuch a manner as to quit them with the colouring atom. In this dilTertation, I have exhibited an effay of my method of treating the art of dying, different from what has been hitherto pradlifed. Philofophers, to whom it is fubmitted, would not be fatisfyed with a fimple narrative of expe- riments, were I not at the fame time to pre- fent them with a theory ®f their fuccefs. I fhall obferve the fame method with regard to the Reds and Yellows, which are alfo fimple colours j becaufe it is abfolutely neceffary to undeftand them, before we proceed to compound colours; as the laft are colours generally applied one upon the other, and feldom mixed together in the fame Vat. Hence, by being informed of what procures the tenacity of a fimple colour, we are enabled to judge more eafily, whether it be poffible for the atoms of the fecond colour to poffefs the vacant fpaces between thofe of the firft. On this principle I have formed my arrangement 5 of 96 THEARTOF of the different colours to be applied to the fame ftuff; becaufe I find it difficult to conceive even a poflibility that the colouring atoms, being depofited one upon another, Ihould thereby form a kind of pyramid, each prefer ving its colour, fo that, from a mixture of the whole, there Ihould refult a compound colour, appear- ing neverthelefs uniform, or rather homogene- ous. To believe this, we muft necefiarily fup- pofe, what it would be very difficult to demon- ftrate, that thefe atoms are tranfparent. Befides, that a yellow atom fhould be immediately applied on a blue atom, already enclofcd within the pore of the fibres of the fluff, in order to be permanently fixed, it is necelTary that their parts in conta6t fhould be extremely polilhed. That a red atom fhould afterwards be depofited on a yellow, we muft fuppofe new planes, no lefs accurate, and equally polillied, than the firft. Imagination can hardly give credit to all thefe fuppofitions ; but it appears to me, much more probable, that the firft colour occupied only the pores that were left open by the firft preparation of the fibres of the ftuffj thatclofe to the pores already filled there remains fpaces, not occupied, where new pores may be opened for the reception of the new atoms of a fecond colour, by the afTiftancc of a fecond preparation. What I have faid, in order to explain the method of condu6i:ing an Indigo Vat, will alfo ferve to fhew the action of the Paftel Vat on woolens and ftuffs: we need only fuppofe that the Paftel Vat naturally poffcfTes falts nearly of DYING WOOL. 97 of the fame nature with thofe which are added to the Indigo Vat. By the difcription which I have given of each of thefe Vats, it appears that the Paftel Vat is infinitely more difficult to condudl than the other. In my opinion, it may be rationally fuppofed, that all thefe difficulties might be removed by preparing the Ifatis in France, in the fame man- ner as the Anil is prepared in the Weft-Indies : we will therefore compare thefe two preparations. I Ihall tranfcribe the following quotation from the memoires of Mr. Adftruc, on the natural hiftory of Languedoc. Paris Cavalier, 1737, in4to. p. 330 and 331. ■ " The colours obtained from the Paftel, ac- cording to the Dyers, are faint and weak. While thofe obtained from the Indigo are bright and lively. It muft indeed be confefled, that this opinion is conformable to reafon. Iridio-o is a fine fubtle powder, confequently capable of pe- netrating the ftuffs, and thereby giving them i bright colour. Paftel, on the contrary, is a thick pafte, clogged With a quantity of earthy particles, by which the aftion and riiotion of the fubtle particles are impeded and, prevented from being efficacious. " The method of remedying this evil, is to prepare the Paftel in the fame manner as the Indigo, by which means you would give the colours, obtained from the Paftel, a brightnefs and vivacity equal to thofe obtained from the Indigo, without in the leaft diminiftiing the excellence and folidity which particularly recom- H mends ^ , TriE Art 6r mends thofe colours, in which the Paftel I's concerned. "I have already, continues Mr. Adftruc, made experiments, of what I now propofe, in minia- ture, and thefe experiments have been fuccefsful, not only in the preparation of the powder of the Paftel, but alfo in the ufe of this powder for dying. It depends upon thofe entrufted with the public weal, to caufe experiments of the fame nature to be made upon a larger fcalej if attended with the fuccefs to be expeded, it will be incumbent on them to encourage the cultivators of the Paftel to adopt this new method of preparation, and to regulate whatever encouragement they may think proper to give at the commencement, in fuch a manner as to fupport the expenccs incurred by this new prac- tice, till they are themfelves determined by the advantages refulting from it." I was ignorant that Mr. Adftruc was of my opinion when I firft propofed to try the Ame- rican method in Languedocj but having fince read his memoire, I was delighted to find that my ideas coincided with the opinion of this great man : as it fucceeded in miniature, it is pro- bable that a larger undertaking would be attended \yith equal fuccefs. With regard to the manufa6tory of the Paftel, I ftiall quote Mr. A.dftruc, whofe account will not, ^ think, be unacceptable in this work. " The peafants of Albigeoife are accuftomed to diftinguiih two different feeds of Paftel, the oneViolet, and the otherYellow. They prefer the Tiolet;! becaufe the leaves are fmooth and even, whereas bVlNGWOOL. 99 Vhereas the leaves of the other are hairy, and therefore lefs valuable, as the duft and fand ad- heres to them. This Paftel is called Pajielbourg^ or Bourdaigne. '' The Paftel fhootsout five or fix leaves, which, xvhile greeny are upright. They are about a foot long, and fix inches broad. They begin to ripen near Midfumnner : when ripe, they bend downwards and turn yellow. They are then cut, &c. The ground fliould be afterwards hoed, which fiiould be repeated after every cutting. *' It fiiould be cut a fecond tinaein July, if the iveather has been rainy. Wet or dry weather either accelerate or retard it for eight days. At the latter end of Auguft it fliould be reaped again. They make a fourth cutting the latter end of September, and about a week after All Saints they cut for the laft time. This interval being longer, it has more fi:rength than the others t at this crop they cut the neck of the plant, viz. the top of the root, whence the leaves proceed. The Paftel produced from this cutting is bad, and therefore prohibited by the regula- tions. " The Paftel is never reaped in wet or foggy -weather. It is neceflary that the weather be very fine, and the leaves dry. " At each crop the leaves are immediately con- veyed to the mill, and ground to a fine f>afte. This fhould be done immediately, becaufe the leaves, when heaped together, foon ferment .and rot, with an infupportable ftench. Thefe mills are fomething like rape mills. They H 2 confill 100 THE ART OF confift of a mill ftone, fixed on its edge, which goes round a perpendicular pivot, in a pretty- deep circular grove, in which the Paftel to be ground is depofited. Mr. Adftruc has given an engraving of this machine. " When the leaves are by this means reduced to a fine pafle, it is piled up in the galleries of the mill, or in the open air. When the paftc has been prefled with the feet and hands, it fhould be beaten, and fmoothed on the furface with a fhovel. This is called Paftel in piles. *^ The outfide forms a cruft, which becomes blackifh. When it begins to crack, it fhould be carefully fmoothed again, otherwife the air gets in, and produces little worms in the cre- vices by which the Paftel is fpoiled. " The heaps are opened at the expiration of fifteen days, broke with the hands, and mixed together, cruft and all j but the cruft is fome- times fo hard that it is neceflary to break it with a club. " The pafte is afterwards made into little round balls. In forming thefe balls, they fliould be well fqueezed, and afterwards given to another perfon, by whom they are molded into a wooden mold, again fqueezed and made ovali finally, they are given to a third perfon, who finiflie* them in a fmaller mold. " Thefe balls are laid upon hurdles, and ex- pofed to the fun, if the weather be fine j but if not, they are depofited over the mill. The Paftel, expofed for fome hours to the fun, grows black at the outfide, while that which is dryed in the fhade, is generally yellow, particularly if the DYING WOOL. lot die weather be rainy. The firft is preferred by the merchants; it is nevertlielefs aflerted that there is not much difference: it even frequently happens that the Paftel is all yellow, becaufe the peafants, by whom it is made, generally work at it in rainy weather, when they can do nothing elfe. " The balls in fummer are generally dried in about fifteen or twenty days; but in autumn, the Paftel of the latter crop is a long while drying. It dries much fafter with a fouth-eaft: wind. " The beft balls are diftinguiihed from the- others by being, when broken, of a violet colour at the infide j the bad ones, on the con- trary, have a bad fmell, and an earthy colour; the confequence of having been cut in rainy "weather when the leaves were covered with' earth. You may alfo judge of their goodnefs by their weight, as the fubftance, not being well fqueezed, evaporates and becomes rotten, con- fequently lighter. " The powder of Paftel is made of thefc balls. The operation is performed in the follow- ing manner, and requires, at leaft, a hundred thoufand balls : you fhould have a detached barn, and a magazine, greater or lefs, accord- ing to the quantity of the Paftel. This maga- zine fhould be on a floor paved with bricks, ;jnd lined with the fame four or five feet high. It were advifablc to have the outfide walls ftone, of the fame height. " It is however frequently thought fufficient ^0 h^ve them plaiftered at the infide with earth ; H 3 bm; lot THEARTOF but this plaifter comes off and mixes with the Paftel, which is thereby impaired and fpoilt. The balls are brought into this magazine, where they are broken into grols powder, with wooden mallets. The powder is then heaped, near the middle of the magazine, about four feet high, leaving a fpace for the conveniency of going round it : it is wet with water, pond water is the beft provided it be clear. [7 fee no reafon why pond water ^ however clear ^ Jhould be -preferred to clear river water, which would be much morejafe, being exempt from the inconveniences neceffarily attend- ing putrid water ^ fuch as a confiant bad fmell, being muddy, and containing a quantity of v.felefs earth, which mufi render the dying with this drug very unequal.'] The Paftel thus moiftened, fer- ments, grows hot, fumes, and emits a very offenfive fmell. " The Paftel is ftirred every day for twelve days, fnoveling it from one fide of the magazine to the other, and wetting it every day during that time, after which it is wet no more: it is then fufficient to ftir it only every two days, and afterwards every three, four, and then five days. Finally, it is heaped in the middle of the maga- zine, and from time to time vifited, in order to give it air in cafe it Ihculd heat. This is ■ the powder of Paftel as prepared for the Dyers." Mr. Adftruc> in order to prove that Upper X-.anguedoc was enriched by the Paftel trade, quotes the following pafi^age from a book enti- tled, Le Marchand: " It was formerly the cuf- tom to tranfport every year into Touloufe and Bourdeaux, by the river Garonne, a hun- dred DYING WOOL. 103 dred thoufand bales of Paftel, which, in that country, fold for at lead fifteen livres a bale. This, amounting to one million five hundred thoufand livres, produced abundance of money and riches in that country/' So fays Caftel, author of the book above cited, in the year 1633, Memoir es de le Hijioire dii Languedocj page 4 9. The comparifon of the two methods of pre- paring the Paftel and Indigo will be fuffici- ent to any intelligent perfon, commilTioned to try the pofTibiiity of producing an extraft from the Jfaiis of Languedoc, refembling that of the Jjiil. We muft not expedt this from cither the Dyer or manufadlurcr. They will at once condemn the projeft, becaufe newj and I queftion much whether they would be capa- ble of properly conducing a fermentation, I could wifh to have this experiment tried on a Jarge fcale, fo as to have at leaft fifty pounds of this extraft, that feveral Vats may be fet in cafe the firft Ihould fail. The perfon chofen for this experiment fhould be very accurate in his de- fcription of every circumftance relative to the operation. He would perhaps fail in the leaves that were firft reaped, becaufe in June they have not fufficient heat, but, in the month of Auguft, he would in all probability fucceed. By letters which I received from Mr. Roman the younger, engineer -general at Dominica, I learn, that during the hotteft feafon in the ifland of Martinico, the thermometer rifes from thirty to thirty-fix degrees of Mr. Raumur's fcale. That in Languedoc it rofe from twenty- feven to thirty- two and thirty- three^ the heat H 4 ci ,04 THEARTOF of the human bodyj a heat fufficient to produce the fermentation of the Paftel leaves, which fhould be fleeped and macerated in the fame manner as the Anilj in a large Vat built of flone. The fermentation will perhaps require no more than thirty or forty hours. It may be accele- rated by throwing three or four cauldrons of warm water into the Vat. The perfon entrufted with this experiment Ihould procure leaves as little withered as pofiible, which perhaps ought to be flightly bruifed. For the firft experiments he fhould have Vats con- ftrufled of mafonry, a third of the fize of thofe the dimenfions of which were given by P. Labat. But the v/hole of the procefs being perfeftly defcribed in his memoires, there remains only to follow his inftruflions. If this experi- ment fhould fucceed, it is probable that there are many other plants, of the fame nature of the J[fc:tisy which would produce the fame extrad. The deep green of many plants is pro- bably compofed of yellow, and a large pro- portion of blue particles. If the yellow particles be deltroyed by fermentation, the blue will flill remain. This idea is not perhaps abfolutely fhimerical, nor would it be difficult to prove that fome utility may be drawn from it. C H A P^ PYING WOOL. 105 CHAP. XI, Of Red, RED, as I have already mentioned, is ac- knowledged by the Dyers as one of the five prinnitive colours. There are in the great ^ye, four different forts of Redsj which are the bafis of alj the feft. There are, firfl. Scarlet in Grain, formerly called French Scarlet, now Venetian Scarlet. Secondly, the Scarlet at prefent in ufe, or Fire Colour Scarlet, formerly Dutch Scarlet, and at prefent univerfally known by the name of Gohlin Scarlet, Thirdly, Crim- Jon I and fourthly. Madder Red. There are alfo half Scarlet Sy and half Crimfom; but thefe are mixtures of other Reds, and therefore Ihould not be confidered as particular colours. The Red, or Nacaret de Boiirre, was formerly allowed to be of the good dyej but, on ac- count of its want of folidity, it was baniflied by the new regulations. It is natural to fup- pofe, that each of thefe different Reds have their particular fliades, but it does not there- fore follow, that they fhould not be confidered as of different clalfes, becaufe the Ihades of each are perfectly diflinft. Reds are, in one particular, efTentially dif- ferent from blues, as I have obferved in the preceding chapter ; becaufe Reds require a pre- vious preparation. This preparation, as I have before mentioned, is called the bouillon. It is generally compofed of acids, as four water, • alum. io6 THE ART OF alum, tartar, aqua-fortisj aqua-regis, &:c. Thcfc preparations are added in different quantities, according to the fhade and colour required. Nut-galls are alfo frequently uied, and fome- times alkaline falts. This I fhall explain in the fequel, when defcribing the manner of work* ing each of thefe colours. CHAP, XIL Of Scarlet in Grainy or Venetian Scarlet, THIS colour is called Scarlet in Grain, becaufe d)'«d with kernr.es, long fup- pofed to be the feed of the tree on which it was found. It was formerly called French Scarlet, becaufe, a^ fome people imagine, it was found in France j but it is at prefent known by the name of Venetian Scarlet, being very much ufcd in that country. It has indee4 lels fire, and is darker than the fcarlets at pre- fent in failiionj but it has the advantage of being more permanent, and is not fo eafily fpotted. The kermes of which it is made is a gall* infect,' which grows, lives, and multiplies on the Ilex acculeala cocci glandifera^ C. B. P. It it is found in the Garrigues in the environs of Vauvert, of Vandemian, and of Narbonne; but in Spain, on the coaft of Alicant, and Va- lencia, in much greater quantities. As foon as it is gathered every year, the peafants of Languedoc. bring it to Montpelier and Nar- bonne^ D-YING WOOL. 107 bonne, where they fell it. Thofe who buy It for exportation, fpread it on tiles, and in order to kill the infed which it contains, and which produces a red powder, they fprinkle it with vinegar. This powder is firft dryed, and then feparated from the (hell by means of a fieve. The whole is made into large bales, and in the centre of eachof thefe bales, they put a certain proportion of the red powder in a leather bag, fo that every purchafer may have a part. Thefe bales are generally fent to Marfeilles, from whence they are conveyed to the Levant, par- ticularly to Algiers and Tunis, where this in-^ gredient is very much ufed. The red drapery of the figures in the ancient tapeftry of Bruxelles, and other manu- fafturing parts of Flanders, is dyed with iti and the colour, though two hundred years old, has fcarce loft any of its vivacity. This in- gredient is fcarce ever employed but for the wcrfted intended for tapeftry, and is ufed in the following manner. The wool fhould be firft drenched, for which purpofe you put half a buftiel of bran into a copper, with a quantity of water fuf- ficient for twenty pounds of wool, which to the beft of my knowledge is the ufual batch for one dying. In this liquor it fhould boil for half an hour, ftirring it from time to time j after which it is taken out and drained. I fliall obferve, once for all, that, when you dye worfted, you put a rod through each ikein, which commonly weighs about a pound, find which Ihould be kept on the rod during the io8 THE ART OF the whole procefs, by which means the llcein is prevented from tangling. It is alfo convenient for turning the fkein, in order to dip each part, that the whole may be equally coloured ; for which purpofe, you raife it about half way out of the liquor, and holding the rod with one hand, you pull the fkein with the other fo as to let the part, which before was next the rod, fall into the liquor. If the worfted fhould be too hot for the fingers, it may be done by means of another rod. The equality of the colour depends fo entirely upon the fre- quency of this manoeuvre, that it cannot be too ftrenuoufly urged. In order to drain them^ you reft the ends of the rods, juft mentioned, on two poles 5 which, as I have already faid, (hould be fixed in the wall over the copper. While the worfted is draining, after being thus drenched, you prepare a frefli liquor, viz, by throwing out what remained in the copper, and repleniftiing with frefti waterj to this you add about a fifth part four water, four pounds of Roman alum, grofsly pounded, and two pounds of red tartar. As foon as it boils, the worfted on the rods fhould be immerfed for two hours, almoft continually moving the rods, one after another, as I have before diredbed. It is neceflary to obferve, that ^fter the alum is put in, when the liquor is ready to boil, it will fometimes rife fuddenly out of the copper, if you do not mind to check the boil- ing by throwing in cold water. If, when it is ready to boil, you put in the cold worfted quickly, it will have the fame effeft. It is alfo DYING WOOL. rsf fiflfo proper to obferve, that when dyers work In the great they fliould havetheir legs bare, that the hot liquor, may not reft in the ftockings. When the quantity of tartar is rather confiderable, as in the prefent operation, the liquor does not rife fo high ; but when there is nothing befides the alum, it fometimes, when it begins to boil, half of the liquor boils over, unlefs prevented by the above precautions. When the worfted has boiled in this liquor for two hours, drained, lightly fqueezed, and put into a linen bag, it is depofited in a cool place for five or fix days, and fometimes longer ; this is called leaving the worjied in the preparation. This delay helps it to pene- trate, and increafes the adion of the faltsj for, as a part of the liquor conftantly evaporates, it is clear that what remains, being more im- pregnated with the faline particles, becomes more adlive, that is to fay, provided there remains a fufficient degree of moilture i for the falts being once cryftalized and dry, their power is deftroyed. I am much more explicit concerning this preparation^ and the manner of making it, than I lliall be hereafter; becaufe for many colours the quantities are pretty nearly the fame. Hence I fhall content myfelf in future with mentioning it flightly, obferving only the different quantities of alum, tartar, four water, or other ingredients. When the worfteds have remained in this ftate for five or fix days, they are then in a proper condition ii6 THE ART OP condition for being dyed. A frefh Ilquof is then prepared, according to the quantity of the worfted, and when it grows warm> if you want a full fcarlet, you throw into it twelve ounces of pounded kermcs to every pound of worfted J but, if the kermes be ftale, it will require pound for pound. When the liquor begins to boil, the worfted fhould be put in, being ftill moift; but, if it has been fuffered to grow dry after boiling, it fhould be put into warm water, and well drained. Before you put the wool into the copper with the kermes, it were advifable to throw in a fmallhandful of refufewool,which, being boiled for a moment, imbibes a part of the black* nefs and drofs of the kermes, fo that the wool, afterwards dyed, takes a much more beautiful colour. You now dip the flceins on the rods in the fame manner as in the preparation, continually ftirring them, and giving them air, from time to time, one after another. In this manner they fhould be kept boiling for a full hour. They are then wafhed and drained. If you would reap any advantage from the dye ftill remaining in the liquor, you may dip a little prepared wool, which will take a colour in proportion to the goodnefs of the kermes, and to the quantity which had been put into the copper. If you mean to dye a number of lliades, one darker than another, you require much lefs of th^ kermes J feven or eight pounds being fuf- ficient D Y I N G W O O L. Til ficlent for twenty pounds of prepared wool. You then dip the quantity of worfted intended for the lighted fhade, leaving it in the copper no longer than neceffary, in order to turn it, that it may imbibe the colour equally. It is then raifcd upon the pegs, and the next fhade immediately put in, and fufFered to remain for a longer time. You proceed in this manner to the laft Ihade, which fhould alfo remain till it has acquired the colour you defire. You begin with the lighteft colour, becaufe if the wool was fuffered to renaain in the cop- per longer than neceffary, it would be no lofs, provided you referve this batch for the darker Ihade: whereas by beginning with the darkeft you would have no remedy in cafe of any acci- dental fl-iip in the light Ihades. The fame pre- caution is neceffary in regular fhades of all colours; but of the colour in queftion thefe arc fcldom made ; becaufe the dark fhades arc not much in ufe: and as the operation for all colours is the fame alike, what I have faid refpedling this will anfwer for all the reft. When the wool has been dyed in this manner, and before it is carried to the river, you may fwill it in warm water, with a fmall quantity of foap, well diffolved j this adds a brightnefs to the colour; but, at the fame time, gives it a little of the ro/e, that is to fay, a crimfon tinft. As I fhall in the fequel of this treatife, efpecially when fpeaking of reds, frequently make ufe of the terms ro/er or crimfoned, and avlvfr, or brightened. Ill THEARTOF brightened, it is proper to explain what I mean by thefe words. Rofer, crimfoned, as I have juil faidj is to give to red a crimfon tindti that is, rather a violet caft; Soap and alkaline falts, fuch as lixivium of pot-afli, lime, &c. crimfons the reds in fuch a manner, that thus you may give them, when too bright, what fhade you pleafe. Avivery to brighten, is quite a different pro- cefs. It is effefted by means of acids^ fuch as red and white tartar, cream of tartar, vine- gar, lemon juice, or aqua-forcis. More qr lel^ of thefe acids are ufed, according as you Would have the colour more or lefs brightened. If, for example, in the prefent cafe, you would give Scarlet in Grain a flame colour, or make it more like common fcarlet, it requires only to thro\^ into the liquor, after the kermes have boiled, a little of the fcarlet compofition which fhall be mentioned hereafter. The dark colour of the liquor is immediately brighted by the acid, and becomes more lively: the wool dyed in it has more of the orange) but, at the fame time, is more liable to fpot. The caufe of which will be feen in the chapter on the Scarlet of Gob- lins. In order to render this colour more bright and beautiful than common, I have tryed a great number of experiments, but could not Tobtain a red equal to that produced by co- chineal. Of all the liquors for the prepa- ration of wool, that which fucceeded the beft was made according to the proportions I have mentioned. By changing the natural tinge of the DYING WOOL. 113 the kermes, by various kinds of ingredients, metallic folutions, &c. various colours may be obtained, which I fliall prefently mention. One word only concerning the dying of fluffs the abovementioned red; for it is impoffible to prefcribe any proportions for an ell of fluff, confidering the infinitive variety of their breadth, and even of their thicknefs, and the quantity of wool in their fabrication; experience is the beft guide. NeVerthelefs, if you chufe to be exafl, the furefl way is to weigh the flufr to be dyed, and to diminiHi about one quarter of the colouring ingredients prefcribed for worfleds ; becaUfe the fluffs take internally lefs colour, as their texture, being d^cr, prevents it from penetrating; whereas the, worfled or woolen fleece takes the colour iniernally, as eafily as on the exterior furface. | The alum and tartar, ufcm in the preparation for fluffs, fho^id ^9 be diminifhed in the fame pro- portion; neitlierV it neceffary to let the fluffs remain in the pT*£par^ion as long as the worfted : They may be dyede^i^ the day after they had been boiled. Woolen fleece dyed in\the red of kermes, and to be afterwards incor^rated in mixed cloth, or for the manufactory of thick cloths, will have a much finer effe(5l than if dyed with madder. I fliall fpeak of this in the defcription of colours in which kermes are ufed, or, at leafl, where it ought to be preferred to madder, which is nothing like fo beautiful, but which being much cheaper, is almofl univerfally ufed. I ' A mixture 11+ THE ART OF A mixture of half kermes, and half madder, is called Scarlet in half-grain. This mixture gives a colour extremely permanent ; but not fo lively, inclining rather to a blood colour. It is prepared and worked precifely in the fame manner as if kermes alone were ufed ; only that in the liquor they put but half this grain, the other half is fupplied by miadder. This is confequently much cheaper, and it frequently happens that the dyers, who make it, render it much lefs beautiful than it might be, by di- minifl^ing the quantity of the kermes and in- creafing that of the madder. From the tryals made on Scarlet in Grain, or Scarlet of kermes, both bv exoofinor it to the fun, and by various liquors, it is proved that there does not exift a better, nor a more lading colour. It may for folidity be com- pared to the blues already mentioned. Never- thelefs, the kermes is fcarce ever ufed except at Venice i for fmce the fiery fcarlets are be- come the tafte, this colour is almoft intireiy exploded. It has, notwithftanding, many advan- tages over the other, as it neither blackens nor fpots, {o that fliould the ftuff get greafed, the fpot may be taken out without impairing the colour. Neverthelefs kermes is fo little known to the dyers, that when I wanted a certain quan- tity for the above experiments, I was obliged to have it frorn Languedoc i the merchants of Paris encumber themfelves witii no more tiian what they vend for the ufe of medicine. When a dyer is obliged to dye a piece of cloth of the colour called Scarlet in Grain, as he neither DYING WOOL. 115 neither knows what kermes are, nor how to ufe them, he does it with Cochineal; as I fliall ex- plain in the following chapter. This is much more expenfive, and lefs permanent, than that obtained from the Kennes. Worfted, defigned for tapeftry, is coloured in the fame manner; but as this colour is rather difficult to hit with the cochineal, they frequently mix it with brafil wood J an ingredient hitherto confidered as falfe, and permitted only in colours not in grain. Thefe colours confequently fade in a very fhorc time, and though they may at firft appear ever fo lively, they frequently lofe all their brightncfs in lefs than a year. It were therefore much to be wifhed, that the ufe of kermes were re-efla- bliflied. Any dyer, by adopting its ufe, would certainly obtain many colours with more eafe and lefs expence. Befides, his colours being much better, and more durable, he would in all probability eflablifh a much graater repu- tation. I have with the kermes made fifty experiments, which may be ufeful in pra6lice; but (hall mention thofe only which produced the mod remarkable colours. From kermes with cream of tartar, without alum, and with as much of the compofition as is ufed for cochineal fear- let, you obtain in a fingle Vat a very bright cinnamon colour; for this mixture containing acids only, the red particles of the kermes are fo attenuated as to be almoft invifible. But were this cinnamon to be dipped in a folution of Roman alum, the red would in part re-appear, whether, becaufe the addition of the alum had expelled a part of the acid of the com- I 2 pofition. fi6 THEARTOF pofition, or whether the earth of the alum, being precipitated by the aftringency of the kermes, whofe effeft is fimilar to that of galls, re-unites the red particles, before difperfed, and with them adheres to the wool. Be it as it may, the red by this naeans recovered is not fine. With cream of tartar, the compofition for Scarlet, and a greater quantity of alum than tartar, kermes gives a lilac colour, varying according to the proportion of thefe ingre- dients. If inftead of alum and tartar you fubftitutc vitriolated tartar, which is a hard fait pro- duced by a mixture of the acid of vitriol, and a fixed alkali, fuch as oil of tartar, and lixivium of pot-afb, &c. and having the kermes boiled in the folution of a fmall quantity of this fait, the ftuff be immerfed, and fufi^ered to boil for one hour, you obtain an agat grey colour, tolerably fine, with a reddifh caftj for the acid of the compofition having too much divided the red of the kermes, and the vitriolated tartar not containing the earth of alum, it could not in precipitating colled^ the red atoms which had been difperfed. But this agat grey is permanent, for as I have faid in the chapter on Indigo, vitriolated tartar is a hard fait which will neither calcine in the fun, nor be diflfolved by rain. Glauber falts intirely deftroys the red of the kermes, and produces an earthy grey, unable to withftand the trials, becaufe this fait neither refills DYING WOOL. 117 refifts cold water, nor the power of the fun, by which it is reduced to powder. Green or blue vitriol, feparately fubftituted inflead of alum, but employed with cryftal of tartar, deftroys in like manner the red colour of kermes, which in thcfe two experiments pro- duces the fame effefl, as it would with nut- galls ox Jmnach j becaufe it precipitates the iron of the green vitriol, which gives the cloth a brownilh grey, and the copper of the blue vitriol, which gives an olive tinge. Concerning blue vitriol, I lubilitute a folution of copper in aciua-fortis ; this alfo produces an olive colour, a certain fign that kermes poflefs the precipitating quality of galls. Why the red of kermes is as permanent as that of madder, is probably becaufe this infeft being nourifhed on an aftringent fhrub, the juice of this plant has notwithftanding the alteration which digeftion in the ftomaeh of the infed may have produced, prefervcd its aflrin- gency, and confequently the power of giving greater elafticity to the pores of the wool, in order to make them contract more fpeedily and vigorously when taken out of the boilincr water, and expofed to the cold: For I have ob- ferved that all the barks, roots, woods, fruits, and other fubftances, pofTefTing an aftringent quality, give a permanent colour. The white vitriol of Collar, whofc bafis is zinc, as mentioned in my Memoir on this femi-metal, of the year 1735, being employed with cryftals of tartar, changes the red of the Jicrrnes to violet. Thus, with a fingle colouring I 3 drug, ii8 THE ART OF drug, and a fimple alterant, violet colours may be produced without previoufly giving them a bafis of blue. For this compound colour, or confidered as fuch (becaufe hitherto impofTible to beprocuredwithout the application of blue on red, or red on blue) fucceeds alfo with cochineal, or even with madder, as will appear when I mention thefe two colours. As white vitriol is procured from a mineral containing lead, arfenic, and various other fubftances, whofe recrements being fufed with fand, and alkaline falts, is vitrifyed into a blue mafs, called Sapphire; I fufpe(fled that the white vitriol might contain a portion of this blue, which changed the red of kermes to violet, and that confequently the bifmuth iTiineraljwhich really contains this blue fubftance, and the bifmuth itfelf, would produce an effect fimilar to that of the white vitriol. It will pre- fently appear that I was notmiflakenin myconjec- t'.5re; for having thrown fome of the extraftion of the bifmuth-mineral on the experimental liquor, which I made with kermes, and a folution of bifmuth itfelf, into another deco6lion of the fame ingredient, they each of them dyed white cloth a violet colour. I fhall not in this place give the method of making an extradlion from the ore of bifmuth, for befides that it is an operation, rather difficult for a dyer, this ore is not found in France. It muft be imported from Mifnia, where they do not part with it fo eafily. Neverthclefs, fhould the reader be curious to know what I mean by an extraction of the ore of bifmuth, he will find the procefs in the Memoirs of the Academv of Sciences for the DYING WOOL. '. ^^ the year 1737, in which there is a paper of mine on fympathetic inks. With regard to the folution of bifmuth, which produces nearly the fame etfe(5t, I make it in the following man- ner. I take four parts of the fpirit of Nitre, and four parts pure water, mixed together, in which I diflblved one part bifmuth, which I break into fmall pieces, in order to put them into the liquor by degrees, left they fhould produce too violent a fermentation. Whenever there is too great a quantity of acid added to the liquor of kermes, be it fpirit of vitriol, fpirit of nitre, or aqua-foriiSy vinegar, lemon juice, or even four water, it {o perfectly divides the colouring red particles, that the cloth acquires only a cinnamon colour, with an aurora caft, if there be much acid, and iF there be lefs acid, the colour is rather more red. Fixed alkalies, with the addition of four water and cream of tartar, inftead of alum, do not like acids deftroy the red of kermes j but if the quan- tities be too great, they deepen and foil in fuch a manner, that the cloth obtains only a tarnifhed lilac colour. From other experiments ftill more varied, I procured an infinity of colours, but as there appeared none finer than thofe pro- duced by ingredients much lefs expenfive than the kermes, I thought *a relation of them needlefs, as it would only extend this treatife to an unnecefTary length. I 4 C H A P. t : THE ART. OF CHAP. xni. Of Fire Scarlet, FIRE Scarlet, formerly known by the name of Dutch Scarlet, and at prefent called Scarlet of Gobelins, the difcovery of which Kunckel attributed to Kufler, a German chymifl:, is the fined and brio-hteft colour in the Art of Dying. It is alfo the moft expenfive, and one pi the moft difficult to bring to perfection. It is indeed fcarce poffible to determine what is the flandard of perfeftion; becaufe, independent of the different talles, by which mankind are divided in their choice concerning colours^ there is be- fides a general tafte, which makes fome colours fafhionablc at one time more than another. It is falhion, therefore, Vv'hich conftitutes the per- ♦ feftion of colours. Formerly, for inflance^ deep unglaring Scarlccs were generally preferred. The fafhionable Scarlet at prefent is tinged ^ith orange, is fiery, and dazzling. I (hall not^, at prefent, decide which is the preferable taftej but fliall defcribe the method of obtaining both thefe colours, with their intermediate fhades. (Cochineal, which produces this beautiful co- lour, and which is called Mejiique^ or T'ejcakj is an infect, gathered in confiderable quantity in Mexico. They are cultivated by the natives of the coun- try^ that is to fay, they are gathered from the plant, by which they are nourifhed, before the rainy feafon. Thofe defigned for fale are killed and drycd, and the reft are kept in order to multiply DYING WOOL. 121 fn.u!tiply when the bad feafon is over. This in- fed: lives and multiplies on a fpecies of fpinou? Opuntia, called Tppal. They may be preferved in a dry place, for many ages without fpoiling. I have a Imall quantity from Amfterdam un- doubtedly ijo years oldj they are, neverthelefs, as entirely perfed, as if they had but juft arrivecj from Vera Cruz, and produce the fame cffed in dying as the frelli cochineal. The cochineal of Syh'jcftre or Cum-pejfiane, 15 alfo imported into Europe from Vera- Cruz. The Indians gather it in the woods of Old and Nev/ Mexico. The infed lives, grows, and multi- plies, on the uncultivated Opuntias, which grows there in great abundance. It is there .expofed to all the inclemencies of the rainy feafon, and dies naturally. This cochineal i$ much fmaller than the cultivated cochineal, and its colour more durable, though lefs bright: but there is no advantage in ufing it, for though it is cheaper, a greater quantity is required. Damaged cochineal is fometimes fold at Cadiz, either fhipwrecked, or, by fome mifchance, wee with fea water. This fort of accidents confide- rably leflens the price j for as the tinge of the cochineal is fometimes crimfoned by the fea water, it can only be ufed for purples, which are not of the fineft. There was, however, in the year 1735, a perfon who poflefTed a fecret of turning it to as much advantage, even for Scarlet, as the fined cochineal. The difcovery of this fecret would not be very difficult; we >vill not, however, by making it publick, deprive him J22 THE ART OF him of his cxpcfted reward, at a time too when perhaps it may be neceflary. There is fcarce a Dyer who has not a par- ticular receipt for Scarlet, and each of them is prejudiced in favour of his own method. His fuccefs, notwithftanding, depends on the choice of the cochineal, the water ufed for dying, and the manner of preparing the folution of tin, called by the Dyers, the compofitlon for Scarlet. As it is this compofition which gives a fine bright fire colour to the cochineal, which without the addition of this acid folution would be crim- fon, I Ihall, from my own experience, give the beft method of making this compofition. I take eight ounces of fpirit of nitre and weaken it by adding eight ounces of river water; I then difiblve, by degrees, half an ounce of fal-am- moniac, very white, in order to make an aqua- regis3 for it is well known that the fpirit of nitre alone is not a proper menftruum for tin. Laftly, I add only two drachms of faltpetre of the third drying; this might be omitted, but I am per- fuaded that it contributes to blend the colour, and make it more uniform. In this weak aqua- regis I diflblve an ounce of Englifii tin, previ- oufly made into grains, by dropping it, when melted, from a certain height, into a bafon of cold water. Thefe grains I drop into the folution one after another, waiting till the firfl: is diflblved before I put in a fecond, in order to preferve the red vapours which rifes in a great quantity, and which would be loft were the metal to be diflblved too precipitately. It is neceflary to preferve this vapour, which, as Kunckel obferved in his time, contributed D Y I N G W O O L. 125 contributed to the vivacity of the colour. This is doubtlefs a much more tedious method than that ufed by the Dyers, who throw their aqua- fortis immediately on the tin grains, and who, when it produces a rapid fermentation, and a quantity of vapour, allay it with cold water. When my tin is thus gradually diflblved, the Scarlet compofition is complete, and the liquor of the colour of a folution of gold. I ufe the fineft tin, without alloy, fuch as the firft produc- tion of the furnaces at Cornwall j confequently there is neither dud or black fediment at the bottom. This folution of tin, though fo very tranfparent when juft made, becomes milky in the violent fummer heats. The Dyers are almoft generally of opinion that it is then turned, and no longer good. I found, however, that this apparent defed made no difference. Befides, in cold weather it refumes its former tranfpa- rency, provided-it be prepared with the feveral precautions which I have juft dire6ted. I muft likewifc add, that it fhould be prefcrved in flafl^s well (topped with glafs ftoppers to prevent the volatile parts from evaporating. The Dyers compofition, for want of this at- tention, is frequently of no ufe in twelve or fifteen days. I give them the beft method, and if they expect perfecftion they muft alter their prefent defective method. The Dyers have a ftone veflcl with a wide mouth, in which they put two pounds of fal-am- moniac, two ounces of faltpetre refined, and two pounds of tin granulated in water: they put into a feparate velTel four pints of water, half a 4 pint M4 THEARTOF pint of which they throw on the mixture in the ilone vefTd. They afterwards add a pound and half of common aqua-fortis, which produces a violent fermentation ; when the ebullition ceafes they add as much more aqua-fortis, and imme- diately afterwards another pound. After this they pour on it the remainder of the four pints of water. They cover the veflel well, and let it ftand till the next day. The faltpetre and fal- ammoniac may be diffolved in aqua-fortis before the tin is added ; but this they fay is the fame thing, though it is very certain that the lad is the befc method. Others mix the water and aqua-fortis together, which mixture they throw on the tin and fal-ammoniac. Others, in fhort, obferve different proportions. The day after preparing this compofition they make the preparaticn for Scarlet, not in the leaft refembling that mentioned in the preceding chap- ter. As for eijample, for one pound of worfted they put into a fmall copper ten gallons of clear river water. When the water is a little more than \^'arm, they add two ounces of cream of tartar in fine powder, and a drachm ^nd half of pulverized cochineal fifted. They keep a quick fire, and when the liquor is ready to boil, add two ounces of the compofition, which acid immediately changes the colour of the liquor from crimfon to blood colour. As foon as the liquor begins to boil they plunge the worfted, previoufly fteeped in hot water, and exprelTed. Jt is then {birred without ceafing, and fufFered to boil during an hour and half; after which it is taken out, gently fqueezcd, and waflied in cold water. The DYING WOOL. 125 The worded when taken out is of a tolerable bright flefli colour, or even fome ihades darker, according to the goodnefs of the cochineal and the ftrengch of the compofition. The colour of the liquor is fo intirely imbibed by the worfted, that it remains almoft as clear as common water. This is called the Scarlet boiling; a preparation abfolutely neceffary, and without which the cochi- neal dye would not hold. In order to finifli, there muft be another pre- paration of very clear water, as the goodnefs of the water is of infinite confequence to the per- fection of Scarlet. They add, at the fame time, half an ounce of ftarch, and when the liquor is better than warm, fix drachms and half of cochineal, alfo pulverifed and fifced, is added to it. Two ounces of the compofition is poured into the liquor a little before it boils, which, as at firft, immediately changes colour. You wait till it begins to bubble, and then dip the worfted. It ihould be conftantly ftirred as at firft, and in the fame manner fuf- fered to boil for an hour and half, after which it is taken out, expreffed, and rinced at the river : the Scarlet is then in perfe6lion. One ounce of cochineal to a pound of wool will give it a fine colour, and make it fufficiently deep, provided it be managed with attention according to my diredlions, and that there re- mains 'no colour in the liquor. If, neverthclefs, you would have it deeper, you may add a drachm or two more of the cochineal; but a greater quantity would deftroy all its brightnefs and vivacity. Though 126 THEARTDF Though I have afcertained the quantity of the compofition,aswell (or the preparation as for dying, this quantity fhould not be confidered as inva- riable. The aqua-fortis generally ufed by the Dyers is feldom of an equal ftrength, confe- quently, if it be always mixed with an equal quantity of water, it will not always produce the fame effe6b. There are certainly fome methods of afcertaining the different degrees of the acidity of the aqua-fortis, as, for example, to ufe that only two ounces of which will diflblve one ounce of filver: by obferving this method you might fucceed in making a compofition that would be always the fame; but then the qua- lity of the cochineal would occafion other vari- eties; however the little difference which this generally produces in the fcarlet fhade is not of much confequence ; befides, there is a method of remedying this defedb, and bringing it pre- cifcly to what colour you pleafe. If the compofition be weak, and lefs of it be added than I have direfted, the Scarlet will be rather deeper and ftrongerj but if, on the con- trary, there be a little too much, it will have more of the orange colour; more of what is called fire. In order to give it this Ihade, a little more of the compofition may be added after the fixfl-, if the worfled appears to have imbibed too deep a colour. But the wool Ihould be taken out firft, and the compofition well ftirred in the copper, for if it happens to touch the wool before it be v/cll mixed, it would fpot. If, on the con- trary, the Scarlet be too fiery, too much on the orange, or too rufty, there is nothing to be done; but DYING WOOL. J27 but when it is entirely finifhed, to dip it in hot: water: this will crimfon it a little, that is, it will diminifli the brightnefs of the orange j but if this is not found fufficient, it will be necefiary to put a little Roman alum into the hot water. When you would dye a regular ferics of fear- let fliades in worfteds, half the quantity of cochi- neal, and of the compofition ufed for a full Scarlet will be fufficient: you alfo diminifli in proportion the cream of tartar in the preparation. The worfted fliould be divided into as many fkeins as you would have fliades, and when the preparation is made you dip the fkcin intended for the lighted fliade, which fliould remain but a very little times the next fliade fliould after- wards be put in, and fuffered to remain fome little time longer, and fo on to the darkefl: fliade: the worfl:eds arc then waflied, and the liquor pre- pared, in order to finifli them. As foon as the liquor is in a proper fl:ate, every fliade is dipped one after another, beginning with the lightefl:. If you perceive any flcip in the fliade, the flvcia which appears deficient in colour fliould get another dip. This deficiency is eafily perceived, and a very little pradice enables you to fort them perfedly. One circumftance in the art of dying which deferves attention, but which I have not yet mentioned, is an enquiry concerning the materials of which the cauldron is made — Dyers are divided in this particular. Their caul- drons in Languedoc are made of fine tin. They are alfo ufed by fcveral Dyers at Paris; but Mr. Julienne, whofe Scarlet is very highly efleeraed. lag THEARTOF efteemed, makes ufe of brafs cauldrons. Thefe are alfo ufed in the dying manufaflory of St. Dennis. Mr. Julienne is careful only to fufpend a large pack-thread net, with pretty fmall mefhes in his cauldron, to prevent the fluff from touching. At St. Dennis, inftead of a net, they ufe a large open wicker bafketi but this is lefs convenient than the net, becaufe it requires a man at each fide of the copper^ to keep it even, and to prevent it, when loaded with the fluff, from rifing to the furface of the liquor. This praflice, fo different with regard to the materials of the cauldron, determined me to make an experiment. I took two ells of white Sedan cloth, which 1 dyed in two cauldrons, one of copper, furniflied with a packthread net, and the other of tin. I weighed the cho- chineal, the compofition, and other ingredients, with as much accuracy as poffible. They boiled exaftly the fame time. In fhort, I was fufficiently attentive to make the operation the fame in every particular ; that in cafe of any perceptible difference it could only be attributed to the different materials of the cauldrons. After the firfl boiling, the two patterns were abfolutely alike, except, that the piece done in the tin cauldron was rather more mar- bled, and not quite fo even as the other; but this in all probability might be occafioned by their not having been equally cleanfed at the mill. I finiflied each piece in its proper caul- dron, and they were both of them very beau- tiful. Ncverthelefs it was very evident, that the cloth, which had been dyed in the tin I was DYING WOOL. . 129 was more fiery, and the other rather more crim- foned. They might have been eafily brought to the famefhadej but this was not my objed. From this experiment, it appears that, with a copper cauldron, the quantity of the compofition fhould be increafedi but then the cloth grows harfh to the feel. Thofe who dye in copper, to pre- vent this evil, add a little of the Turme?ick, which is a drug only ufcd for falfe colours, and therefore prohibited by the Regulations to dyers in grain, but which gives Scarlet that dazzling fiery colour, fo much the falhion at prefent. It is however, if you have any fuf- picion, eafy to difcover the deception, by cutting the pattern v;ith a pair of fcifiars. if it has no ^iirmerick the cut edge will appear white, otherwife it will be yellow. When the clofe texture is equally dyed with the fuper- ficies, let the colour be what it will, they fay the colour aitSj and the contrary, when the middle of the texture remains white. Legiti- mate Scarlet never cuts. I call it legiti- mate, and the other falfe, becaufe that with the addition of the Tiirmefick is more liable to fade. But as the tufte for colours is fo variable, as the bright Scarlets are at pre- fent the mode, and as it is neceflary, in order to pleafe the buyer, that it fiiould have a yellow cad, it were better to authorife the life of the Turmericky though a falfe colour, than to allow too large a quantity of the compofition by which the cloth is injured, being more liable not only to dirt, but alfo to tear, as the K fibres no TflE A RT OF fibres of the wool are rendered brittle by thtf acid. I miifl alfo add, that a copper cauldron fliould be kept extreamly clean. I have myfelf fre- quently failed in fcarlet patterns by neglefting to clean the cauldron. I cannot in this place forbear condemning the practice, even of fome eminent dyers, who at about fix o'clock in the evening, make their preparation in a copper cauldron, and in order to gain time, keep it hot till day light the next morning,, when they dip their flufrs. The preparation rnuft un- doubtedly corrode the copper during the night, and confequently by introducing coppery par- ticles into the cloth, injure the Scarlet. They will tell us that they do not put in the com- pofition till immediately before the cloth is dipped, but this is no apology,, for the crean^ of tartar added on the preceding evening, being fufficiently acid to corrode the copper, forms a verdigris, which difTolves, it is true, as foon as it is formed, but which neverthelefs produce^ Tthe fame effed. As tin is abfolutly neceflary in the Scarlet dye, it were much better to have a cauldron of this metal, which would infallibly contribute to the beauty of the colour. But thefe cauldrons, if fufficiently large, coft three or four thoufand livres, an obje(ft of confideration, efpecially as they may melt in the firft operation, if not carefully attended to by the workmen. Befides it would be very difficult to cafl a vefiel of fo large a fize, without flaws that would require to be filled. It is abfolutely necefiary that they be DYING WOOL. 131 be made of block tin. If the flaws Ihould be filled with folder, which contains a mixture of lead, many parts of the cauldron will retain the lead, which, being corroded by the acid compofition, will tarnifh the Scarlet. Hence there are inconveniencies in every particular, neverthelefs if it were pofTible to procure a fkilful workman capable of calling a cauldron of the Melac tin, without flaw, it were cer- tainly preferable to every other; for though the acid of the compofition fhould in fome parts corrode it, the detached particles will do no harm, as I have already obferved. There is no danger of melting a tin cauldron, but when it is emptied in order to fill it with a frelh liquor, I Ihali therefore add the precau- tions neeefl^ary to prevent this evil. In the firfl place the fire fhould be taken entirely from the furnace, and the remaining embers quenched with water. Part of the liquor fhould then be taken out with a bucket, while the remain- der fhould be dafhed about with a fliovel by another perfon, in order to keep the upper part of the cauldron continually moift, at the fame time cooling what remains in the cauldron with cold water. In this manner it fhould be continued, till you can touch the bottom without being burnt. It fhould then be entirely emptied and all the fediment taken up with a moifl fpunge. This attention will preferve your cauldron. Having given the method of dying worflcds in Scarlet, and of making the fhades required K 2 for 132 THE ART OF for all kinds of tapeftry, I fhall now add the method of dying feveral pieces of fluff at the fame time, and fhall in this place defcribe the praftice ufed in Languedoc, as it was com- municated to me by M. de Tondieres, then infpedlor general of the manufaflories. I made the experiment myfclf with feveral ells of fluff, and fucceeded perfeftly well, though the colour was not quite fo fine as the fcarlet of Gob- lins. It is firfl neceffary to obferve, that woolens are never dyed Scarlet in the fleece, for the two following reafons. The firfl is, or ought to regard all fluffs of fimply one colour; thofe of many colours are called mixed fluffs. Thefe kind of fluffs are never dyed in the wool, cfpecialiy when the colours are bright and fine ; becaufe in the courfe of the fabrication, the fpinning, twifling, or weaving, it would, be almofl impoffible to prevent fome white or other colour wool from mixing, v/hich though ever fo trifling would injure the fluff. For which reafon, reds, blues, yellows, greens, or any of thefe unmixed colours fhould not be dyed till after they have been manufaflured. The fecond rcafon is peculiar to Scarier, or father to the cochineal, which, being hightened by an acid, cannot fland the fulling, without lofing much of its colour, or being at leafl exceffively crimfoned. Tor the foap which contains an alkaline fait deflroys the vi- vacity produced by tlie acids. Hence is ic evident that neither cloth or fluffs fliould be D Y I iN G WOO L. 133 be dyed Scarlet till they have been fulled and djcfled. For exannple, in order to dye five pieces of CarcaiTionne cloth at the fame time, each piece five quarters broad, and fifteen or fixteen ells in length, it is neceffary to obferve the following proportions: You begin by making the compo- fition in a very different manner from the pre- ceding procefs, viz. twelve pounds of aqua-for- tis put into a (lone jar, or glazed vefTel, with twenty-four pounds of water, and one pound and half of tin grains added. The folution goes on more or lefs flow according to the acidity of the aquafortis, and fliould (land for twelve hours at leaft. During this time a kind of blackifh dirt falls to the bottom; the top fhould be then drained off the fcdiment : this liquor is of a clear lemon colour, and is preferved by itfelf. This procefs evidently differs from the firfl: by the quantity of water mixed with the aqua- fortis, and by the fmall portion of tin, of which fcarce any remains in the liquor; for the aqua- fortis not being in itfelf a folvent for tin, only corrodes and reduces it to a calcs, provided nei- ther faltpetre nor lal -ammoniac be added, which would convert it into an aqua-regia. The effedt of this compoJition is not, however, different from others, and is perceptible to thofe who from experience are competent judges of this colour. The compofition without fal-ammoniac has been for a long time ufed by the manufadlu- rers of Carcaffionnc, who doubtlcfs imagined that its effedl was owing to a fuppofed fulphuv of K 3 tin %' 134 THE ART OF tin, and may be preferved from putrcfaflioa for thirty hours in winter, and only twenty- four in fummer. It then grows turbid, forms A cloud, which falls to the bottom of the veflel in a white fediment. This fediment is a fmall portion of the tin, which was fufpended in an acid not prepared for the folution. The compofition which ought to be yellow, be- comes clear as water, and if employed in this flate . never fucceeds, but produces the fame efFeft as if it had been milky. The late Mr. Barron pretended to be the firft at CarcafTionne who made the dif- covery that fal-ammoniac was neceflary to pre- vent the tin from precipitating. Hence it follows, that there was not in this city a creature who knew that aqua-regia is the only aitual folvent for tin. When the compofition is prepared, as I have now defcribed, according to M. de Fondieres, you put for the quantity of cloth laft mentioned, about fixty cubic feet of water into a large copper ; when the water grows warm, you add a fack full of bran: it is fometimes. neceflary to ufe four water; they will either of them do, as they fay, to corre<5b the water, viz. to abforb the terreous and alkaline fubftances, which, as I have already faid, crimfon the tinge of the cochineal. We fliould be well informed concerning the nature of the water employed, in order to know whe- ther thefe correftives be neceflary. Be it as it may, when the water is a little more than warm, you add ten pounds of cryftals, or cream of tartar pulverifed, that is to fay, two pounds to each piece of cloth. The liquor K ihould DYING WOOL. 135 {liould be then violently (lirred, and when rather liot, you fhould put into it half a pound of the powder of cochineal, mixing it well together, and imnnediately afterwards you pour into it twenty-feven pounds of the compofition, very clear, which alfo requires to be well ftirred. As foon as it begins to boil, the cloth being immerfed, fliould boil very faft for two hours, and during that time fhoujd be kept in continued motion on the wynch, and when taken out pafllng it through the hands by the lifting, in order ta open and give it air. It is afterwards carried to the river and well waflied. In order perfediy to underftand the method of ftirring the cloth, it is requifite to recoiled what has been faid in the beginning of this work, 'viz. that 3 kind of reel, or wyn/:b with a handle for turn- ing, fhould be placed horizontally on the iron iiooks which are fixed in the felloes that fup- port the edge of the cauldron. You firft join the feveral ends of each piece of ftufF to be dyed at the fame time, and, as foon as they are im- merfed, you carefully keep the end of the firft piece in your hand, you then lay it on the reel, which ftiould be turned till the end of the laft piece appears. It is then turned the contrary way, and in this manner every piece will be dyed as even as pofTible. When the cloth has been well wafiied, the cauldron ftiould be emptied, frefti liquor pre- pared, to which you muft add, if neceflary, a fack of bran, or fome four w^aterj but if the quality of the water be very good, there is no occa- K 4 fion 135 THE ART OF fion for any addition. When the liquor is ready to boil, you put in eight pounds and a quarter of cochineal pulverifed and fifted. The whole is then mixed together as even as pofTible; but when you ceafe to ftir you muft mind when the cochineal rifes to the furface, forming a kind of fcum the colour of lees of wine. As foon as this fcum begins to divide, you pour in eighteen or twenty pounds of the compofition. You fhould have a vefTel full of cold water near the cauldron ready to throw in, left after putting in the com- pofition it flioUid rife above the edge, as is fome- times the cafe. When the compofition is put into the copper, and the whole well mixed, you turn the wynch quick for two or three turns, that every piece may imbibe the cochineal equally. It is then turned more flowly in order to let the water boil. It fhould boil very fail for two hours, con- ftantly turning and keeping the cloth down with a (lick. The cloth is then taken out, and pafled through the hands by the lifting, in order to give it air and to cool itj it is afterwards waftied at the river, dryed, and drefled. Hence it appears that for every piece of Lan- guedoc cloth defigned for the Levant, is required a pound and three quarters of cochineal. This quantity is fufficient to give the cloth a very fine colour; but if you increafe the quantity of the cochineal, and ftill require an orange tincfl, yon muft necefiarily increafe the quantity of the compofition, which would injure the cloth with- out improving the colour. 4 Ther^ DYING WOOL. 137 There is a confiderable advantage In having a great quantity of fluff to dye at the fame time; as for example, when the five firfl pieces are finifhed, there remains a certain quantity of the cochineal, which, fuppofing feven pounds at firfl, might amount to twelve ounces, fo that cloth put into this fecond liquor will imbibe the fame fhade of rofe colour as if you had coloured a frefh liquor with twelve ounces of cochineal. The quantity remaining may, however, vary very much according to the quality of the cochineal, or according to the finenefs of the powder; but I fhall fpeakof this more particularly before the conclufion of this chapter. Though the quan- tity of colour remaining in the liquor may be very inconfiderable, it neverthelefs deferves attention on account of the dearnefs of this drug. Of this liquor, therefore, a preparation may be made for five pieces of cloth, and it will require lefs of the cochineal and lefs of the com- pofition, in proportion, as near as you can guefs, to the quantity remaining in the liquor. This is alfo a faving of wood and time; but it is im- pofTible to give pofitive diredlions concerning tiiis manoeuvre, which mull be left to the inge- nuity of the Dyer; for having dyed rofe colour after the Scarlet, you may make a tiiird prepa- ration, which will dye a flefh colour. If there is not time to make thefe two or three prepara- tions in twenty-four hours, the liquor fpoils; ibme Dyers put Roman alum into the liquor to prevent it from fpoiling; but this changes it to a crimfon. Scarlets 13$ THE ART OF Scarlets thus crimfoncd in the fame liquor in which they had been dyed, arc never To bright as thofe done in a frelh liquor. Drugs, which reciprocally deftroy each other's efFe<2:, are more efficacious when employed in fucceflion. When you dye cloth of different qualities, or any kind of fluffs, the bcfl method is to weigh them, and for every hundred pound to allow about fix pounds of cryftals, or cream of tartar, eighteen pounds of thecompofition in xht prepara- tion, the fame quantity in the completion, and in each of them fix pounds and a quarterof cochineal. For the accommodation of thofe who would themfelves make fmall experiments, the whole may be reduced, viz. one ounce of cream of tartar, fix ounces of the compofition, and an ounce of cochineal for every pound of fluff. Some of the Paris Dyers fucceed very well by ■putting two thirds of the compofition and a quar^ tcrof the cochineal in the preparalion, and the re- maining third of the compofition, and the other three quarters of the cochineal, to the comple- tion. It is not the cuflom to put cryflal of tartars in the finilh; 1 am however convinced by experi- ence that it does no harm, provided that at moft you put but half the weight of the cochineal, and, in my opinion, it made the colour rather more permanent. There have been Dyers who have dyed Scarlet at three times, in this cafe they had twopreparationSy and afterwards thefinifh; but they always ufed the fame quantity of drugs. 1 obferved in the preceding chapter, that the kermes were fo little ufed for brown or Venetian ScarlefeB^ DYING WOOL, 139 Scarlets, that thefe kind of colours were made with cochineal. For this purpofe the preparation is made as ufual, and for the dying, they add to the liquor eight pounds of alum to every hun- dred weight of fluff. This alum is diffolved in a feparate cauldron with a fufficient quantity of water: it is thrown into the liquor before the cochineal. The remainder is done precifely the fame as in common Scarlet : it gives the cloth the colour of Venetian Scarletj but it is not by any means fo permanent as the colour obtained from kermes. There are no alkaline falts that do not crimfon Scarleti but it is more generally the cuftom to ufe alum, becaufe thefe alkaline falts are no ad- dition to the permanency of the colour, and may pofiibiy injure the fluffs, becaufe all animal fubllances are diffolved by fixed alkalies. The alum, by being deprived of its phlegm by cal- cination, will more certainly crimfon. The liquor which had been ufed for crimfoning is red, and ftill redder in proportion as the Scarlet is more crimfoned, fo that the colours part with much of their bafis in the liquor by which they are darkened. It is however impofTible to darken in Grain without falts. The late Mr. Barron, in a memoire which he prefented to the Royal Academy of Sciences twelve or fifteen years ago, remarks, that he fucceeded better with the fait of urine than with any other fait for uniting the colour and preferving its brightnefs and fulnefs i but, as he obferved, it is very' in- >:onyenicnt to make any quantity of this fait. Ifaid 140 THEARTOF I faid in the beginning of this chapter, that the choice of the water for dying Scarlet was of importance;, the greateft part of the common waters fadden, becaufe they almoft always con- tain a quantity of ftony or calcarious earth, and fometimes of fulphureous or vitriolic acid. Thefe are commonly called hard waters ; by this term they mean water that will not diiTolve foap, and in which it is not eafy to drefs vegetables. By abforbing or precipitating thefe heterogeneous fubftances, all waters are rendered equally good. If the matter be alkaline, a little four water will produce this efFecfl. Five or fix cubic feet of this four water, added to fixty or feventy cubic feet of other water before it has boiled, will caufe the alkaline earth to rife in a fcum which may be eafily taken off the liquor. A fack full of any kind of white mucilaginous root cut in fmall bits, or, if dry, powdered, will alfo, if the fack be left to foak in the water for a half, or three quarters of an hour, correal a doubtful water; bran, as 1 have faid above, will alfo an- fvver the fame end tolerably well. "What I have hitherto faid in this chapter, is meant for the inftrudion of thofe who would acquire knowledge in the art of dying. I fhall now endeavour to fatisfy the philofopher, and prefent him with the experiments by which I difcovered the invifibie mechanifm, if I may be allowed the exprefiion, of thefe various prepa- rations. Cochineal infufed, or boiled only in clear water, yields a purpleilh crimfon, which is its natural colour. Put this folution into a glafs, and drop on DYING WOOL. 14? on it fome fpirit of nitre, it will gradually beconne lighter till it is almoft yellow ; add a few drops more and fcarce any of its original rednefs will remain. In this manner acids deftroy red, by dillblving and dividing it into particles of fuch tenuity as to become imperceptible. By fub- flituting vitriolic acid inftead of nitrous acid, the firil alteration in the colour will be purple, then purple lilach, afterwards light lilach, then flefh colour, and then no colour at all. The bluifli tinge, which by mixing with a red conftitutes purple, may proceed from that fmall portion of iron from which oil of vitriol is very rarely exempt. Cream of tartar is the only fait uled in the ^preparation for Scarlet, without the ad- dition of alum, as is common in the ^r^^^ri?//^^ tor other colours, becaufe its vitriolic acid, would crimfon the dye. It is neverthelefs neceflary to have a white earthy fubftance; a lime which, with the red particles of the cochineal, may form a kind of painter's lacker, and which, by the help of cryftals of tartar, is introduced into the pores pf the wool. This calx is obtained from a folu- tion of pure tin. Let this experiment be made in a fmaU glafed earthen veffd, and when the cochineal has tinged the water, the compofition fhould be dropped into it drop by drop, examin- ing, with a magnifying glafs, the efFcft produced by each drop. You perceive a fmall circle, whence arifes a pretty brifK fermentation. The calx of the tin feparates, and is immediately dyed the fame lively colour which is imbibed by the cloth in the fec^uel of the operation. I: 143 THE ART OF It is evident that the calx of tin is neceffary in this operation, bccaufe if the cochineal is ufed with fpirit of nitre, or aqua-fortis only, it pro- duces a very ugly crimfon. If you diflblve any other metal in the fpirit of nitre, fuch as 'iron or mercury, the firft will produce a deep afh colour J and the fecond, a marone colour, without the lead appearance of the red of the cochineal in either of them. Hence it is rational to fup- pofe that the calx of tin, having been dyed by the colouring particles of the cochineal, enlivened by the diflblving acid of this metal, has formed this kind of terreous lacker, the atoms of which are introduced into the pores of the fibres of the wool, which were opened by the heat of the boiling water ; they are there wedged in by the cryftals of tartar, and the pores of the cloth being immediately contraded by tjie fud- den cold, when expofed to the air, the colour- ing particles will be fufficently fixed to be termed in Grain. If, by being expofed to the air after- wards, it fhould lofe any of it former vivacity, it will not fuffer alike in all places, but accord- ing to the heterogeneous fubftances with which the air is impregnated. In the country, for example, and particularly in a high fituation, a fcarlet cloth will preferve its beauty much longer than in a large city abounding with urinous and alkaline effluvia^ for it is well known, as I have before obferved, that all alkaline fubftances deftroy the effedt produced by an acid on any colour whatfoever. For this reafon, if you boil a piece of Scarlet in a lixivium of pot-afh, the colours become purple, and by continuing to lee DYING WOOL. 143 let it boil, is entirely difcharged; becaufe fixed alkali and cryftals of tartar produce a foluble tartar, which water diflblves, and eafily detaches from the pores of the wool. The intire maftic of the colouring particles being thus deftroyed, is mixed with the lixivium of the falts. 1 have tryed feveral different experiments with the cochineal colour, in order to try the cffed of its union with fubftances which arc generally fuppofed not colouring j but I fhall relate thofe only which produced the moll extraordinary effeds. For example. Zinc, dilTolved in fpirit of nitre, converts the red of cochineal into a viplet flate colour. Sugar of lead inftead of cryftals of tartar, pro- duces a tarnilhed lilach, which Ihews that the leaden particles unite with the colour of the cochineal. Vitriolated tartar, made with pot-alhes and vitriol, dellroys die red of this ingredient, and leaves only an agate grey. Bifmuth, diffolved in fpirit of nitre, diluted with an equal quantity of water, poured on the cochineal liquor, gives cloth a beautiful bright turtle grey colour. A folution of copper in fpirit of nitre, not diluted, gives with the cochineal a dirty crim- fon. That of filver, a cinnamon colour. Arfenic, a nwre lively cinnamon than the preceding. A folution of gold in aqua-regia, produces & ftreaked marone, which makes the cloth appear 144 THEARTOF appear as if it had been manufactured \Vith different coloured wool. A folution of mercury in fpirit of nitre pro* duces nearly the lame effeA. Glauber falts only, mixed with the cochineal liquor, deflroys the red, in the fame manner as vitriolated tartar, and like it produces an agate grey colour; but not in grain j becaufc this fait is too eafily diflblved, even- by cold water, and is alfo of the clafs of falts, which arc cafily calcined by the air. Fixed fait of urine produces a clear afli-colour, without the lead appearance of red, and like the preceding article is not in grain, becaufe it yields no per- manent maftic, and confequently is diflblved by the humidity of the air only. Finally, the cxtradl of bifmuth changes the red of cochi- neal to a violet colour, as fine as if the cloth, previous to the application of red, had been dyed an azure blue. From thefe experiments it is eafy to con- clude that the falts, and metallic Iblutions, unite with the particles of the colouring in- gredient, and it is alfo demonftrable, that the addition of thefe particles greatly contribute to the tenacity of the colours. Before the conclufion of this chapter I Ihall make fome obfervations, which will not 1 think be unacceptable to the reader. Neither the dirt of the flreet, nor many other acid fub- flances, will fpot Scarlet, if immediately walhed off with a clean towel and clear water; but, if fuffered to dry, the fpot is then a dark violet colour and cannot be corrected, without a vege* table DYING WOOL. 145 table acid, fuch as vinegar, lemon juice, or a weak folution of white tartar made hotj but tfiefe acids, if not managed with care and dex- terity, will, in taking out the dark fpct, leave a yellow one. I have before obferved that acids will ruft and deftroy even the red of cochineal. A red cloak, extremely fpotted with dirt, may be cleaned with four water. For fome kinds of fpots it is neceflary to dip the ftuTs in the liquor that remains after dying fcarletj but for others, you are obliged td difcharge the colour and dye it again. Alkalies have not alone the property of dif- charging the fcarlet colour. A piece of fcarlet cloth put into the preparatkn, for this colour, will be difcharged in fuch a manner, that if It boil but for one hour with three pieces of white cloth, it will be difficult to diftinguifh that which was fcarlet, from the others. If you dip a piece of fcarlet cloth in the preparation-zvater, it will immediately lofe all its colour, becaufe the firft falts diffolve and mix with the frefh; but if you boil it again in a cochineal liquor, it will recover its firfl colour, with the addition of fuper- fluous colouring particles; and the cloth will have much lefs vivacity than it would have ac- quired in the common operation. Hence it appears, that the inventors of this magnificent colour muft have made a confiderable num- ber of combinations, before they attained per- fedtion. Scarlet cloth always lofes a great part of its brightnefs in the dreffing, becaufe it lays the L fibres, 146 THEARTOr* fibres of the nap almoft parallel with the wefc. In this ftate the cloth has lefs fuperficies, and confequently refledts fewer rays of light. Befides the ends of the hair is always the moll impregnated with the dye, fo that when they are layed down by the drefllng, their ends not appearing is a great difadvantage to the vivacity of the colour. CHAP. XIV. Of Crimjon, CRIMSON, as I have before faid, is the natural colour of the cochineal, or rather that which it gives to wool when boiled in alum and tartar, the common preparation for every colour. The following is the method generally pra6tifcd with worftedsj nor is there any great difference with regard to cloth, as will be fhewn in the fequel. You put into a cauldron two ounces and half of alum, and an ounce and half of white tartar, for every pound of wool. As. foon as it begins to boil you put in the wool, ftirring it well, and fufFering it to boil tor two hours i it is, then taken out, lightly fqueezed, and put into a bag, in which it fliould remain, as for fcarlet in grain, and for every other colour, A frefh liquor is prepared for the dying, rn which you put an ounce of cochineal for every pound of wool. When it begins to boil you put in the wool, ftirring it well, as fhould be done In the preparation, and thus it fhould remain for an hourj it is then taken out, fqueezed, and rinced at the rivei^. If bViNG WOOL. 147 If you require a regular feries of fhades, you proceed in the fame manner as I have directed for fcarlets, viz. putting but half the quantity of cochineal; the fhades fhould be dipped one after another, the darker (hould remain longer than the lighter, beginning always with the lighteftHiadc. I have made many attempts to bring crimfon to greater perfedlion than has been hitherto done, and have fucceeded fo far as to render the grain colour equal in brightnefs and vivacity to the falfe crimfon. I proceeded on the following principles. It is very evident, from what has been already faid, that cochineal is faddened by alkalies: this was my foundatioa. I tried foap, pearl-a(h, and pot-afli ; thefe falts had the dehred efFect ; but at the fame time they tarnifhed and diminifhed the brightnefs. I determined to try volatile alkalies, and found that the volatile fpirit of fal-ammoniac, pro- duced a very good effedl; but it evaporated in a moment, fo that being obliged to ufe a confiderable quantity, the expence of the dye Vvas vaftly increafed. I had then recourfe to another expedient, which fucceeded better, and the expence was very trifling : which was, to life the volatile alkali of fal-ammoniac, in the moment of its extradion from its bafis. For this purpofe, when I had finiflied after the com- mon procefs, I dipped my crimfon in a new liquor, in which I diflblved a fmall quantity of fal-ammoniac. When the liquor was a little better than warm, I put in the fame quantity of pot-afh, and my wool immediately took a L 2 colour 143 THE ART OF colour very highly crimfoned, and very bright. This method even faves cochineal, which being raifed by the frefli folution, lefs of it will do than is ufual in common praftice. Several, even eminent Dyers highten their crimfon with Archil, a drug of the falfe dye. A very beautiful crimfon is obtained by boiling the wool, as for common fcarlet, and after^yards making a fecond preparation with two ounces of alum, and an ounce of tartar, to every pound of wool: it fliould remain an hour in this decoflion. You then immediately prepare a frefh liquor, in which, to every pound of wool, you put fix drachms of cochineal. When it has remained an hour in this liquor it is taken out, and immediately dipped in a folution of barilla and fal-ammoniac. You may in this manner make a very beautiful feries of fhades of crimfon by diminifhing the quantity of the cochineal. It is neceffary to obferve, that in this procefs fix drachms of cochineal to every pound of wool is fufficientj becaufe, in the firft preparation for fcarlet, they allow a drachm and half of cochi- neal to every pound. It Ihould alfo be obferved, that in this procefs your folution of alkaline and ammoniacal fait mull not be too hotj becaufe, in that cafe, the volatile fpirit of the latter would evaporate too quickly, and the cryftals of tartar, being thence converted into foluble tartar, lofc their property. The fam.e effeft may be produced by ufing the cochineal Jyhejire, or campajfianne^ inllead of fine cochineal; nor is the colour inferior provided you put in a fufficient quajitityj for, 5 i». DYING WOOL. 149 ki general, four parts of cochintdX fyhejire has • no more effe6t in dying than one part of fine cochi- neal. You may even employ the cochineal Jyl~ vejlre in fcarlet, but then it Ihould be ufed with great precaution, and it were even better not to ufe it but for half fcarlets or half crimfons. I Jhall mention this more fully when fpeaking of thefe colours in particular. When fcarlet is fpotted, either in the opera- ration, or by fome unforefeen accident, or even when the dye has failed, the common method is to dye it crimfon ; which is done by dipping it into afolution containing two pounds of alum to about a hundred pounds of wool. In this it is immediately dipped, where it is fuffered to remain till it has acquired the crimfon fhade you defire. The following is the prefent method in Lan- guedoc, where they make a very beautiful kind of crimfon cloth which they export to the Levant; but which is not fo deeply crimfoned as that I have been mentioning, and which comes much nearer to the Venetian Scarlet. For five pieces of cloth the liquor is prepared as ufual, adding bran if ncceffary. When it is a little better than warm, they add ten pounds of fea-falt inftead of cryftals of tartar; and when ready to boil, they pour into it twenty-feven pounds of the compofition for fcarlet, made ac- cording to the CarcaiTionne method, without any addition of cochineal; the cloth is kept in the li- quor for two hours, keeping the reel conftantly turning, and the liquor boiling. It is then taken out, opened, and rinced at the river; a new liquor is L 3 then I5P THEARTOF then made with eight pounds and three quarter^ of cochineal well pulveriled and fifted ; when rea- dy to boil you throw into it one and twenty pounds of the compofition. In this dye the cloth Jhould boil, with the ufual precaution, for three quarters of an hourj after which it is taken out, opened, and waflied. It is a very fine crin^ifon, though not very deep. If you require it deeper, you put a good deal of alum into the firft liquor, or preparation, and in the fecond lefs of the compofition : you alfo add fome fea-falt to the fecond liquor. Experience will teach you foon how to produce every poffible Ihade of crimfon. After the various operations mentioned in the two preceding chapters, there will be in the bottom of the finifliing liquor a confiderable brown fedimenr, which is thrown out as ufelefs.- This I ordered to be brought to me for exami- nation, and found that the fediment, which remained after fcarlet, contained a precipitated calx of tin. I have even revived the metal, though I Tnuft confefs with great trouble, fo that there can •be no advantage in the repetition of what I have done. The remaining particles of this fediment were the dregs of the cream of tartar united with the grofs animal particles of the cochineal, which, as I have before faid, is a little infeft. Thefe little animal particles I walhed in cold water, and, agitating the veflel, gathered with a fmall fieve what was thrown to the furface by the motion of the water. In this manner I di- vided the light particles from thofe which were earthy DYING WOOL. tsi earthy and metallic. They were dryed feparately, and afterwards bruifed with an equal weight of cryilals of tartar ; when reduced to an impalpa- ble powder, I had a part of it boiled with a little alum, and fuffered a pattern of white cloth to remain in this -toiling folution for three quar- ters of an hour, at the expiration of which time, it was taken out a very beautiful crimfon. From this experiment I am convinced that the common cuftom of reducing the cochineal to powder, and only fifting it, does not fufficiently extra6t the whole that may be obtained from this precious drug; and I think it incumbent on me, in this place, to mention this experiment for the advantage of thofe Dyers who will be tradable enough to avail themfelves of the difcovery. For example, I take an ounce of cochineal, pulverifed and fifted as ufualj I add to this a' quarter of its weight of cream of tartar, very white, very clear, and very dry. Thefe being ground on a painter's marble to an impalpable powder, I ufe it both in iht preparation and in the ^ye, omitting in the preparation the fmall propor- tion of the cryftals of tartar which was added to the cochineal. What I put to the dye, though mixed with a quarter of the fame fait, fo far from injuring the colour makes it evidently more fixed. L 4 CHAR 15:? THE ART OF CHAP. XV, Of Gum Lac Scarlet. ^nr^HE red particles of Gum Lac is alfo ufec^ -*• for dying Scarlet, and though the cplouK may not be quite as bright as that obtained fronq fine cochineal only, it has the advantage of being more permanent. The Gum Lac moft efteemed for dying, is in the form of branches, becaufe moftfurnifned with animal particles. That which is redded in the infide, and at the outfide rather ablackifh brown, is the bell. It appeared from a particular exa- mination of Mr. GeofFrie's, made fome years ago, to be a kind of comb, refembling in fonne de- gree that ufually produced by bees and other infe6ts. It is fometimes ufed for dying ftuffs, pulverifed and tied up in a linen bag; but this is a bad method, as fome part of the gum-refin, being melted by the boiling water, efcapes through the linen, and fo clofely adheres to the cloth when cold that you are obliged to fcrape it off with a knife. Others reduce it to powder, boil it in water, and when it has communicated all its colour, let it ftand to cool : the refinous particles fall to the bottom. The coloured water is then evaporated in the air, where it frequently becomes putrid. When it has acquired the con- fidence of fyrup it is preferved in veffels. Under this formic is difficult to determine the precife quantity, and therefore I endeavoured to find a method of feparating the colour from the gum- refin^ DYING WOOL. 153 r.efin, without the neceffity of evaporating fo Jarge a quantity of water. I fhall not mention the variety of experiments which I made with weak lime water, with a decoc- tion of the heart oiJgariCi and with a decodlion of the root of Birth-'-jJort, recommended in an an- cient difpenfatory i becaufe, though the water left a part of the colour which it had imbibed on the philtering paper, it was neverthelefs too much coloured, and therefore it was neceflary to evaporate in order to procure all the colour. To avoid thffs evaporation I had recourfe to mucila« ginous roots, which of themfelves yield no colour, but whofe mucilage retains the colouring particles in fuch a manner as to remain with it on the philtre. I have hitherto fucceeded befl with the Comfrey-root. I ufe it dried and made into a grofs powder, half a drachm to a quart of water, letting it boil for a quarter of an hour; I then drain it through a linen cloth, and pour ic quite hot on the Gum Lac, pulverifed and fxfted through a hair fieve. It immediately acquires a fine crimfon colour. I put the vef- fel to digeft in a moderate heat for twelve hours, obferving to flir the gum which remains at the bottom feven or eight times. I afterwards decant the water impregnated with this colour into a veflel large enough to contain four times the quantity, which I fill with cold water. I then add a very fmall quantity of a ftrong folu- tion of Roman alum. The coloured muci- lage precipitates J but, if the water ftill re- mains coloured^ I add fome drops of the folu- tion 154 THEARTOF tion of alum to complete the precipitation, pro- ceeding in this manner till the water becomes colourlefs. When the crimfon mucilage is entirely funk to the bottom, I draw off the clear water with a fyphon ; the remainder I philtre, and when perfectly drained caufe it to be dried in the fun. If the firft mucilaginous water does not fuffici- cntly extract the colour from the Gum Lac, fo as to leave the gum a pale ftraw colour, I add fome more, boiling hot, repeating everything that I had done in the firft extradion. In this mannA- 1 fepa- rate all the colour that it is capable of furnifliing; but as I had it dried and then pulverifed, I know the whole that may be obtained from this gum, and am alfo better enabled to judge of my quan- tities in dying than thofe who are fatisfied with the extrad procured by evaporation, as that which is moft compact will contain moft colour. The beft chofen Lac, detached from its branches, yield little more than a fifth part of its weight in colour. Hence, confidering the price which it bears at prefent, the advantage of fubftituting it in the place of cochineal is not fo great. To dye Scarlet with the Gum-Lac colour, cxtrafted according to my method, and reduced to powder, requires a peculiar precaution in the diluting; for by putting it into the water when ready to boil, as you do the cochineal, you lofe three quarters of an hour before it entirely diflblves. To be more expeditious, I put the quantity of this dry powder, defigned for ufe, in an earthen, or block tin vefTel; I then DYING WOOL. 155 then pour on it fome hot wp.ter, and when well moir(.ened, add the rcquifite quantity of the Scarlet coinpor'tion, ftirring the mixture with a glafs peftle. This powder, which was before a dark dirty purple, acquires in the fblution a fire colour red cxtteamly brighc. I pour the folu- tion into the liquor, to which I had previoufly diilblved cryftals of tartar, ut the fineft roots for the firft fort, in drying them with certain precautions, in feparating the bark at the mill, and in preferring the infide of the root moift in cafks, where it fhould re- main two or three years, when it will be better for dying than if newly ground. If madder be not kept clofe in this manner it will fpoil, and in a great meafure lofe its vivacity. It is at firft yellow-, but becomes red and darker as it grows old. Madder fiiould be chofen of a fine fafFron colour, in very hard lumps, and of a very ftrong fmell, though not difagreeable. It is alfo cultivated in the fuburbs of Lifie in Flanders, and in many other parts of the kingdom where it is known to grow wild. The madder iifed in the Levant, and in the Indies for dying cottons, is in fome refpedts different from that ufed in Europe. On the coaft of Coromandel it is called CbaL This plant grows wild in the woods on the coaft of Malabar. That which is cultivated is imported from Faour and Tuccoriiiy but the moft efteemed is the Perfian Chat, called Dumas. They alfo gather on the coaft of Coromandel the root of another plant, called Raye de chaye^ or colour-root, fuppofed to be a fpecies of madder root, but which is a fpecies Q>i Galium flore albo, as we are informed by the Memoirs tranfmitted from India in 1748, This is a long flender root, and gives cotton, after it has received the neceflary preparation, a tolerable fine red colour. At DYING WOOL. i6i At Kurder, in the neighbourhood of Smyrna, and in the country of Ak-hijfar and 2^ordaSj they cultivate another fpecies of madder, called in that country Chive-boy a, Ckme Hazala. It is, according to fome experiments, the beft of all madders for dying red, and is therefore more eftcemed in the L-evant than the fine Zealand madder carried thither by the Dutch. This madder, ^o greatly efteemed, is called by the modern Greeks Lizari, and by the Arabs Fonoy. \T^hef8 madders J becaufs dryed in the air, and not in jlovesy give a much better colour than the jinejl Zealand grapfe madder, The madder of LanguedoCf end even that of Foitou, when dryed without fire, Jucceeds as well as the Lizari. '\ There is likewife another fpecies of madder brought from Canada, and there called Tyjfa- Voyana : the root is extremely flender, and pro- duces nearly the fame effed as the European madder. The preparation for Madder Red is pretty much the fame as for the red of kermesj it is always made with alum and tartar. With regard to the proportions, dyers are not per- fectly agreed; for my part I put five ounces of alum, and one ounce of red tartar, to every pound of worfted; I alfo add about a twelfth part of four water, and in this liquor I let the wool boil for two full hours. If worfted, I keep it well moiftened for feven or eight days with this folution ; but, if cloth, I finiih in four days. I prepare for dying this wool afrelh liquor, and when the water is fo hot as to bear your hand in it, I throw in, for every pound of M wool. i62 THE ART OF wool, half a pound of the finefl: Madder, care- fully ftirring and mixing it well in the copper before I put in the wool, which I keep in it for an hour, without letting it boil, as that would tarnilh the colour. Neverthelefs, for the Dyer's better fecurity it may boil for three or four minutes at the conclufion of the operation. \Jt^ more Madder is boiled y the worje the colour it yields, "l For fhades of Madder you proceed as I have already diredled for other colours j but thefc fhades are feldom required ^ a gradation of thefe not being necelTary except for mixt colours: there are, however, a very confiderable number of Grain colours which muft have a Madder ground. If you have feveral pieces of cloth to dye at the fame time, you proceed in the fame manner, only increafing the quantity of the ingredients in proportion to my direflionsj remembering, con- Itantly, that in fmall operations there fhould be fomewhat more than a proportionable quantity of the ingredients, not only with refpeft to the red of Madder but to all other colours. Thefe reds are never fo beautiful as the red of kermes, and much inferior to thofe of the lac and cochineal j but they coft lefs, and are con- fequently ufed for common fluffs, the price of which is too low to bear the expence of a dearer colour. The greateft part of the reds worn by the infantry and cavalry are generally dyed with Madder, and crimfoned with archil or brafil wood (drugs of the falfe dye) but which make them much finer and improves the nap; whereas this advantage could not be procured by means DYING WOOL. 163 means of the cochineal without greatly increaf- ing the price of the (luff. I have already obferved, that Madden applied to fluffs, before they have been prepared in a folu- tion of alum and tartar, will colour them it is true, but then the colour will be uneven and not permanent, therefore it is the falts which fix the colour : this is common to all colours j confequently red or yellow is not to be obtained without this preparation. The queftion is, whe- ther, by fimply extrafling the oily perfpiration of the Iheep, the pores are prepared to receive more immediately the colouring particles; or rather, whether a part of thefe falts, efpecially of the two which cannot be diffolved even by warm water, remains in them in order to attach and fecure the colouring atoms, the pores being opened or dilated for their reception by the heat of the water, and afterwards, in order to retain them, contradled by the cold. For the convidion of thofe prejudiced in favour of the lirfl opinion, let them fubfli- tute in the place of alum and tartar, any alkaline falts, fuch as pot-afb, or lixivium of oak-afhes, in a proper quantity fo as not to diffolve the wool; and after this preparation the fluffs, being dipped in the Madder Vat, will take the colour; but then this colour is fo entirely unfixed, that boiling water only will carry off at leaft three-fourths of the dye. Now it is impoffible to fay that fixed alkaline fait is incapable of cleanfmg the pores of the wool of its animal fat, fince lixivial falts are ufed with fuccefs in feve- ral cdes, where it is neceffary to extrad that fat M 2 from \ 164 THEARTOF from ffufis, of whatfoever kind they be, which water alonewill not wafh off. It is well known that the extraneous fat and alkaline falts produce a kind of foap, which is afterwards eafily wafhed out with Water. i ' Take a hit of cloth dyed in the red of Mad- der, according to the common method, letting it boil for fome time in a folution of a fmall quantity of fixed alkali, you will in this manner deftroy the colours for the fixed alkali uniting with the mi- nute atoms of the cryftals of tartar, by which the pores of the fibres of the wool are lined, produces a foluble tartar which it is well known eafily dif- folves in water; confequently the pores being opened by the boiling water of the experiment, tlie colouring atoms are thereby extraded, toge- ther with the faline atoms by which they were attached. This (luff being wafhed in water, the remaining red colour is therein diluted and becomes a dirty fawn colour. If inftead of alka- line fait you ufe foap, which is an alkaline fait combined with oil, and for fome minutes boil in it another pattern, which had been alfo dyed a Madder Red, this red becomes more beautiful; becaufe the alkali, which in the foap is enveloped with the oil, cannot pofiibly attack the vege- table acid fait : the boiling only carries off^ the loofe colouring particles, and their number being diminifhed, what remains will appear lefs loaded, or lighter. 1 fay further, as an additional proof of the exift- ence of the falts in the pores of the wool of a ftufF boiled in the preparation, before it was dyed with Madder, that with this root, by put- ting DYING WOOL. 165 ting in more or lefs tartar, you procure an infinite variety, not only of (hades but even of colours; for, by diminifliing the quantity of alum and augmenting that of the tartar, you produce a cinnamon colour j but, if you put nothing into the preparation but tartar, the red is deflroyed, and you obtain only a deep cinnamon or fawn colour, but nevcrthelefs of the good dye; becaufe the crude tartar, being an acid fait, dif- folves the red particles in fuch a manner, that there remains but a very fmall quantity with the woody fibres of the root, which, like all com- mon roots, yields only a fawn colour, more or lefs deep in proportion to the quantity employed. I have already demonftrated that the acid moil enlivening to reds will alfo deftroy them, if the quantity be too great, by dividing them into particles of fuch extreme tenuity that they arc imperceptible. If in the alum preparation for fluffs to be dyed in Madder, you ufe infleadof tartar, which is a hard fait, a fait eafily foluble, as, for example, faltpetre, the greateft part of the red becomes ufelefs; it difappears, and you have only a cin- namon colour, very bright indeed, but not fuf- ficiently folid to ftand the tefl, becaufe the two falts ufed in the preparation are not fo firm as the tartar. The volatile urinous alkalies which develope the red particles from certain plants, fuch as perilla, archil, and moiTes, or lichens, which, a priori, could not have been fufpefted, deve- lope alfo the red of the Madder root ; but they 9X. the fame time communicate their volatility to M 3 fuch i66 THE ART OF fuch a degree, then when I ufe this Madder, prepared in the fame manner as the archil with fermented urine and quick lime, I could procure only a nut brown, either light or dark ; but neverrhelefs durable, becaufe the fmall quan- tity of volatile alkali which moiftened the Madr der, evaporated in the boiling. When you apply a pure red, fuch as the red of cochineal, to a cloth previoufly dyed blue, and afterwards prepared by a folution of alum and tartar, in order to receive and retain the red, you produce either a purple or violet colour, in proportion to your quantity either of the blue or of the pure red. But the Madder has a dif- ferent effedl, becaufe not pure like the red of cochineal, and befides, as I have already obferved, it is fpoiled by the fawn tinge of the woody fibres of the root. Hence this red, tarnifhed by the colour of the root, produces with the blue a marone, more or lefs dark, according to the intenfity of the blue firft applied. To give this marone colour a purple calt, and to confirm it in grainy you mud neceffarily ufe a little cq- chineal. To avoid the colour of the root, the beil Madder Dyers are very careful not to make ufe of the dye too hot, and to take out their fluff a minute or fwo after it begins to boili for if it boils rnore, the Madder is confiderably tar- nifhedj the heat of the water being then fuffi- cint to detach the fawn colour particles, lb that they are applied with thofe of the red. This evil may be avoided if, while the Madder root js frefli, you can contrive, without much difHr pulty^ DYING WOOL. 167 culty, to feparate from the reft of the root the red circle under the brown Ikin, by which the pith of the infide is encompafled. But as this procefs enhances the price of the ingredient, as it requires patience, and after all is never equal to the cochineal, it is therefore hardly worth while to attempt it in the great. It may however be ufeful in dying cottons, the price of which will bear the expence of this preparation. Madder being the cheapeft of all fubftances employed for the good dye, it is ufeful for mixing with others, and thereby diminifiiing the expence. Half fcarlet, otherwife half-grain, is produced with Madder and kermes, and the common half fcarlets and half crimfons, with Madder and cochineal. To make half-grain fcarlet you proceed with the preparation and with the reft of the operation as if for the fcarlet of kermes in grain, only that in the fecond decoftion you put but half the quantity of the kermes, and the other half of the beft Madder. For half fire coloured fcarlet, or fcarlet of Gob- lins, the compofition and preparation are made as ufual. To this you put the pure cochineal only 3 but in the reddening or finifh, you put half cochineal and half Madder. In this cafe you may alfo ufe cochineal Jyhejire ; for having made the preparation with common cochineal, if you dye a quantity of wool, as for com- mon fcarlet, you muft put in the reddening two pounds of cochineal ; but it would be fufEcient to put half a pound of common M 4. cochineal, i68 THEARTOF cochineal, a pound and half of cochineal com* paiTienne, or fylveflre, and a pound of Madder. To dye wool ^nd ftuffs as even as poflible, it is abfolutely necefrary that each of the cochi- neals be well ground and fifted as well as the Madder, with which they Ihould be perfedlly incorporated before they are thrown into the decoftion. This ihould be obferved with regard to all colours requiring a mixture of feveral ingredients. The half fcarlet is finilhed as the common fcarlet, and faddened in the fame manner, either with boiling water or alum. Half crimfon is alfo produced in the fame man* ner as common crimfon, adding only half Mad- der and half cochineal. Cochineal Jylvefire may alfo be ufed, obferving only to retrench half of the common cochineal, fupplying its place with three tim^es the quantity oi Jylvejire; but if you increafe the quantity of the fylveftre, and at the fame time diminifh the other, the colour will not be fo fine. If you require inferior Ihades of all thefe colours, and that you are obliged to match them to patterns, the proportion of Madder and Cochi- neal may be augmented or diminifhed. Hence is is impoflible to give any fixed rules concerning |his particular^ but from what has been already faid, it will not be difficult to difcover the belt method of fucceeding. I Ihall finifh this chapter with an experiment, from which 1 have obtained a tolerable purple without the help of cochineal j and alfo without having previouily given the cloth a blue dye, I boiled a bit of cloth, weighing about half an ounce. DYING WOOL. 169 ounce, with fix grains of Roman alum and fix grains of cryftals of tartar. At the expiration of half an hour I took it out, fqueezed it, let it cool, and then added to the dccodion twenty- four grains pf gmpet or beft Madder: when it had yield^ its colour to this water, yet im- pregnated \M[\ falts, I dropped into it twenty drops of the| folution of bifmuth, made with an equal quantity of water and fpirit of nitrci into this liquor I re-plunged the cloth, which in half an hour I took out, fqueezed, and wafhed. It appeared to be fufficiently complete 3 never- thelefs, to afcertain the difference which might be produced by an augmentation of the dye, I plunged it into the fame decoftion, and letting it boil for a quarter of an hour longer, obtained a purple tolerably bright. When tried by the proof of alum, it became brighter and more beautiful ; and when tried with foap, it re- mains a much finer red than the common Mad- der red. By keeping the cloth for feveral days moid in its preparation of alum and tartar, and then dying it in a frefh decoftion of Madder without falts, according to the ufual method, until it had imbibed a bright cinnamon colour, and having afterwards added to the liquor the fame folu- tion of bifmuth, I have obtained only a marone colour. This fhews the neceflity of being accu- rate in prefcribing rules for dying, and that for want of this accuracy the books publifhed on this art have been hitherto ufelefs. In this fecond experiment the cloth had im« jjibed too much of the falts ; and in the decoc- tion iro THEARTOF tion for dying, there was none.. The want of the alum prevented the purple from appearing ; becaufe the white earth of this fait was wanting to precipitate with the difTolved particles of the bifmuth, which, as I haye Ihown in my chapter of kermes, carry with them the blue particles of the fmak conftantly exifting in the mineral of bifmuth, a portion of which probably unites with this femi-metal in the melting. This mutual precipitation is produced in the operation of dying by means of the aftringency of the wpody par- ticles of the Madder root. CHAP. XVIIL Of Yelloiv, 'TpHERE are ten fpecies of drugs for dying •*' Yellow J but we find from experience that of thefe ten there are only five fit to be ufed for the good dye : neverthelefs, as yellow is a common colour in nature, there is no reafon why feveral others Ibould not be added to thefe five. I fliall at prefent, ■ however, fpeak of thefe five only, 'viz. Weld, Savory, Green-wood, Yellow wood, andFenugrec, becaufe thefe are of the good dye. The three firft plants are very common in the environs of Paris, and in moft of the provinces of that kingdom. The Bois JaunCy or yellow wood, comes from the Indies, and the Finugrec is common every where, Th« DYING WOOL. 171 Weld or wold yields the trueft Yellow, and is generally preferred to all the others. Savory and green-wood, being naturally greenifli, are the beft for the preparation of wool to be dyed green; the two others yield different ihades of Yellow. The fhades of Yellow, beft known in the Art of Dying, are ftraw colour, pale Yellow, lemon colour, and full Yellow. The common ' orange colours are not fimple, and therefore I Ihall not fpeak of them at prefent. For dying worded and fluffs Yellow, you make ufc of the ufual preparation, viz. of tartar and alum. You allow four ounces of alum to every pound of wool, or twenty five pounds to every hundred. With regard to the tartar, one ounce to every pound is fufficient for Yellow, though it requires two for red. The method of boiling is fimilar to the pre- ceding. For the welding, that is to fay for yellowing, when the wool or fluff has boiled, you make a frefli liquor, allowing five or fix pounds of weld to every pound of fluff; fome inclofe the weld in a clean woolen bag, to prevent it from mixing in the fluff; and to keep the bag down in the copper they put on it a crofs of heavy wood. Others boil it in the liquor till it has communicated all its colour, and till it falls to the bottom; the fluff is then fufpended in the net, which falls into the liquor; but others, when it has boiled, take out the weld with a rake, and throw it away. They fometimes mix yellow wood with $his weld 5 and fome dyers mix any of the other ingredients 172 THEARTOF ingredients, before fpecified, according to the Ihade required. By varying the proportions of th€ falts for the preparation, the quantity of the colouring ingredient, and the time of boiling, I am convinced that it is poflible to pro- duce an infinite variety of Ihades. I know it from my own experience, and from the experiments which I made with the flower of the virga aurea CanadienfiSj which would be a ufeful acquifition in the Art of Dying, fhould any one think it worth their while to cultivate this plant, as it throws out many fuckers, which are eafily tranf- planted. For regular fliades of light Yellows you pro- ceed as for all other regular fhadcs, only that light Yellows require a weaker preparation. For example, twelve pounds and a half of alum to a hundred pounds of wool is fufficient. The tartar fhould alfo be diminiflied, becaufe the wool is always wafled a little by the preparation, and that when you require only light fhades they may be as eafily obtained by a weaker preparation; thus you fave alfo in the expence of the falts. But thcfe light fhades do not fo well Hand the tefl as the darker fhades, which are dyed with the full proportion of tartar. Some dyers fuppofe that by letting their wool and fluff remain longer in the dye, they remedy this evil j becaufethey imbibe the colour more flowly in proportion to the weaknefs of the deco6lion : if you put wool into the dye, differently prepared, it will in the fame time imbibe different fhades. Thefe weaker preparations are called \\^\^ preparations or quar- ter preparations, and require great attention, 5 '' efpecially DYING WOOL. 173 cfpccially for light fliades of wool when dyed in the fleece for the manufadory of cloth and mixt fluffs, becaufe the wool is harder and more difficult to fpin, in proportion to the quantity of alum in the preparation. The fluff is confe- quently lefs fine. This obfcrvation is not how- ever of much importance with regard to wor- fleds for tapeflry, neither with refped to fluffs; but it is not much amifs were it only to fhew that the quantities of the ingredients, ufed in the preparation, are not fo very exadl j but that they may be varied without any rifque, whether to give the fame fhades to wool, prepared in different preparations, or whether to make but one preparation, if more convenient for different ihades. In order to dye with Yellow wood, it fhould be fplit, or rather fhaved with a joyner's plane: by this means it is more divided, confequently yields better, fo that a fmaller quantity will do. Prepare it as you will, it fhould always be tyed up in a bag, to prevent it from mixing with the wool, and from tearing the fluff. The Sa- vory and green- wood, when ufed infleadof weed, in order to vary the fhade, fhould be inclofed in the fame manner. The other five ingredients for dying Yellow I clafs with thofe for dying the falfe dye* With regard to the good dye I fliail here mention only the root of the Dock, the bark of afh, efpecially the fecond baric j the leaves of the almond tree, peach, and pear tree; in fhort, all aflringent leaves, barks, and woods. Thefe will produce good Yellows, more 174 THEARTOP more or lefs fine, according to the tinne they have boiled, and in proportion as the alunn, or tartar, predominates in the preparation. A larger quantity of alum makes it almoft as fine as the yellow of weld ; if the tartar prevails, the Yellow has more of the orange ; but if thefe roots, barks, or leaves, boil too much, the Yellow terminates in fhades of fawn co- lour. Though feveral Dyers are accuflomed for the good dye to ufe turmeric, a root imported from the Eaft-Indies, and which produces an orange Yellow, it is however blameable ; becaufe the colour very foon fades, at leaft if not fixt with marine fait, as praftifed by fome Dyers who carefully conceal this art. Thofe who ufe it for common fcarlet, in order to fave cochineal, and to give a lively orange red, are alfo reprehenfible j for, as I have already obferved, fcarlets dyed in this manner very foon loofe their bright orange caft, which darkens by the air. We are, however, obliged in fome degree to tolerate the deception j for this flaming colour being fo much in vogue, it were impof- fible to produce it otherwife, but by increafing the quantity of compofition, the fuperabundant acid of which confiderably injures the cloth. CHAP. DYING WOOL. 175 CHAP. XIX. Of Browfty or Fawn colour, 'TpHE Fawn colour, root or nut colour, is ■*■ the fourth primitive colour in tlie Dyer's clafs. It is fo clafled, being introduced into a great number of colours. It requires a very- different procefs from the others, becaufe the wool, to be dyed a Fawn colour, has fcarce ever any preparation, otherwife than being foaked in warm water, in the fame manner as for blue. For dying Fawn colour you make ufe o{ the green Ihell of the walnut, the root of the walnut tree, the bark of the alder, Santaly Sumac, Roudoul or FoviCj and foot: The green fhells of the walnut, collefted when the nuts are perfedjy ripe, and put into tubs or cafks, and afterwards filled with water, are in this manner preferved till the year follow- ing. The fhells are alfo ufed before the nuts are ripe ; but thefe fhould be faved apart, in order to be firfl ufed ; becaufe, as the foft Ihell which adheres putrifies, it will keep but for two months only. The Sanial or Saunders is a hard wood imported from the Indies, generally ground into a very fine powder, and preferved in bags j becaufe it is fuppo- fed to ferments by which it is thoughtto be greatly improved; but I have never obferved any dif- ference. This ground wood is generally ufed with one third of Cariatour wood, by which, in the opinion of thofe who prepare it for fale, it is much improved. It is however nothing like 176 THE ART OF like fo good as the walnut fliells ; becaufe, if iifed in too large a quantity, it ftifFens con- fiderably, and thereby injures the wool; hence it were bed not to ufe it, either for wool or fine Ituffs, except in the (lighter lhades,where it would not havd fo bad effe£t. It is generally mixed with galls, alder bark, and fumach, as by this means only you can obtain its colour when not mixed with the Cariatour. It yields but very little with the preparation of alum and tartar, efpecially if it be not chipped; but, notwith- flanding thefe dcfe<5ls, it is tolerated in the good dye on account of the Iblidity of its colour, which is naturally a yellow red brown. The air makes it deeper, and foap lighter. It lofes but little by atryal of alum, and ftill lefs by tartar. Of all the ingredients for dying Fawn colotirs the walnut rind is the beft. Its Ihades are finer, its colour folid, and by making the wool flexible, renders it lefs difficult to work. It is prepared in the following manner. You fill a cauldron half full of water, and when it grows warm, you add rinds in proportion to the quan- tity of fluffs to be dyed, and to the colour required. It is then boiled, and when it is boiled for a quarter of an hour, the ftuffs, having been previoufly moiftened with warm water, are dipped ; they are then turned and well flirred, till they have imbibed the colour defired. If for worfteds, requiring an exafl afibrtment of Ihades, you put lefs walnut rinds, and begin with the lighteft fhades. You put more walnut rinds in proportion as the colour is exhaufted, and then dip the darkeft Ihades, With regard to ftuffs, you generally t)YING WOOL. 177 generally begin with the deepeft, and as the colour of the dye diminiflies, you dip the lightcfl. They are aired as ufual, dryed, and drefled. The root of the walnut tree is, next to the hufk, the bed dye for Fawn colour : it alfo gives a very great number of fhades, nearly refembling thofc of the hulks ; hence they may be fubftituted for each other, but the root requires a different f>roCefs. You fill your cauldron three quarters full of river water, putting in the root, cut fmall, in proportion to the quantity of wool to be dyed, and to the fhade required. When it is very hot, you dip the wool or iluff, turning and re-turning it as before, remembering to air it from time to time J and, if ftuff, to draw it through tlie hands in order to (hake off the fmall bits of the root, which might elfe fpot the ftuff. To avoid thefe fpots, the root fhould be tyed in a bag, in the fame manner as the yellow wood. You after- terwards dip the lighter ftuffs, and fo on, till the colour of the root is exhaufted. If "worfted, you always begin with the lighteft, as for other colours j but of all things you muft be careful to keep your liquor from boiling at the beginning, as in that cafe the firft piece of ftuff would imbibe all the colour. The method of dying with roots is not very eafy j for if you are not very attentive to the de- gree of heat, to turning and returning the ftuffb or worfteds, fo as to dip them equally, you run ,1 rilk of their being eitlier too dark or fpotted, for which there is no remedy. In this cafe, the only refource is to dye them marone, prune, or N coffee 178 THEARTOF coffee colour, as I have already obferved, whert^ fpeaking of colours and fhades, refulting from a mixture of Fawn colour and black. In order to avoid this evil, you muft keep the fluffs con- tinually turning on the reel, and dip them only piece by piece, nor let the liquor boil till the root has yielded all its colour. The worftcds or fluffs, dyed in this manner, fhould be aired, well wafhed, and dried. I can fay nothing more concerning the bark of alder, than what I have already obferved with re- fpeft to the root of the walnut tree, only that letting it boil at the beginning is not of fo much confequence, becaufe it yields its colour lefs free- ly. It is generally ufed for worfleds and colours darkened with copperas. It neverthelefs produced a good effe(5l on wool not intended for colours cxtreamly dark, and perfedlly withftands the power of the air and fun. Sumach is nearly of the fame nature, and ufed in the fame manner as the hufks: its colour is not fo deep, and is rather greenifh. It is for dark colours frequently fu&flituted for nut galls; but a greater quantity is requifite. Its colour is alfo perfedlly folid and permanent. Thefe diffe-. rent fubllances are fometimes mixed together, and as they are equally good, and produce nearly the fame effedl, there is no great difficulty in ob- taining certain fhades. We mufl, neverthelefs, be diredled by cuflom in the production of thefe Fawn colour fhades, which abfolutely depend upon the eye, and which are not difficult to manage. With JCrYING WOOL. 179 "With regard to the mixing of thefe ingredients With ground Jantaly you put four pounds of the latter into the copper, half a pound of nut- galls pounded, twelve pounds of alder bark, and ten pounds of funfiach j (thefe quantities will dye 25 or 27 ells of cloth). The whole is boiled, and having checked the boiling with a little cold water, you immerfe the cloth, turning and re- ftirring it for two hours j it is then taken out, aired, and wafhed in the river. You afterwards dip fome more ftufF in the fame decodion, if you want a lighter fhade; and in this manner you may contrive fo long as the liquor retains any colour. The quantities of thefe ingredients are augmented, or diminiflied, in proportion to the depth of the fhade required, letting the wool or ftufF boil accordingly. J have already obferv- ed, that there is no other method of obtaining the colour of thtfantal or faundefS. I have here mentioned the faunders, and the me- thod of ufing it, though perhaps it would have been iTiore feafonable when treating of the falfc dye, confidering that this wood, fhould never be tifed but for low priced ftiiffs. Neverthelefs, as it is employed almoft in the fame manner as the other ingredients for Fawn colours, and as there are many provinces, where it is tolerated in the good dye, becaufe it withftands the weather, I thought it might be as well to men- tion the method of ufing it in courfe with the othet- ingredients. I fliali for the fame reafon defcribe alfo the manner of dying with foot, though permitted only for the falfe dye, hav- ing lefs folidity than the others, and becaufe N 1 i8o THEARTOF it hardens the wool, and gives fluff a veiy drfa- ereeable fmell. The foot and water is generally put into the copper at the fame time, and the whole well boiled. The fluff is then immerfed, and more or Icfs boiled according to the fhade required j it is afterwards taken our, and cooled, and thofe in- tended for the lighefl iliade are then put in; they are afterwards well wafhed and dried. But the befl method is to boil the foot in the water for two hours, to let it fland afterwards, and then to empty the liquor into another copper, without mixing the foot. The wool and fluffs are then dipped in the liquor, and are thereby lefs hardened than if they had been mixed with the foot s but this does not render the colour more permanent, and in- deed it were better never to make ufe of this in- gredient, except for ftuffs of little value, efpeci- ally as it can be fupplied by other ingredients which I have mentioned above, and which give s. better and more lafling colour, and are befides more foftening to the wool. In the dye they frequently employ the green walnut (hcU, and the root of the walnut tree for their Fawn co- lours. Thefe two fubflances are ufeful both for the greater and lefler dye : there are, however, places where it is difficult to meet with them, and where they are therefore obliged to make life of faunders, and even of foot. The reafons which 1 have above given for the folidity of true colours may feem to be con- tradidled by this method of dying, in which the colour adheres permanently to Fawn colours, without DYING WOOL. i8r "vrithout the previous preparation of alum or tartar, confequently without introducing into the pores of the fibres a fait capable of being harden- ed by cold and of retaining the colouring atoms. Bur, if we examine the green fliell of the walnut, the root of the walnut tree, the bark of the alder, by a chymical analyfis, befides their well known allringent qualities, we fhall find, by dccom- pofing them according to art, that they contain a vitriolated tartar, a fait, which is neither calcined by the fun, nor difiblved, except by boilino- water, and we fliall then perceive, that thefe in- gredients are of themfelves fufficient to produce efFefts equal to thofe drugs whofe colours cannot be folidiy applied, without the afllftance of a fait, capable of retaining the colouring atoms. Soot does not give a colour fo permanent, becaufe it contains only a voktile and marine fait, eafily diflblved. In fliort, foot, being compofed only of the lighteft, and mod volatile particles of combuftible bodies, ufed as the pabulum of fire, cannot raife a vitriolated tartar, which does not become volatile by heat, and which, befides, rarely exifts in the wood ufually burnt in our chimnics. CHAP. XX,. Of Black. "DLACK is the Dyers fifth primitive colour, •*-' It includes a prodigious quantity of (hades, beginning from the lightcft grey, (Tr pearl colour, N 3 ta i«i THEARTOF to black. On account of thefe fhades, it \^ ranked amongft the primitive colours, for the greateft number of browns of whatfoever fhadq they be, are finifhed in the fame dye, which would dye white wool a grey, more or lefs dark. This operation is called browning. I Ihall fpeak of this when I come to treat of the fhades refulting from a mixture of the primitive colours ; but I iTiaU now give the method of dying wool a fine black. For thi? , purpofe, I fliall be obliged to fpeak of a procefs ufed in falfe dying. In order to dye fluff a fine black, it Hiould be begun by a great Dyer and finifhed by a Dyer of the kjer dye. Stuffs fhould be firft dyed, when intended for black, a mazareen blue, as deep as pofTible, called the bafis or ground, which fnould be exe- cuted by great Dyers, and in the fame manner as 1 have direfted in my chapter upon the blue. The ftuff fhould be wafhed at the river as foon a^ it comes out of the woad vat, and fhould be well fcowered in the fulling mill. The wafhing is of great importance, becaufe without it the lime in the liquor fpots, and injures the ftuff. It is alfo very neceffary to fcower it in the fulling mill, clfe it blackens the linen and the hands, as is frequently the cafe When it has not been fuffi- ciently fcowered. After this preparation, the fluff is finiflied and blackened, which is performed in the following manner, in the lefTer dye. For a hundred weight of cloth or fluff, which, according to the regulations, fhould have had 4 grey blue ground, you put into a moderate I cauldron DYING WOOL. 183 cauldron ten pounds of logwood, cut into chips, and ten pounds of Aleppo galls pulverifed, the whole enclofed in a bag: thefe ingredients are boiled in a fuflficient quantity of water for twelve hours. A third part of this liquor is emptied into another cauldron, with two pounds of ver- digris; the fluff is then entered and turned for two hours without ceafing. It is neceffary to obferve that this liquor fhould boil very flowly; or it is ftill better to keep it very hot without boiling. The fluff is then taken out, and the fecond third of the liquor thrown into the copper to the firft third, with the addition of eight pounds of copperas. The fire under the cauldron is diminiflied, and the copperas left to diffolve for half an hour, let- ting the liquor cool, after which the fluff is kept turning an hour; it is then taken out and cooled. The refl of the liquor is then mixed with the two firft thirds, carefully fqueezing the bag well. To this is added fifteen or twenty pounds of fumach : you give it another boil, and then cool it with a little water; having pre- vioufly added two pounds more of copperas, you again turn the ftuft' for two hours j it is then taken out, cooled, and again put into the caul- dron, turning it conftantly for an hour lunger. After this it is carried to the river, well walhed and fcowered at the fulling mill. When it is thoroughly fcowered, and that the water comes out of it clear, you prepare a frefh liquor with as much weld as you think proper; you give it one boil, cool it, and dip the ftuff. This U^ deco<5lion foftens and confirm^ i: a very N ^ fine i84 THE ART OF fine Black. For the moft part, however, they do not take fo much painsj but are fatisfied, when the cloth is blue, to dip it in a decodtion of nutgalls, and tq let it boil for two hours. It is afterwards wafhed, and fome copperas and logwood added to the liquor; after which the fluff is again dipped for two hours, and then waflied and fcowered. I have aifo dyed in the following manner: for fifteen ells of cloth, previoufly dyed blue, I had a pound and half of yellow wood, five pounds of logwood, and ten pounds of fu- mach, put into a cauldron. In this the cloth boiled for three hours j after which it was taken out, and ten pounds of copperas thrown into the copper. When the copperas was diffoived and the liquor cooled, the cloth was put into it for two hours ; it was then taken out and cooled, after which it was again im- merfed for an hour, and then waflicd and fcow- ered : it was tolerably fine, but not lb velvety as the preceding. It was commanded by the ancient Regulations^ that ftuffs fhould be maddered after they had been blued, and before they were dyed Black. Defirous of afcertaining the advantage refulting from this procefs, I took a bit of cloth which had been dyed blue, this being divided, one half was boiled with alum and tartar, and afterwards maddered. It was then blackened in the fame liquor with the other half which had not been maddered conformable to the fir fl^ of the two methods juft defcribed. They were each of them ^ very beautiful Black: it neverthelefs appeared DYING WOOL. tJ5 appeared that the maddered liufF had a reddifh call : the other Black was certainly more beauti- ful, more velvety, and much finer. There is, indeed, lefs danger of the maddered ftufFs foiling the hands and linen, becaufe the alum and tartar of the preparation had carried off all the loofe particles. This advantage is not however fuffi- cient to make amends for the inconvenience of maddering, as the fluff is always in fome degree injured by the alum and tartar, and as the madder gives it a reddifli caft difagreeable to the eye, and, befides, this operation raifes the price of the dye to no purpofe. Some Dyers, to avoid thefe incoveniencies in part, madder their cloth without having pre- yioufly boiled it in alum and tartar. But 1 have already fhewn that madder ufed in this manner has no permanency; hence I cannot per- ceive the advantage refulting from fo bad a prac- tice. Black is fometimes dyed without having given it the blue ground; and this method of dying was permitted for light or thin fluffs of inferior value, confequently not confiderable enough to bear the expence of a deep blue previous to their being dyed Black. It was however ordered at the fame time to give thefe fluffs a ground of the green walnut fliell, or of the root of the walnut tree, to avoid the neceffity of blacken- ing them with too great a quantity of copperas. This procefs intirely regards the falfe dye ; never- thelefs as it was alfo allowed to other Dyers, ;his feems the proper timp to mention it, efpe- cially j86 THEARTOF cially as I am fpeaking of colours appertaining to both. This procefs is attended with no nnanner of difficulty. The cloth, as we have already ftcn in the chapter upon Fawn colour, is pre- pared with the green walnut Iliell, and after- wards blackened in the manner I have already defcribedj or as near it as poflible. For with Black, as with fcarlet, moft Dyers fuppofe that they are pofleffed of a fecret for dying a much finer Black than any of their fraternity; this, however, confifts in augmenting or diminilhing the quantities of the fame ingredients, or in fubllituting others which produce the fame cfFed. I have myfelf tried feveral methods, and fancy that what is ftriftly meant by fucceeding to per- feftion, depends rather on the manner of work- ing, handling, and airing the ftuff properly, than upon the exaft quantity of the ingredients. For this reafon I have been more particular than may be thought necelTary in my defcription of what appeared to me to be the bed method. It may not in this place be improper to explain the reafon of the neceffity of giving fluffs a blue, or at leall a root colour ground, previous to their being dyed Blackj and why the dying white Black is exprefsly prohibited, becaufe in that cafe ic is necefTary to ufe a much greater quantity of nutgallsj this would indeed be no great evil, as nutgalls of themfelves do not injure the wool; but in order to overcome this gallf according to the workmen's phrafe, that is, to bUcken it, or properly fpeaking, rather t9 DYING WOOL. 187 to form an ink on the fluff, it requires a greater quantity of copperas, which not only hardens the fluff, but, fronn the acidity impreffed on the fibres of the wool by this fait, makes it brittle: on the contrary, when the fluff has had a ground, that is to fay, a flrong layer of fbme deep colour, there is much lefs occafion for cither. Blue is preferable to any other colour j firfl, bccaufe it is the nearefl to Black, which is in fa6l only a deep blue; and, fecondly, as there is no occafion for any other preparation than previoully boiling the wool, the fluff is in no refped injured. For the fame reafon, viz. the prefervation of the wool, the root colour is fubfticuted for inferior fluffs, inflead of the blue, which would enhance the price; it is therefore heceffary that this root colour ground fhould be as deep as pofTible; becaufe the darker it is there is occafion for lefs copperas to complete the Black. It alfo frequently happens that when fluffs of any colour are badly dyed, or fpotted, they are dipped in Black: it is however advifeable to dip them firfl in blue, unlefs the colour be very dark, in which cafe they would take a very fine Black ; but this is the lafl refource. Thefe fluffs arc not commonly dyed Black, if it be poffi.ble to make them any other colour; becaufe, having been prepared with alum and tartar for the firfl colour, the copperas requifite for the Black would confiderably injure and greatly diminifh pheir quality. The i88 THE ART OF The fhades of Black are greys, from the darkcfl: to the lighted. They are of great ufe in the arc of dying, as well for their own colours fimply as when applied to other colours, which is called darkening ; but I fhall fpeak of thefe more parti- cularly when treating of their mixture with the primitive colours. At prefent I fliall confine rayfelf to greys only, and confider them as ihades proceeding from Black j relating the two me- thods of producing them. The firft and mofl general method is to boil fome pounded nutgalls with a proper quantity of water for two hours; at the fame time dif- folving fome copperas in a little water fepa- rately. Having prepared a cauldron of liquor fufficient for the quantity of wool or fluff to be dyed, you add to it, whilfl the water is too hot for your hand, a little of the decoftion of the nutgalls with thefolution of copperas. The fluff intended for the lighted grey is then dipped. When fufHciently coloured according to your defire, you add fome freih decoftion of nutgalls with fome of the infufion of the cop- peras, and then dip the next fhc^de. In this manner you proceed to the darkefl fliade, conflantly adding thefe liquors, from the tawny grey even to Black s but it is much better to give the tawny grey, and the extream dark fliades, a blue ground, more or lefs as you like, for the reafon abovementioned. The fecond method of producing grey is in my opinion preferable i becaufe the juice of the galls is better incorporated with the wool, and that you are thereby fure of ufing no more cop- peras DYINGWOOL. iS^ peraS than is abfolutely necefifary. It even ap- pears from the experiments I have madej that the greys are more beautiful and the wool brighter. It alfo appears to be equally folidj for they are both of them equally proof, againft the air and fun. What determined me therefore in favour of the fecond method is, that befides its being much lefs prejudicial to the quality of the wool, it is attended with no more difficulty than the firfl. You boil a fufficient quantity of nutgalls, well pounded and inclofed in a clean linen bagj you afterwards put the wool or fluff into thia liquor, letting it boil for an hour, moving and ftirring it about, after which it is taken out. You then add to the fame liquor a little copperas diffolved in a part of the folution, and then dip the woolens intended for the lighted fliade. You again add a little of the copperas folution, continuing in this manner as in the firft operation, till you come to the darkefl: fhades. In either procefs, if not reftrained by patterns, you may catch the precife fliades, beginning with the dark and finifliing with the light, in pro- portion as the liquor becomes exhaufted of its ingredients J keeping the pieces of fluff or wool immerfed for a longer or fhorter time, till the fluff takes the colour defired. It is as impoffible to determine the quantity of water neceffary for thefe operations, as it is to fpecify the quantity of the ingredients, or the time for letting the wool remain in the liquor. The eye muft judge of thefe things. If the liquor be llrongly impregnated with coJour, 19* THeARTOF colour, the wool will imbibe the Ihade in a Short timci but, on the contrary, it muft remain longer if the liquor be exhaufted. When the: wool is not dark enough^ it is dipped a fecond time, a third, or even more, till it is of a fuf- ficient colour -, the only neceflary attention is to prevent the water from boiling. If it be by chance too deep, the only remedy is to dip thci fluff in afrelh warm liquor, adding to it a little of the decoftion of nutgalls. This liquor car- ries off a part of the precipitated iron of the copperas J confequently the wool or ftuff be- comes lighter. But the beft way is to take it out of the liquof from time to time, not leaving it in long enough to imbibe more of the colour than required. It may alfo be dipped in a folution of foap or alum? ibut thefe correctives deftroy a great part of the! colour, fo that it is often neceffary to darken it again 5 by this means the wool, which fuffers greatly by the reiterated a6bion of thefe ingre- dients, is injured, , All greys, however dyedj^ Ihould be well wafned in a large flream, and the darkeft even fcowered with foap. Thefe dingy Ihades, from the lighteft to the darkeft, are produced by the fame operation from which common ink is obtained. The green vitriol contains iron j were it blue, it would con- tain copper. Pour a folution of this green cop- peras into a glafs, holding it in the light, and dropping into it fome of the decoftion of nut- galls. The firft drops that fall into this limpid folu- tion of ferruginous fait, producesa reddifh colour^ the next turns it bueifh, then a dufky violet cok>ur> DYING WOOL. 191 colour, and at lad it becomes a dark blue, almoft black, which is called ink. To this ink add a quantity of pure water; let the vefiel reft for feveral days, and th^ liquor by degrees becomes clearer and clearer, till it is almoft as limpid as common water, and, at the bottom of the vef- iel, you will perceive a black powder. Having dried this powder, put it into a crucible; calcine this, and put to it a little fuet, or any other fat, you will obtain a black powder which may be attracted by the loadftone. This, therefore, is iron ; this is the metal which blackens the ink, and this, when precipitated by the nutgalls, lodges in the pores of the fibres of tlie wool, di- lated by the heat of the liquor, and contra(5led when the ftuff is expofed to the air. Befides the ftyptic quality of the nutgalls, by which they have eminently the property of precipitating the iron of the copperas, and producing ink, they alfo contain a portion of gum, as may be afcer- tained by evaporating the philcereddecodlion.This gum being introduced into the pores with the ferruginous atoms ferves to retain them; buc this gum being eafily foluble, it has not the tenacity procured from a fait more difficult of folution ; therefore thefe dark colours have not the folidity of other folid colours prepared in a boiling folution of alum and tarta!% and therefore plain greys have not been fubmitted to the ufual trial. Thus have I, to the beft of my knowledge, given the beft methods of producing what the Dyers call primitive colours; or at leaft thofe which they fuppofe moft deferving of that appellation, as i^i THE ART dF as from their mixture and combinations, all otlief colours are derived. I fhall now begin with the fimple combination of two colours, in the fame order in which I have defcribed them fingly. When I have given the colours refulting from their firft degree of combination, I fhall join them by threes j continuing in the fame manner, till I have exhibited every colour exifling in nature and imitated by art. CHAP. XXI. 0/ the colours obtained from a mixture of Blue and Red. ^ TT7HEN fpcaking of red, I obferved, that ' ^ there were four different fpecies in grain. We (hall now fee what thefe reds produce when applied to a fluf? previoufly dyed blue. A blue fluff boiled in alum and tartar, according to my dire6tions in the article concerning red, and afterwards dyed with the kermes, the refulc will be the King's colour. Prince's colour, Violet, Purple, and feveral fuch colours. But, for thefe colours, they feldom make ufe of kermes on account of its high price, and the quantity re- quired, and becaufe the fame colour produced by cochineal and madder are both finer and obtained with lefs difficulty. Befidcs I have already remarked, that kermes is not much iri life, though it produces feveral compound co- lours with good effefb, as will be more particu- larly Ihown in the fequel. When kermes is ufed in order to apply red to blue, it is of no confe- quence whether the blue ground be given before or DYING WOOL. 191 br after the llufF has been dyed red, the red of kermes being too permanent to be changed either by the lime of thewoad vat, at lead if not overcharged, or by the pot-afh of the indigo vat. If, therefore, the woad vat be not too old, you may begin with either of the two colours as you like, or as you fhall think moft fuitable to the fhade required. It is eafy to con- ceive, though I have mentioned but a very fmall number of colours, that from thefe two prin- ciples a very large quantity of fhades may be obtained, according as the one or the other predominates. You never mix blue with fire colour fcarlct, or tviththe fcarlet of Goblins, in any of their fliades. In order to difcover the caufe of this, I dipped a bit of fcarlet cloth in the blue vat, and dyed a fecond bit according to the fcarlet method, having previoufly dipped it in the blue vat. They each of them fucceeded very ill, and pro- duced a dufky marbled violet colour, as if tiie two colours were not well united^ and had been applied feparately to different parts of the wool. This was doubtlefs occafioned by the acids in the compofition of the fcarlet. But I ihall not now examine this operation phyfically, as it would produce a tedious differtation j the fad is fufficient. It proves the impofilbility of procuring a fine colour from a mixture of blue with fcarlet, unlef* the fcarlet be dipped in a folution/of alum, by which the acid of the com- }5or]tion would be deftroyed; but then it would be crimfon, a colour very different from fcarlet; O the 192 THE ART OF the procefs of which I have given in a particular chapter. A mixture of blue and crimfon produces colom- bine, purple, amaranthe, penfy, and violet colour. Thefe colours alfo produce a very great number of ihades, which vary according as the colours from whence they are derived are more or lefs dark. I have been fo minute in my dirediohs for the management of the primitive colours, that it is impoflible for the leaft difficulty or embarralT- ment to occurin the execution of compound co- lours. The fluff and worllcd beingof one colour, it is afterwards dyed another, precifely in the fame manner as if it had been quite white. You muft only obferve, in the prefent cafe, to dye the ftuff blue before you dip it crimfon; becaufe the alkali of either of the blue vats confiderably tarnifh the brightnefs of the cochineal. Take notice, that in producing violet, purple, and fuch like fliades, to obferve what I have already faid concerning crimfon; becaufe thefe colours have no vivacity or brightnefs, if not managed ■with all the preciiutions neceflary towards the produ6lion of a fine crimfon. Blue and the red of madder produce king's pur- ple, &c. but much inferior to that obtained from the kermes; becaufe the red of this root is always tarnifhed by the colour of its woody fibres. The minime, tan-colour^ a7naranthe and the dry roje colour y are always lefs lively than if obtained from the kermes. It is neverthelefs fometimes mixed with madder, as I have already faidj in order to produce fcarlet half-grain; and the colours procured from it are much finer than thofe bYING WOOL. 193 thofe bbtained from the madder only, applie4 to a blue ftuff. Madder mixed with cochi- heal, as for half-crimfon, gives a vail number of fhades, which bear fome affinity to thofe already mentioned ; but which it were impoffible to fpecify particularly. Some of them are as fine as thofe produced by more expenfive ingre- dients. As it is incumbent on Dyers to attend to their own advantage, they will not make ufe of the deareft when it is pofllble to produce the fame effect with common ingredients. It is dif- ficult to give particular inftru6lions upon a prac- tice that mult be acquired from experience only. Old madder and cochineal liquors are frequently pfed when the colour is not entirely exhaufted^ . they produce a very good colour, and fave a confiderable expence. With regard to this, however, I can fay nothing pofitive, as itseffecT:s depend on the quantity of colour remaining in the liquor, and on the degree of fhade required* CHAP. XXII. 0/ the mixture of Blue and Tdlow^ TT is impoffible to obtain more than one colour ■*■ from a mixture of Blue and Yellow, which is green; but this colour comprehends an infi- nite variety of Ihades, the principal of which are, Tellozv G'reefij Pale Gree?!, Bright Green, Grafs Green, Laurel Green, Olive Green, Sea Green, Parrot Green, and Cahbnge Green. To thefe may be ^ddtd Duck' s-lFing Green, and i"^*^ Gr^^« without blue. Tl^efe iliades, with tlieir intermediate O 2 ones. 191 THE ART OF ones, are produced in the fame manner and with the fame eafe. You take ftufF or wool, either a dark or light blue, and having boiled it in alum and tartar, as you would white ftufF for common yellowj you afterwards dye it with weld, favory, or greening wood. Thefe feveral fub- ftances are equally good with regard to their folidity; but as they give different Yellows, the green refulting from their mixtures are alfo different. Weld and favory give the fineft Greens. ForYellow green fliades the ftuff fliould be a fine light Blue, boiled with the common quantities of alum and tartar, in order to receive the Yellow ; as without thefe falts the colour would not be permanent. For Cabbage or Parrot Green, the Blue (hould be very deep; but as it ought to have but a tinge of Yellow, the ftuff will require but half the boiling. Even a quarter of the falts of a common preparation is fometimes fufficient, as I have already explained. The workmen, for thefe kind of colours, feldom weigh the falts, judging by the eye the quantity fufficient for the ftiade required. Conftant pradtice will in fome degree make them tolerably exad; but it were to be wiftied, that they would not truft to the eye in this particular. I know from experience, that thefe Blue-Green ftiades are produced as well, by giving the ftuff the ufual preparation. The Yellow afterwards applied is much more folid J but then there is much lefs weld or other colouring fubftance required, neither fhould the ftuff be left fo long in the liquor. Neverthelefs there are two reafons to the con- trary : DYING WOOL. 195 trary : the firft, and moft interefting to Dyers is, that they fancy they confume a greater quan- tity of ingredients than neceflary; and the fecond, that the fmaller the quantity of alurn, the more you preferve the foftnefs and quality of the wool ; and alfo that the firft blue dye is Jefs impaired, as the alum always deadens the blue obtained from the woad. Hence I am of opinion, that in this particular, the Dyer fhould be at liberty to regulate the ftrength of his preparation by the depth of the colour re- quired. I have faid that in order to dye green the wool Ihould be previoufly dyed blue ; becaufe it is my opinion, that when the colours are thus ap- plied, the green is more durable, and that the colour would not be fo fine were it otherwife. I was convinced of this in dying the greens of which I have been fpeaking. I found that they all flood the weather. Thofe which were (irft dyed Blue were the leaft afFe6led; but with reg-ard to the trial-liquors there was evidently much lefs difference. Neverthelefs, whenever it is neceflary, the Dyer fliould be allowed to dye their fluffs Yello'.v firft j but then thefe foil the linen much more than the others ; becaufe when the blue is firft given, the loofe particles are wai"hed off' by the alum preparation. The beft remedy for this defeat is to have the green well fcowered whei'i taken out of the vat, by which means it will be ren- dered like the Blue mentioned in the tenth phapter, O 3 King's 196 THE ART OF King's Blue cloth dipped Green with the flower of the Virga aurea Canadienfis^ becomes a very fine green, provided the ftufF is boiled in a folution of three parts alum and one part white tartar. This green is equally permanent as that dyed with weld. I have alfo greened blues with the bark of afh tree pulverifed; this is perfeflly folid, but not fine, and therefore of no ufe except for particu- lar colours. The leaves of the almond, the peach, and pear tree, &:c. as they furnilh yel- lows, may ferve for thofe green Ihades which it may be difficult to hit immediately with the ingredients hitherto employed for dying Yellow. A kin^s V«ue ftuJfF, well fcowered, and after- wards boiled in a folution of four parts alum and one part tartar, takes a fine dark green of the duck's wing fhade, if it be boiled for two full hours in a vat with a fufficient quantity 'of the root oi La-pat nm folk aciUo^ (harp pointed dock grofsly powdered. This root is alfo a good acquifition in the art of dyingj for it will, without any other addi- tion than the preparationy give an infinity of fhades, from the paleft yellow to a tole- rable olive colour J it requires nothing more than to increafe or diminifh the quantity put into the vat, and to boil it from half an hour to three hours. All thefc ihades withftand the trial of boiling. I would ftrongly recommend the cultivation of this root in moift places, and the ufe of it in dying, as it is already ufed in medicine^ efpecially for the poor. Sea DYING WOOL. 197 Sea green, a particular colour, and much, the tafte of the people of the Levant, may be made perfc<^ly folid by giving the (tuff a Blue ground ; but this Blue fiiade fiioujd be vc'ry feint, icarcely exceeding a bluifh white, which it is difficult to dye equal and uniform; but when you have obtained this (l:iade, the Vh-ga aura above- mentioned is better for giving the yellow tinge than the weld But this Virga aiirea is not yet known to the Dyers of Languedoc, by whom thcfe kind of colours are chiefly made -, and befides, the blue fhade required being very diffi- cult to obtain, they arc fometimes permitted to dye Sea Greens with verdigris, though this co- lour is claflTed amongft the falfe colours. The Dutch ni^jl? this colour very well, and more iblid than^fcfual with verdigris. Tlie following is their method of proceeding : It requires two cauldrons placed at a little diftance from each other. In one of thefe caul- drons you put for two pieces of cloth, of about forty- five or fifty ells long, eight or ten pounds of white foap fhaved, which fbould be perfeftly diflblved. When the vat is ready to boil, the ftuff fliould be immerfed, and fuffe- red to boil for a good half hour. You prepare another liquor in the other cau'dron, and yA\^vi it is quite hot you put into it a clean linen bag, containing eight or ten pounds of blue vitriol, and ten or twelve pounds of lime, each of them pulverifed and well mixed together; for ir i:. necelTary that this mixture be as accurate as pofTible. This bag fliould be moved about in O 4 the igS THEARTOF the hot water, but not boiling, till the vitriol is diflblved. You Ihould then fix on the two forks a winch made as ufual, but which Ihould be carefully wrapped round with a clean linen cloth very tight and well fewed. One end of the cloth is fixed on the winch which is turned fwiftly round, that the cloth rnay pafs quickly from the foap cauldron into the cauldron with the vitriol j it is then turned more flowly, that the cloth may have time to imbibe the particles of copper, which, by means of the lime, were difi^ufed in the liquor, by feparating and precipitating them from the blue vitriol in which they were coa- tained. The cloth is left in tjiis liquor, which Ihould never boil till it has taken the Sea Green ihade required. It is then taken out, drained on the winch, and aired by the lifting. It ihould then hang till it is perfectly cold before it is wafhed at the river. If it touches wood before it has been wafhed it will fpotj for this reafon the winch is covered, and for the fame rea- fon the horfe fhould be alfo covered before the cloth is folded over it. CHAP. XXIII. Of the mixture of Blue and Fawn cclour. 'nr^HE olive fliades refulting from Blue and •*' Fawn colour are of very little ufe, except in the fabrication of tapcftry. There is no difficulty in making them when required; and it is abfolutely indifferent whether you begin by dipping DYING wop t. 19^ dipping your worded Blue, or Fawn colour; if the latter, you fhould be careful to rince your worfted, which fhould be always obferved with regard to Blue, and and alfo for fuch compound colours as are compleated in the Blue Vat. \Vhen you would produce thefe colours, it 15 equally indifferent which of the Fawn colour fubftances you ufej the preference being due to thofe only, which give the fhade requixed with ;he lead difficulty. F CHAP. XXIV. Of the mixture of Blue and Black, ROM this mixture there is no particular lliade to be obtained as the Grey only dark- ens the Blue, which may be better effeded by giving them the fhade required, in the Blue Vat. You may neverthelefs by a mixture of Blues and Greys, which are numbered amongft the Black (hades, as I have obferved in Chap. XX. produce Tawneys. In this cafe the Blue fhould not be very deep, and the procefs is then the fame as for Black, only that as the colour is not quite fo dark you Ihould not put fo much copperas; but, as I have before faid, this colour fhould be con- fidered only as a black fhade. Hence it may be truly faid, that no fhade can be obtained from Blue and Black only, and but very few from Blue ^.nd Fawn colour. CHAP. 2ft« THE ART OF CHAP. XXV. Of the mixtures of Red and Yellow, CCARLET of kcrmes and Yellov/ produce Aurora, couleur de Soiici, and orange colour. When the wool has been boiled in alum and tartar it may be dyed in one of thefe colours, .and afterwards dipped in the otiier, or it may be dyed at once, by mixing the kermes with weld, favory. Sec. But the precife fhades are more eafily obtained by the firft method, as the wool or ftufF may be dipped, alternately, till it has taken exaftly the Ihade required. From common fcarlet, or fcarlet of Goblins and yellow, you procure lobfter colour, and the colour of the pomegranate flowerj but they are not very permanent : they are dyed in the following manner. You begin with the fcarler juft as 1 have before direfled, that is, by boiling with cream of tartar, cochineal, and the com- pofition: it fhould then be taken out, cooled and wafiied at the river. In order to finifh, you muft prepare a frelli liquor as for fcarlet, only lefTening the quantity of the cochineal, and fub- ftituting a little ground yellow wood, I cannot however fpecify exaftly the quantity either of the cochineal or yellow wood, as that depends upon the colour required. If an orange colour, you add a greater quantity of the yellow v/ood, diminifhing the cochineal in proportion. I have endeavoured to produce this colour by three different methods, and fucceeded ia them all. The firft method I have juft defcribed. The DYING WOOL. aot The fccond is to fubftitute fuftic for ycilow wood, which is a confiderablefaving of cochineal, being much more upon the orange than yellow wood; but this ingredient wants folidity, and fliould never be ufed but for falfe colours j fo that it is tolerated in Languedoc for dying cloth the lobfter colour, fo much admired in the Levant, only becaufe the colour obtained from it is more beautiful than that produced by the yellow wood. The third method of procuring the lobfter colour, with cochineal only^ is by augmenting the quantity of the compofition, according to the degree of orange required, but this method is attended with very great inconvenience. In the •firft: place, it enhanccs'the price of the colour, as it requires more cochineal than common fcarlet ; becaufe the acid of the compofition in fome degree lefiens its ftability. Secondly, for the fame reafon, the colour always appear* ftarved. Thirdly, the too great quantity of the compofition hardens the wool and renders it more liable to Ipot, and therefore this method is probably the worft of the three. I have already faid, that the fecond method was attended with in- convenience, on account of the neceffity of ufing fuftic, a wood prohibited for dying true colours, confequently the firft method ftiould have the preference, if the colour it produces be equal to that obtained from the fecond j but the colour of the yellow wood is not fo folid as might be wiftied, as I know from experience, having expofed it to the fun. This feems rather extraordinary, confidcring that tl^e ingredients I are 302 THE ART OF arc polTefTed of all pofTible folidity ; but the fol- lowing will account for their not anfwering in the prcfent cafe. Cochineal, with the fcarlet coinpofition and cream of tartar, is fo permanent, that the lobfter colour is fcarce affedled by the air. It is how- ever different with regard to the yellow wood ; for though very folid, when the wool is boiled in alum and tartar, efpecially if a little alum be added to the Vat, it is nothing like fo folid when the fluff has received the fcarlet dye, which will not admit of alum ; confequently when thefe colours are expofed to the air, they will very quickly crimfon, that is to fay, they will lofe a part of the orange produced by the mixture of Red and Yellow j fo that the air which fades every other colour feems to have a different effeft upon this, which by being expofed becomes deeper and darker j becaufe the air in fome degree deftroys the brightnefs of the orange. Its effeds are neverthelefs the fame : for it is demonftrable from various chymical experiments, that there exifts in the air a vitriolic acid, like that obtained from a decompofition of alum ; for if you dip a lobfter fluff in a flight folution of alum, the acid of this fait will immediately fad- den the colour; if therefore the air be impregated with che fame acid, it will produce the fame effedl. Very few fhades are obtained from Crimfon and Yellow, on account of the price of thp former of thefe colours i efpecially as madder , and kermes will produce the fame fhades. In the fame manner orange fliades may be produced with Yellow and half Scarlet, and with Yellow ^n4 DYING WOOL. 163 and half Crimfon. Thefe mixtures produce the various colours of Souciy Orangey Cold, and fuch other fhades as may be obtained from the mix- ture of Yellow and Red. CHAP. XXVI. Of the mixture of Red and Fawn 'T^HE red of kermes or cochineal is feldom "^ ufed for the colours refulting from this mixture; becaufe for thefe kind of colours, which it is impoflible to make lively on account of the Fawn mixture, madder will be equally good. A frefh Vat of cochineal and kermes is rarely prepared, purpofely thefe ingredients being too dear for fuch common colours, and therefore it is fufficient, after maddering, to dip in an old decodtion. If therefore when the ftuff has been prepared with alum and tartar, proportioned to the madder Red required, you dip it in a decoftion of this root, as diredled in Chap. XVII. and afterwards dip and ftir it in another decoftion of walnut root or hufks, you produce the various colours of cinnamon, tobacco, cheft-nut, &c. which are obtained without difficulty by varying the madder ground, and according as they are fufFered to remain in the decofbion of this root. You may begin with either of the two colours; but it is molt common to begin with the Red ; bccaufe the preparation, abfolutely necefTary for the mad- der, would in fome degree hurt the Fawn colour. Hence they fliould never be mixed together. Red and Yellow are fometimes mixed. CHAP. ao4 THE ART OF CHAP. XXVlI. Of the mixture of Red and Black, - 'T^HIS mixture ferves to produce dark Reds ■*■ of all kinds j but thefe are feldom ufed except for worfteds intended for tapeftry. It is here neceflary to recoiled what I have faid con- cerning greys, which may be obtained, either from one Vat, by putting into the copper a deco6lion of nut-galls, and the folution of copperas, or from two, viz. by dipping the wool in a decoflion of galls, and afterwards adding the copperas j but this method is rather embarrafling, when a good afTortment of patterns is required. The moft convenient method is therefore to prepare a decoftion of galls and copperas, as directed in the article concerning greys, and to dip the wool in it, after it had been dyed Red, with any ingredient whatever, till it becomes as dark as neceflary. By this method you obtain dark fcarlets, crimfons, and all other dark Reds, let the fhades be what they will. This mixture produces alfo wine greys, by firft giving the wool a flight tinge of Red with kermes, cochineal, or madder, and afterwards dipping it in the darkening liquor for a longer or fliorter time, according as you would have the wine colour predominate. I can give no further inftrudtions concerning this procefs, as it depends upon the colour required ; nor can it be fuppofed that any body will find the leaft- difficulty. CHAP* DYING WOOL. 20S CHAP. XXVIIL Of the mixture of Tellow and Fawn colours. 'T^HIS mixture produces the fhade of the -*• feuille morte, withered leaf, and of the poil d'ours, bear's fkin. It is pretty much the cuftom to ufe foot in thefe colours, inllead of walnut hufks, or the root of the walnut tree; becaufe it really gives a finer colourj but it is very neccflary to fcower the wool after it is dyed, in order to deftroy the bad fn^l which it imbibes in this liquor. It is alfo ne^iaffiiry that the. foot liquor fhould be clarified as T have before direded. I would always neverthelefs prefer the walnut hufl-cs to foot ; at lead, if not obliged to make a very exaft aficrtment of the feuille mcrte Ihade, which could not be fo well obtained with the hulks, or root of the walnut tree. Thefe are the only two fubftances of any ufe in the Fawn colour ih^dcs; /um^cb and the bark of the alder tree, do not yield a fuf- ficient ground. The wool fhould be boiled in alum and tartar, in order ro dye it Yellow, before it is dipped again in the Fawn colour: but, if you perceive that it has not had a fufEcient bafis, it may be dipped in the Yellow, not- withftanding it has already had the Fawn colour ; though, to fay the truth, this method of obtaining the precife fliades does^ not produce a colour fo folid as when it has firft had a fufHcient quantity of the Yellow: CHAP. 2q6 the art of chap. xxix. 0/ the mixture of Tellow and Black. THE mixture of thefe colours is only ufefiii when you require greys inclining to Yellow; but thefe greys are much more ealily produced with Fawn colour, and the Dyers generally pre- fer it, being more folid, more eafily obtained, and at a much lefs expence. Befides, there is no Gccafion to boil the wool, which fhould be avoided as often as poffible. CHAP. XXX. Of the mixture of Fawn colour and Black. TJ^ROM this mixture you obtain an infinite number of colours j fuch as coffee colour, marone, prune, &c. The following is the man- ner of working. When the wool or fluffs have been dipped in Fawn colour, as already defcribed, and that feveral fhades are produced in fuc- ceffion, obferving to give thofe intended for the darkeft, a greater proportion of the Fawn colour, fuch as coffee colours, marones, &c. you put into a cauldron, nut-galls, fumach, and the bark of the alder tree, in proportion to the quantity of fluffs to be dyed. When the whole has boiled for an hour you add a little copperas. You then dip the fluffs intended for the lightefl. As foon as thefe are finifhed you take them out, and dip thofe which fliould be darker DYING WOOL. 209 darker, carefully fupplying the Vat, with copperas every time, in proportion as you perceive ic neceflary, which you will foon dil- cover, by its being longer in darkening the fluff. You continue in this manner, and with the fameVat, till all the fluffs are darkened. The fire fliould be carefully kept in under the caul- dron j but as the liquor fhbuld not boil, a flow fire is fufEcient. Having firfl boiled the galls and other ingredients, you check the boiling with a little cold water before you put in the fluffs. This precaution, as I have feveral times obferved, is abfolutely necefl^iry. You will alfo recollefl, that it is necefTary to foak the fluffs in warm water before you put them into the cauldron, in cafe they had been fuffered to dry, after they had the Fawn colour dip, and that when they have remained fome time in the darkening liquor, it is necefTIiry to cool them, paffing them through the hands by the liflings, without which .the fluffs would be in danger of being unequally dyed : befides, if not aired, the dark fhade would not be fufHciently folid; becaufe the fuc- cefiive congelation of the faline particles of the vitriol would not be accompliflied. Having thus confidered all the colours and fliades that could poflibly be produced by a mixture of the primitive colours, by two and two, in which I think I have been fufficiently explicit, I now proceed, for the workman's ad- vantage, to give him a fpecimen of fuch as I have obtained from a combination of the fame primitive colours, by three and three. This mixture produces a great number. It is true P that 2IO THEARTOF that fome of them will be found fimilar to thofe refulcing from two only, there being few colours which may not be produced by various methods. The Dyer will therefore prefer the lead difficult when the colour is equally good. CHAP. XXXI. Of the p'fTiicipal mixtures of the prmithe colours by three and three, BLUE, Red, and Yellow, produce ruddy olives, and greenifh greys, and other colours of the fame kind, of little ufe, except for worfted defigned for tapeftry. I need not here repeat the method of ufing thefe colours, already fufficiently explained in the preceding article. When the mixture contains Blue, it is ufual to begin with this colour. The fluff is after- wards boiled in the other colours fucceflively. They are however Ibmetimes mixed together, which is equally good, when each requires the lame preparation, as, for inftance, the Red of madder and Yellow. With regard to cochineal and kermes they are feldom ufed for common colours, unlefs for light ones, re- quiring a vinous tinge, which Ihould be bright and lively and then only for the laft dip, unlefs you require them more on the grey, when they fhould be dipped for the laft time in the darkner. It is however impofTible to give any precife rules concerning this procefs, as the leaft experience will teach more than a long detail of opera- tions. Blue, DYING WOOL. 2IE Blue, Red, and Fawn, produce olives from the darkeft to the lightefti but the flate, laven- der, and fuch like colours, require but a very flight ihade of Red. Blue, Red, and Black, produce an infinite number of greys of all fliades ; as fage grey, flate, and lead colour, king and prince's colour, when darker than common, befides a vaft variety of colours, many of which run into thofe pro- duced by other combinations. Blue, Yellow, and Fawn, produce greens and olives of all kinds. Blue, Yellow, and Black, produce all the dark greens, even to black. Blue, Fawn, and Black, produce dark olives and greenifli greys. Red, Yellow, and Fawn, produce orange co- lour, gold colour, withered leaf, carnations de 'veiUiardsj burnt cinnamon, and tobacco colours of all kinds. Red, Yellow, and Black, produce colours fomething like the withered leaf. Laitly, from Yellow, Fawn colour, and Black, you obtain hair colours, nut browns, &c. This enumeration is meant only to give a general idea of the ingredients proper for the produdlionof colours compofed of fcveral others. Four of thefe colours may be mixed together, and fometimes fivej but this is very uncommon. It is however needlefs to enlarge upon this fub- jed, and therefore I fhali relate only by what means I have myfelf feen' forty different fliades of carnations obtained. This example will be a fufficient guide in all other cafesi but thefe P 2 Ihades 212 THE ART OF ihadcs include none of the lively colours belong- ing to fcarlet, which are produced according to my directions in the chapter on that colour. All thefe carnations were meant for the flefh colour of old men and their fhades, and were procured from the red of kermes, yellow, fawn, and black. The Dyer began by giving the worfteds an unequal preparation, referving thofe which had the weakefl: for the lighted fhade. Having re- mained four or five days foaked in the prepa-raiiofi, as ufual, he began by dying the lighteft. The colours were difpofed in four different veffels feparately, andwere kept as hot as poffible without boiling. A fkein of worded was then dipped in the kermes vat, which being taken out and ex- prefied, was dipped in a decodtion of weld, and a moment afterwards in the fawn colour, till it imbibed the diade required. Another fl>iein ■was then immerfed, which was fuffered to remain a little longer in each liquor. In this man- ner the procefs was continuedi but if any of the fkeins, when expreffed, appeared deficient in any of the colours, it was again dipped in that particular liquor. By this means all the colours had obtained the diades required j only fuch as were intended for the darked diade were dipped in the darkening liquor. I am con- vinced, by this procefs, that patience and a little pra —^ Of THE ^- CHAP. XXXVIII, ^CU^^^^''*^^''^,.J^ Of Brnftl Wood. ^^^ ^ "C U*^"^' UNDER the general denomination of Bra- fii Wood, is comprehended that of Fer- namlouCf of Sainte-Marthe^ mija^ariy and fomc R 3 others 246 THE ART OF others needlefs to be diftinguiflied in this place, as they are ufed in the fame manner : fome of them, it is true, give more colour and better than the other; but this is frequently occafioned by fome parts of the wood having been more expofed to the air than others, or perhaps in fome places rotten. That which is the mod found and the highefl coloured fhould be prefervcd for the ufe of dying. All thefe woods give a tolerable fine colour, whether ufed alone or mixed, either with log- wood or any other colouring ingredient. We have juft feen that for falfe violets a little Brafil wood is added to the logwood; but for wine greys, or for colours ever fo little inclining to red, much more is required. A very little nut- galls with the Brafil is fometimes fufficient if darkened with copperas; but logwood, archil, or fome other fubftance, is frequently added ac- cording to the fhade required. Hence it is ob- vious that there is no pofTibility of prefcribing any pofitive rule for this kind of procefs, on account of the almoft infinite diverfity of Ihades obtained from thefe different mixtures. The natural colour of Brafil wool, and for which it is moft frequently ufed, is for falfe fcarletj which is neverthelefs a fine colour, though inferiour to the fcarlet of cochineal or gum-lac. To obtain the colour of this wood you muft make ufe of the hardeft well water: river water has by no means the fame effeft. Having boiled this wood, cut into chips, in the firft water for three hotirs, the liquor is poured intq DYING WOOL. 247 into a calk. You then pour on the Brafil wood fome frefli well water, and letting it alio boil for three hours, you pour this water alfo to the firft liquor. This decoftion, called the juice of the Brafil wood, Ihould grow old, ferment, and rope, like oily wine before it be ufed. In order to obtain from this wood a lively red, it is necef- fary that the fluffs fhould have the common pre- paration of falts and alum, only the alum ihould predominate, as the beauty of this colour is greatly impaired either by tartar alone or by four waters; in a word, acids injure it by diffolving the red particle. Hence it is neceffary to put into the liquor from fix to eight' ounces of Roman alum for every pound of wool or fluff, and but two ounces of tartar, or even lefs. The wool fhould boil in it for three hours ; it fhould then be lightly expreffed, and kept moifl, in a damp place, for the fpace of a week, that the falts may be fufEciently lodged fo as to prepare it for the reception of the colour. For the dying, you put into a proper fized cauldron one or two buckets of the juice of Brafil wood, very old, in which you dye fome common fluff that had been boiled in alum and tartar. This coarfe fluff being dyed, you replenifh with frefh Brafil juice, only half the quantity of the former, boiling in it a fecond piece of common fluff pre- pared in the fame manner. Thefe two fluffs muft neceffarily imbibe three quarters of the colours. The deco6lion being thus weakened, you dip the piece of fl:uff that had been kept in the preparation for eight or ten davs, ilirring it well, without letting the liquor boil R 4 XQQ 248 THEARTOF too much, till it is uniformly dyed. But, as I have already faid, you mud mind to wring a corner of the ftufF every now and then, in order to judge of the colour j for it appears at lead three Ihades darker when wet than when dry. By this method, rather tedious indeed, you obtain very fine lively reds, a perfe6l imitation of certain colours fold by the Englifh for logwood fcarlets, and which, tried by the debouilUs^ are no better than thefe, were it not that they feen> as if they had been (lightly maddered. The red I have juft mentioned, and no where elfe defcribed, will withftand the air during the winter without loofing any of its (hade ; on the contrary it grows darker, and feems to acquire depth; but it will notrefift the tartar Ijquor. Some of the greaf Dyers ufe l^rafil wood to heighten their madder reds; either to fave the root, or to give its red more vivacity than ufual. This is performed by dipping a ftufF began with madder in the Brafil liquor; but this fraud is exprefsly prohibited by the regulations, as well as all mixture of true and falfe colours. The firft colour obtained from the Brafil wood is never Jolid', probably becaufe it is an ill digefted fap, and the colouring particles not fufficiently ?ittenuated to enter the pores of the wool. When the firfl , grofs particles of the colour have been imbibed by the common fluff, as above defcribed, thofe which remain are finer; and mixing, with the yellow ligneous par- ticles^ the red refulting from it is much more folid. By DYING WOOL. 24.9 By the addition of acids of any kind, the red colour of this wood may be entirely deftroyed j and in this cafe the fluff dyed in it takes a hind colour of in proportion to the time of its immcrfionj and this colour is perfeflly permanent. It is faid that the Amboife Dyers have a me- thod of fixing the colour of the Brafil wood. After their fluffs are lightly reddened with madder and dipped in a weld liquor, con- fequently twice boiled in alum and tartar, they put to the Brafil juice a fufficient quantity of arfenic and pot-afh, and then they fay that this colour is capable of withftanding all trials. I have myfelf tried this procefs, but without fuccefs. If you do not require a very bright red frora the Brafil wood, I know from experience, that it is poflible to fix thefe colours in fuch a manner that, having this fummer expofed them to the fun for thirty days, they were not altered. But thefe are coffee colours and marone purples. In order to produce thefe colours, I kept the fluff for a fortnight moid with the preparation, compofed as for the reds beforementioned, in a yault. I filled a copper two-thirds full of well- water j I then filled it up with the juice of Brafil Wood, adding of Aleppo galls, very finely pow- dered, about an ounce to every pound of fluff, and half the quantity of gum-arabic; let it boil an hour and half or two hours, according to the fhade required. It was aired from time to fime, and when it had imbibed the colour I wiflied, I let it grow very cold before it was wafhed 250 THEARTOF wafhed. This ftufF when brufhed, fheered, and put in a cold prefs, was extreamly fine, very even, and perfeftly well finifhed. CHAP. XXXIX. Of Fiijtic, 'npHE Fuftic wood gives an orange colour, '*' but without folidity. It is generally ufed for the inferior dye in the fame manner as the root of the walnut tree, or walnut hufks without boiling the fluff, fo that there is no difficulty in ufmg it. To produce tobacco, cinnamon, and fuch like colours, it is frequently mixed with walnut hufks and weld. But this wood fhouid be confidered as a very bad ingredient, as its colour by being expofed for a very fhort time, lofes all its brightnefs, and a great part of its yellow fhade. By dipping a fluff dyed with Fullic into a blue vat, you obtain a very difagreeable olive colour, which will not fland the air, and which in a very little time becomes ugly. I have already faid, that it is ufed in Langue- doc for producing the lobfler colours, exported for the Levant in order to fave cochineal. For this purpofe they mix Fuflic, weld, and cochineal, with a little cream of tarter in the fame deco againfl the alum folution : on the contrary the falfe purple Iofes great part of its colour. XIV. Lobfter colours, &c. if obtained from cochineal, grow rather purplifh by the proof- liquor; but fade confiderably, if obtained from fuftic, which is prohibited. XV. Blues, whether of woad or indigo lofe nothing by trial j but if falfe are almoft entirely deftroyed. XVI. Slate colours, lavender greys, &c. lofe almoft all their colour, if falfe j but if true, ftand perfeftly. XVII. The following colours are tryed with a folution of foap, viz. Orange and all yellow S 2 fhades. 26o THEARTOF fhades, all kinds of green. Madder reds, cinna- mon, tobacco, and fuch like colours. XVIII. By this folution, we are perfe and lefs luflre than the filks of China, which are^ they fay, prepared without foap. Thefe confi- derations induced the Academy at Lyons to propofe, as a fubjeCl for the year 176 1, a method of preparing filk without foap, and the premium has been lately decreed to M. Rigaut, of St. Quin- tin, already known for feveral chymical enquiries very ufeful both for the improvement of the arls and with refpeft to commerce. This philofopher, prepoffeffed, by an edi6l of the academy, that the oil in the foap produced the DYING SILK. 273 the bad qualities fo much complained of, pro- {Dofed as a fubftitute for foap, a folution of /o^a in a proper quantity of water, fo as not to impair or weaken the filk, which doubtlefs anfwered the expeftations of the Academy. Of White, CILK when deprived of its gum, and ix)iied as we have faid, acquires by thefe operations the greateft poflible degree of whitenefsj but as there are different fhades of White, fome with a yellow call, fome blue, and others red- dilh, the Dyers are obliged when they would obtain any particular White, to add fome ingre- dient, either in the foftening, the boiling, or by a third liquor flightly impregnated with foap, called the whitener. I fhall now defcribe the method of giving filk the principal fhades of White. Whites are diffinguifhed by five Ihades, or rather five principal fhades, viz. ChinaWhite, In- dia White, Thread or Milk White, Silver and Azure White. All thefe Whites, though differ- ing from each other by very flight fliades, are neverthelefs apparent, efpecially when compared with each other. The three firfi: Whites are prepared and boiled as I have already fhown. The Silver and Azure White require azure in the preparation or ungumming of the filk, which is done in the following manner: Take fine indigo, walli it two or three times in clean water moderately v/arm, pound it afcer- T • v.'ards 17+ THEARTOF wards in a mortar and pour fome boiling watef on it. It fhould then ftand till all the grofs particles of the indigo fall to the bottom; the clear only fliould be ufed, ^vhich is called azuring. This azure is put into the foap liquor for un- gumming of the filk. The quantity of the azure is not fpecifiedj becaufe if the filk appears deficient more may be added to the whitening. For Silver and Azure White, the boiling Ihould be azured according to the eye, as for ungumminac. When boiled, the filk is taken out of the cop- per by barrings that is, by means of a fmall bar, as already explained ; but inftead of throwing the pockets on the ground they are put in a harquey or trough full of clean water. The pockets are opened in the water and then taken out, but the filk remains. Jt is then fpread and opened in the water: it is afterwards wafhed and laid on the barrow, which is placed acrofs the trough and through which the filk is drained. The firfl foap and water is again put into the copper in which the whitening was boiled, and which ferves for another boiling. The trough is again filled with clean water, in which the white fhades are waflied and rincedj they are then drained, and afterwards dreflied. The filks are then made into hanks proper to be wrung, and at the fame time the whitener is pre- pared in the following manaer; JVhUeninz* DYING SILK. 275 fVlntening. TO make this, the copper muft be filled with with clean water, and a pound or a pound and a halfof foap added to thirty buckets of water. When it boils and the foap is diflblved, it fhould be well ftruck with a ftaff, to fee if the Whiten- ing be more than fufficiently ftrong, or not ftrong enough : either of thefe inconveniences Ihould be equally avoided, for if it be too poor the filk will not be uniform, and if too ftrong it will not take the azure properly, but will be fpotted blue in feveral parts. The Whitening is good if, when ftriking it with a ftick, the froth it produces is neither ftrong nor weak. The filk is then put on the rods and dipped as follows : For China White, examine the liquor, adding for a reddifti tinge, a little rocou, and proceed as follows : The hanks being all ranged on the fods lliould be plunged into the liquor, and thefe rods reaching from fide to fide of the vefiTel, are fo placed that the hanks hang perpendicular, falling into the liquor, except the upper part, which being on the rods and the vefiTel not being quite full remain out. The rods are afterwards taken out one after another, turning the filk upfide down that every part may be equally dip- ped, at the fame time pufliing the rods to the extremity of the vefi^el. This operation is re- peated till the filk is fufficiently and uniformly tinged, and is called returning. At firft it fhould be repeated without intermiffion, and till the Ihade is uniform; but at laft when the liquor T 1 becomes 2^^ THE ART OF becomes weaker, the dipping fhould be Icfs frequent. See this operation in C. Plate II, fig. I. For Indian White the procefs is the fanse, only adding a little azure for the blue call, not to fpoil the Whitening which is intended for other whites. For Thread White and others, a little azure is added in proportion to the fliade required. The liquor Ihould be very hot, but not boiling, during the operation, and the returning con- tinue till the fiik has tak^n the fhadc equally, which it generally does in about four or five returns. The filk as it becomes even and finiihed is wrung, and afterwards fpread on the poles to dry, and then, if neceflary, fulphured, which is done in the following manner : Sulphuring, WHITE filk intended for any kind of ma- nufaclures, except fuch as are to be watered, lliould be fulphured ; the acid of ful- phur giving the greatefl poflible degree of white- nefs. It is done as follows : The hanks fliould be fpread on perches feveR or eight feet from the ground, chufing for tiiis purpofe a high room without a chimney, or an elevated barn, where, in cafe of necefllty, you may procure accefs of air by throwing open doors and windows. A pound and a half, or two pounds of Sulphur in rolls, will fulphur a hundred pounds of filk. This brimftone Ihould beput into an earthen or iron with DYING SILK. ^77 pot with a fevvafiies at the bottom j when grofsly pounded it is put on tlie alhes j you then light one of the bits with a candle, which will fee fire to the reft. The chamber fliould be clofe (hut, and the, chimney carefully (lopped to prevent the vapour from diflipating. The fulphur (liould bura under the lilk during the night. The next morning the windows (hould be Opened to let out the fmoke and admit the air, which in fummcr is fufficient to dry the (ilk. But in winter as foon as the fmoke is difTipated, the windows (liould be again (hut, and tire put into the cha(!ing diflies to dry the filk. It is of great confequence that the place for fulphur*- ing (hould be fo fituated that the windows and doors (hould open at the outfide, and remain open till there is a free circulation of air, as without fuch precaution there would be foms danger of fu(focation. When the fulphur is confumed it leaves a black cruft. This cruft being extreamely com- buftible ferves afterwards to light the fulphur, as it takes fire even more readily than the fulphur itfelf before it is burnt. If, in drefTing, the filk (ticks together, it is not yet fu(hciently dry. Obfervations on Whitening and Sulphuring, ' I ^HE fulphurious or vitriolic acid which flies, off in great quantity during the (low com- buftion of the fulphur, having the property of eating and deftroying th<.* generality of colours, acls upon rhc f;ik in fuch a manner as to make iyS THE ART OF the whites perfe6tly clear and tranfparent. It deftroys the remaining yellownefs, which mixing with the azure would give it a greenifli caft. It likewife give the filk more firmnefs, and even that ruitling called by the French m, or manie- ment. This is very perceptible, when by rolling the threads of a fkein upon each other and prefT- ing them hard with the finger, a kind of vibra^ tion or ruflling is communicated to the hand, and may be even heard by putting the ear clofe and being attentive. As this ruflling proceeds from the hardnefs or ftiffnefs of the filk, it is not the cuftom to fulr- phur fuch as are intended for goods that are to be watered i becaufe when fulphured they do not take the impreffion fufficiently, as it prevents the threads from rolling freely over each other fo as to take a good water. To avoid the inconvenience refulting from this hardnefs, it is the cuftom in fome manufacr tories to take out the fulphuring, which is done by dipping them fevcral times in hot water on the rods as for dying. This operation renders the filk fofter and deftroys the ruftling, but then it is always lefs proper for being watered than if it had never been fulphured. If the filk that has been fulphured is to be dyed, it fhould be unfulphiired, there being fcveral colours that will not take well without this precaution. If when the filk is fulphured it is apparently not fufficiently azured for the fhade to which it properly belongs, it muft be again azured with clean water only without any foapj but it is neceflary D Y I N G S^ I L K. 279 nccefifary to obferve, that if for tliis purpole tJie hard well water be ufed, it will make the azure much more blue tlian fofc water, which on the contrary gives a reddiHi tinge. Silk thus azured fhould be a fccond time ful- phured : the firft fulphuring however is not en- tirely ufclefs, as the acid of the fulphur f\icilitates the azuring with water only, but would not have the fame efFeft with Ibap. With regard to the boiling, in want of azure, you may add a little of the indigo vat prepared for dying blue, as we fhall hereafter mention, called by the Dyers the blue of the 'vat. It will have the fame cfFech provided it be taken from a vat in full ftrength. In cafe of necefTity this blue may be ufed for azuring with water. It is however liable to give a (hade lefs beautiful; bccaufe a fmall quantity of this preparation mixed with much water, lofes its quality and becomes grey. Some (luffs are always fabricated with raw filk, containing all their natural gum and ftiffnefs, requiring in themfelves to be firm and gummed, fuch as filk laces, known in trade by the name of blonds, gauzes, and the like. Silk intended for this manufa6lure fhould neither be ungum- med nor boiled ; it is therefore to be obferved, that in giving them the various preparations neccf- fary for dying, thefe preliminary operations are to be omitted. For this reafon, it is alfo necef- fiiry that at the end of every procefs you fhould be particularly attentive in marking the befb methods for making raw filk take the various T 4 colours. 28o ' THE ART OF colours. I lliall now fpcak concerning the raw ^nd white filk ufed in the fpecies of manufac- tory abovenfientioned. Thofe naturally the whiteft are the beft^ they ihould be dipped in warm water and wrung; then fulphured; afterwards azured, again wrung, and a fecond time fulphured: this at leaft is the common practice. Experience however fhews, that it may anfwer juft as well to foak it in the foap liquor, as for whitening, and only hot enough to bear it to the hand. In this liquor the filk is returned, adding azure if neceflary. When fufficiently done it fhould be well walhed at the river, which reftores the firmnefs it had loft in the foap water. It is then wrung an4 fulphured. Itmuft be obferved, that this method of whiten- ing raw filk is ufed for thofe of an inferior qua- lity; the fine filk of Nankeen, which is of ^ nature extreamly white, requiring nO fuch operation. Of Aluming. ALU MING Ihould be coiifidered as onq of the moft general operations. in the arc of dying. It a£ls as an adringent, without which the greateft part of the colours would never adhere, or at leaft would have neither beauty nor folidity. This fait unites two admi- rable properties, and of the greateft importance in the art of dying; that of augmenting the brightnefs of an infinity of colours, and at the fame time of fixing them in the moft folid and durable manner. I Alum DYING SILK. »8i Alum is always uied in dying of vvooJ, cotton thread and filk ; but the manner of application is different : the following is the method for fiik, which is the obje<5t of this treatife. Forty or fifty pounds of Roman alum being difiblved in a copper, with a fufficient quantity of hot water, is put into a large tub or ton, con- taining forty or fifty buckets of water, fee B.. Plate IV. When pouring the folution into the yefiel, ftir and mix it well, lead the cold water Ihould cryftalize and coagulate the alum, in which cafe the filk would be fpotted in various places with fmall cryftal fpots, called by the dyers frofling. Whenever this happens, by dipping in warm, water the cryftals are imme- diately difiblved, and the water may be added to the alum tub. Having wafhed the filk, it is beetled, and the better to clear it from any remaining foap, drain ic on the pegs and tie it in hanks as for boiling; The hanks are then dipped in the alum liquor one nf:er another, taking care to prevent them from tangling and twilVing together. Theyfliould be loofely tied, that every thread may be equally dipped. In this fituation it fiiould remain eight or nine hours, generally from night to morning. After this it is taken out, and when wrung with the hand over the tub, carried to the river and rinced, which is called cooling; then beetled as long as it is necefi!ary. But of this in its proper place. In fome manufadtories, inftead of tieing the filk for the aluming, it is pafl^ed on the rods, ;hree or four hanks upon each rod, giving them three 282 THEARTOF three or four fhifts or returns. They arc then intirely dipped plunging every rod by the end that is loaded with the filk, the other end fupported on the edge of the trough. The Dyers call this putting in Joude or foak, meaning in general by this exprefTion, the fubmerfion of the filk into any liquor whatfoever, where they are fufFered to remain for any time. To prevent the filk from flipping off the rods and mixing together, care fliould be taken to have a perch juft the length of the trough, upon the edge of which the ends of the rods are fup- ported in fuch a manner as to hinder the filk from flipping oT. A cord tiedto the end of the firft and. laft rod, going under the ends of every other, will anfwer the fame purpofe as the perch. When the alum liquor is prepared as above defcribed, a hundred and fifty pounds of filk may be dipped without any necelTity of adding frefh alum, or according to the terms of the art, re- frelhing. "When the liquor apparently begins to weaken, which is foon learnt from pradice, being lefs Iharp to the tafl:e, twenty or five and twenty poundsof alum diflblved asbefore, fliould be added to the liquor, with the fame precaution as above, thus continually replenifliing according to necefllty and till the liquor begins to have a bad fmell, which is always the cafe fooner or later in pro- portion to the quantity of filk that has been dipped. When the liquor begins to be offenfive, you finifh, by dipping thofe filk s intended for ordi- nary D Y I N G S I L K. 28j nary colours, fuch as browns, marones, &c. and afterwards thrown away. The trough is then rinced and prepared for a frefli liquor. Remarks on Alumijig. VTZHEN a trough of alumng has been ufed ' ^ for fome time, it forms all round on the fide an incruftation, frequently as thick as a crown piece, not fo much on the bottom as at the fides, becaufe the filk often touches the bottom of the trough, and by fweeping it in a manner pre- vents the formation of this cruft. The Dyers leave this incruftation, having remarked that fo far from producing any bad effect it helps to retain the liquor, and prevents the vefiel from leaking. This cruft is occafioned by the filk being commonly put into this liquor, without being entirely deprived of the foap, which mixing with the alum, they mutually decompofc each other : the acid of the alum, and the alkali of the foap^ form a vitriolated tartar; at the fime time the earth of the alum with the oil of the foap, forms a thick fubftance, and thefc together produce this incruftation. It is alfo very evident that to this portion of foap j];enerally remaining in the filk when put into the aluming, may be attributed the bad fmell of the liquor when ufed for any time. The filk fliould always be alumed cold, be- caufe it has been found that if the aluming be warm the filk is apt to lofe a great part of its luftre. We know by experience that it is always more advantageous to make tiiis liquor rather ftrong, thai^ 2^4 THEARTOF than weak, as the fiik with more certainty takes thecolouri whereas, if too weak, it not only takes the colour with more difficulty, but is likewife uneven. Of Blue. Q\\X. is dyed Blue with indigo, like all other •^ fubftances capable of being dyedj this drug however is of a very particular nature, for the colouring fubftance being refinous, it imparts no colour to the water, in which it will not diflblve. It- muft therefore be diflblved by fome falinc fubftance, by a kind of fermentation. But as this fpecies of dying requires a particular opera- tion, and veflcls of a fingular nature and con- venient ftrudlure, called Vats -y I will endeavour to defcribe them, as alfo the method of preparing the indigo, particularly for Dying Silk. Thefe vefTels are generally made of copper, in the form of a truncated cone, or like an inverted fugar-loaf. Plate IV, fig. i. and 2. The under part or bottom C. about a foot in diameter, and the upper part about two feet. It is four and a half or five feet in height. The bottom fixed in the ground, about a foot and a half ^eep as in D. fig. i. It is furrounded with a paved hearth, E. fig. 2. and inclofed with mafonry, F. fig. i and- 2 perpendicular, not joining to the vat, but in fuch a manner as to leave a fpace round the veflTel, G. fig. 2. larger at the bottom than at the top. It joins however at the top, forming a kind of flat border, H. fig. i. of about fix or eight inches. It D Y I N G S I L K. 285 It is cuftomary to have two openings in this mafonry, one upon a level with the ground, I. fig. i. about a foot in length, and CiK or feven inches broad, where the fire is put in. The fecond opening is formed by a funnel of frceftone or plafter, a kind of chinaney, L. fig. I and 2. for the purpofe of fupporting the fire by a current of air. This funnel fhould rife about eighteen tinches above the vat, to prevent the workmen round it from being incommoded with the fmoak or vapour. So far with regard to the conItru(5lion of the vefTel; I Iball now fpeak of the indigo preparation. To begin with the Brevet or compofition, as it is called: it is made in the following manner. To eight pounds of die finefl indigo, add fix pounds of the bell pearl-afh, from three to four ounces of madder for every pound of alhes, befides eight pounds of bran, waflied in feveral waters to take out the flower. When walhed and moft of the water fqueezed out, it is put alone at the bottom of the vat. The pearl-afli and the madder are then mixed, brufing them them roughly together, and then boiling them for a quarter of an hour in a copper containing two thirds of the vat, the liquor is then fuffered to reft, and the door of the furnace fhut. Two or three days previous to this, eight pounds of indigo are fteeped in a bucket of warm water, wafhing it well, and even changing the water which has a reddilh caft. Some dyers begin by boiling the indigo in a ley confifting of one pound of pearl-afh and two buckets of water 286 THE ART OF water. They afterwards pound it in a rnoftar quite wet, and when it is pafty, fill the mortar with the liquor before boiled and ftill hot, bruifing it for fome time, letting it ftand a few moments, and then pouring off the clear into a feparate boiler or into the vat. The fame quantity of the mixture is then poured on the indigo which remained in the mortar, bruifing and mixing it well, and then as before pouring off the clear into the boiler; and this is repeated till the whole of the indigo is thus diffolved in the liquor. The liquor in the boiler is gradually poured into the vat on the bran at the bottom, adding afterwards the remainder of the compofition grounds and all. After ftirring and raking for fome time, it is let ftand, but without fire, till it becomes cool enough to bear the hand in it, when a little fire is put round the vat, only to preferve the fame degree of heat j this fhould be continued till the liquor begins to turn green, which is eafily knnown by trying it with a little white filk. The vat in this ftate indicates that fhe is coming to j that is to fay, that the operation goes on well ; but for better information and in order to bring it forward, it fhould be flruck with the rake, and then fuffered to ftand, till the brown and coppery fkim that rifes on the furface fhews that the vat is come to. But as it is neceffary to be very certain of this, the fcum fliould be well examined, and if when blown afide, it immediately forms a frefh fkum. In this cafe it is fuffered to ftand for three or four D Y 1 N G S I L K. 2S7 four hours, and then a new compofition Is made in order to complete it. For this purpofe as much water as is requifite to fill the vat is put into a copper, boiling it with two pounds of afhes, and four ounces of madder as at firft. This new liquor is poured into the vat, raked and mixed, and then left to ftand for four hours, when it is ready for dying. Silk for the Blue dye fliould be previoufly boiled in about thirty five or forty pounds of foap, to about every hundred pounds of filk, but not impregnated with alum ; becaufe the colouring particles of indigo, and indeed of all refinous fubftances want no aftringents to make them adhere. Before the filk is dipped in the vat, it fhould be previoufly waflied from the foap, and to dif- charge it more effedually, twice beetled at the river, having been divided into hanks for the con- veniency of wringing. One of the hanks is pafled on a round ftafF fourteen inches long, and an inch and a half diameter, called ^paje fee E. Plate II. fig. 2. then plunged into the vat, giving it fome returns, fufficient to produce the colour you would have, and to make it even. It is then wrung as hard as poflible with the hand over the Vat, not to wafte the liquor, opening and fpreading with the hand till it ungreens, when it fhould be immediately wafhed in two different waters provided in troughs within reach of the workmen. When wafhed it fhould be put on the end of the peg or wringer, and wrung as hard as polTiblc, lee this peg. E. Plarc II. fig. I, and wiped with another fkeinlufHciently drained. 1288 T H £ A R T O F drained, to imbibe the liquor that is fqueezcd out by the wringer. It fliould have four turns as quick as pofllble in this manner, and then be wrung on the middle of the peg twelve times, that the water remaining in fpots after the four turns, may be equally diftributed. When wrung and drained fufficiently the filk fhould be fpread on the rods, that it may dry as quick as pofTiblc, remembering if the hanks arc large, to cut the thread by which they are tyed, to prevent their reddening under the firing, which frequently happens if kept tied. Every hank to be dyed fnonld be fucceffively managed in the fame manner. Remarks on the Blue of Indigo, SILK Dyers feldom ufe any other vat than what I have above defcribedj there is however, another that may be ufefully employed, efpecially for greens. It is made like the preceding, with this difference only, that half a pound of madder is added for every pound of pearl afhes. This Vat is much greener than the firfl, and gives the filk a more permanent colour, and at the fame time no lefs pleafing to the eye. When ex- haufled of its colour, it becomes brown almofl the colour of beer, whilft on the contrary the pre- ceding vat becomes blackifh. With regard to other vats, namelv, thofe made with urine, whether cold or hot, and fuch as are cold, made with copperas and without urine 5 they are no more ufed than the paftel or woad : thefe kind of vacs are too tedious and befides fome of them make the filk hard.r Tlie D Y I N G S I L K. 2S9 The velTel ufed for the indigo vat is generally of copper i I have already obferved, neverthe- verthelefs it may be made of wood, but for this purpofe the ftaves fhonld be an inch thick, of a proper height and bound with iron hoops. The bottom however fhould not be made of wood, becaufe by the heat it would be apt to warp, and to rot, from the moifture of the ground. Inftead of wood therefore, the bottom fliould be made of lime and cement put into the vat as it ftands on tiie ground, about fix inches high. While the mortar is frefh it fhould be leveled with a trowel, and as it drys, the cracks and opens carefully flopped. This mortar is commonly made without more water than was ufed for flaking the lime. This vat cannot be ufed till the mortar is per- fe6llydry. For the purpofe of emptying this vat, it is ufual to make an opening of about eight or ten inches at one fide, upon a level with the ground, covering it with a plate of copper, and taking care to fix it three or four inches below the ground, nailing it clofe to prevent the liquor from ouzing out. It is ufual to make the hearth oppofite to this plate with the funnel or chimney,' tlie fame as for the copper vat. But as this vat is liable to open and difunite in confequence of the pearl- afhes, which produce the fame efFefl on wooden buckets, the copper vats are always moft ad- vifable. The indigo commonly ufed by the Silk Dyers is called copper indigo, becaufe of the copper colour on its furface, and even interiorly ; neverthelefs feveral other kinds may be ufed U with 290 T H E A R T O F with equal profit fuperior to this ; fuch a^ the blue indigo, which is lighter, finer, and more pure than the copper indigo j alfo Ca- diz indigo, or the indigo of Gu^fimala, the fined and beft of all. But the price of thofe, par- ticularly the laft, prevents them from being ufed. Madder is generally added becaufe it is fuppofed to improve the Blue, AH Silk Dyers wafh the flour out of the bran, that it may not be too glutinous -, the bran is however ufeful for greening and working the indigo ; we muft obferve that the greater the quantity of bran, the better the vat, and there- fore I have prefcribed more than is generally ufed in this procefs. When the vat fubfides it (hould be then raked, as I have already faid, and ftirred no more, unlefs it fhould begin to green j for it is obfcrved that the neceffary fermentation is retared by the raking. Silk dyed in the blue vat, is apt to take the colour very unequally, which it does moft cer- tainly, if not wafhed and dryed immediately after dying ; hence the necefTity of dipping the filk in fmall parcels, of wafhing directly, of wring- ing it well, of drying inftantly, and opening it well. Fine dry weather is always the beft for thefe operations; for fhould water fall on it even accidentally whilft drying, it would be full of reddifh fpots. It is therefore neceflTary in moift weather, and during the winter, to dry in a room with a ftove, contiiiually fhaking the rods on which the filk hangs. See Plate V, fig. i. For D Y I N G S I L K. 291 For this purpofc it is necefliiry to have a kind of frame. See Plate V. fig. i and 2, viz. An oblong fquare formed of four pieces of wood, two of them ten or twelve feet, and the other two fix or feven, fufpended from the ceiling with moveable iron cramps, B, fig. i and 2, in fuch a manner that the frame may be eafily moved backward and forward. On one of the two Aides, C, fig. 2, there are a number of iron fpikes, D, three inches long, and placed four or five inches afunder. The other long fide E, has oppofite to every fpike a fork, F. When about to dry the filk, it fhould be put on rods, one end of which having a hole, goes on the fpike, whilfl: the other end refts on the fork, by which means the rods are prevented from fallino; when the Ihaker is moved. As the hanks are wrung, they fliould be fpread on one of thefe crofs rods, continually fhaking, till every part of the filk is fucceffively arranged and dryed. In order to produce difi^erent fhades of blue, the filk intended for the darkeft, fliould be firfi: dipped in the frefli vat, and fo on continuing to dip in the fame manner, only as the vat weakens, tlie filk fiiould be kept in a little longer each time, till the vat is fo much ex- haulled, that even after two or three minutes or more, the fnade appears dill weaker. The vat when thus cxhaufl:ed, ferves for the lighter fiiades even to the lighteft. It muft be obferved that having thus dyed a quantity of filk, the vat generally tires, that is, lofes its green, giving a colour Icfs beautiful. U 2 In 2^2 THE ART OF In this cafe it is neceflary to feed the vat with a frefh compofition or brevet j as follows. A decoc- tion of one pound of pearl-afh, two ounces of madder, and a handful of bran, boiled together for half a quarter of an hour, either in water or in a portion of the fame vat, if fhe is yet fuffici- ently full to afford it. After this mixture is added, it fliould be well raked, and fuffered to reft for two or three hours, more or lefs, before the dying is again refumed. For the fineft blues, a frefh vat is the beft, and therefore, if only pale blues are required, to make a vat with a fmall quantity of indigo would anfwer better than a ftrong vat that has been weakened. Light blues done in this manner are much more lively ; the Dyers however, feldom attend to this circumftance, for the price for dying blue being very moderate, it is not worth their while. - A blue vat according to the fize of the vefTel defcribed, will take from one to eight pounds of indigo, this quantity however may be exceeded by fome pounds, without inconvenience. Silk Dyers diftinguifli only five different blues, viz. light blue, or porcelaine blue, JJcy blue, middle blue. King's blue, ^nd Turki/Ij or complete blue. Thefe have their intermediate fhades to number, but no particular names. Deep blues cannot be made by the vat only, becaufe the indigo never gives a colour fuffici- ently full for thefe fliades : Hence it is neceffary toftrengthenrhe colour, by pre vioufly giving them the archil, commonly called a footing or ground. Turkijh D Y I N G S 1 L K. 293 'Turkijh blue, the deepeft of all blues, (hould have a very ftrong archil liquor, prepared in the following manner. This ground though not fo ftrong is alfo given to king's blue, but they fhould all of them be dipped in a frefli vat well fupplied. To give this archil liquor or ground, the filk when taken out of the boiling, jQiould be beetled at the river, and then hung to drain. The filk is then dipped in the archil liquor whilft very hoc, and returned till the colour becomes uniform. It fhould be afterwards wafhed and beetled, then drefled, and then dipped in the vat. With regard to all other blues, they require no ground, only previous to their being dipped in the vat, the filk iliould be carefully cleanfed from the foap after boiling and twice beetled, elfe the foap leaves a white fediment, which if in any quantity fpoils the vat. There is yet another blue as dark as king's blue, but the ground for this is vnade of cochineal, inftead of archil, for which reafon it is alfo called fine blue. But as the dying with cochineal requires a particular procefs, we Ihall defer this colour to the article /w*? violet. Kings blue in imitation of blue cloth is made in the following manner. One ounce of Verdigris for every pound of filk is dilTolvcd in a mortar or bafonof cold water, by means of a peftal j and the filks generally in hanks of about five or fix ounces returned ia this liquor. They take a flight fliade of ver- U 3 digreafe. 294 THEARTOF digrlsj but fo trifling as to be fcarce perceptible when dry. When fufficiently verdigreafed, the filks fliould be wrung, then put on the rods and dipped in a cold logwood liquor, more or lefs ftrong according to the fhade required. In this liquor it takes a blue, like the kings blue on cloth j but the colour is very bad, flies ofl^ immediately, changing to an iron grey. To prevent this inconvenience and to make it more permanent it fhould be taken paler from the logwood than the pattern to be matched, giving it a little warm archil, which reddens and roufes the browning. It fhould afterwards be dipped in the vat when the colour will be much more durable. When the fllk is to be dyed raw, or without having been boiled, care fliould be taken to chufe the whiteft. It Ihould be formed into hanks and foaked in water; but to make the water penetrate more perfeftly, it fhould be twice beetled. When foaked and dried, the hanks are dipped in the vat, like boiled filks, and then dried in the fame manner. Raw filk generally takes the dye fooner and better than boiled ; as much as polTible therefore of the boiled fhould be dipped before the raw, the firft requiring the whole Itrength of the vat. If the blue for the raw filk be a fhade requiring archil, or any of the above mentioned ingredients it fhould be given ia the fame manner as to boiled Of DYING SILK 295 Of yello'uj. '^ I *' H E boiling of filk intended for Yellow fhould have about twenty pounds of foap for ever hundred pounds of filk. When boiled they fhould be waflied, alumed, and again waflied, (which is called refrefliing) drefTed and put on the rods in hanks of about feven or eight ounces, and then dipped and returned in the yellow liquor. To make fine Yellow, or grain Yellow, as the Silk Dyers call it, they feldona ufc any other ingredient befides weld. For this purpofe a copper is prepared with about two pounds of weld to every pound of filk, and that all the weld may be well foaked it is loaded with a large pieces of wood. When it has boiled a good quarter of an hour, the bunches are puflied to the far end of the copper, or rather, if you pleafe taken out; and by means of a bucket or ladle all the liquor may be taken out of the copper, and ftrained into a copper or wooden trough, fuch as the copper trough B or C, or the wooden one D. Plate III. fig. 2. that is, by putting a fieve or linen cloth acrofs the trough, by which means the liquor is cleanfed from all the grain and little ftraws left by the weld in boiling. The liquor thus ftrained is left to cool till you can bear your hand in it: the filk is then dipped and returned till the colour becomes uniform. See the man- ner of returning the filk over a trough in C Plate II. fig. I. If this boiling does not make fufficient to fill the trough, it muft be fupplied U 4 with 2^6 THEARTOF with water, which fhould be added before the liquor is cold, that the degree of h^at already mentioned fhould be preferved. In general, all dying veflels fhould be full, that, the filk when dipped fHouid be only two inches from the edge. During this operation the weld is a fecond time boiled in frefh water, and when it has boiled the filk fliould be raifed at one end of the trough, either upon a kind of barrow, or upon the edge of the trough. Half the liquor is then thrown away and replenifhed by adding of the fecond boiling as much as was taken from the firft, obferving to rake and mix the liquor well : fuch is generally the method when any new addition is made 3 at leaft if the contrary is not particularly fpecified. This new liquor may be ufed rather hotter than the firft; it fhould neverthelefs be always of a n^oderate heat, becaufe otherwife it would deflroy a part of the colour which the filk had already taken, probably owing to the filk being deprived of part of the alum by the heat of the liquor. The filk is returned in this frefh liquor as at firfl; mean while you prepare a folution of pearl-alh in proportion of about one pound to every twenty pounds of filk. For this purpofe the pearl-afh is put into a copper, and the fecond liquor, quite boiling, poured on it, ftirring in order to afTift the diffolving of the fait; This fmall liquor is left to fubfide, and the filk is a fecond tim.e raifed on the barrow or trough, throwing into the liquor about two or three Udles pf the clearefV DYING SILK. 297 of the folution. The liquor is then well raked, the filk rc-plunged, and again returned. This alkali developes and brightens the yellow of the weld. After feven or eight returns, one hank is wrung on the peg to try if the colour be full enough and fufficiently bright; if deficient, a little more of the folution of the allies muft be added, and the rennainder of the filk done in the fanne manner till it has taken the fhade required. The lixivium, feparately prepared may be added if you will, at the fame time with the fecond boiling of the weed-liquor ; care lliould be taken however that the liquor be not too hot. This operation is only for Yellows, nor would the liquor do for greens. For Yellow ftill fuller, approaching to jonquil, when the pearl-afli is added, it may be alfo neceflary to add fome rocou, in proportion to the required. We Ihall hereafter, when treating of orange colours, give the method of preparing the roucou. For the light Ihades, fuch as pale lemon or Canary-bird, they fhould be boiled in the fame manner as for blues, thefe Ihades being much more beautiful and tranfparent when dipped in a clear ground. See the article on the blue of the vat. To do this, when the weld is ready to boil, fome of the liquor fhould be taken out out and mixed with a little clean water, and a little of the liquor of the vat if boiled without ^zure. The filk is then dipped as ufual, and i if !29t THEARTOF if deficient in fhade, the weld liquor muft be re-added and the dipping repeated if neceffary to complete the (hade required. For deeper lemon colours the weld Ihould boil as for Yellows, adding only a certain quan- tity with clean water according to the fulnefs of the fhade required ; fome of the liquor of the vat may alfo be added if neceffary i but thcfe dark lemon colours may be boiled in the common boiling as for yellows. It muft be obferved, however, that the blue of the vac is never added to thefe colours but when it is intended to give them a greenifh caft. Thefe very pale Yellow Ibades are rather dif- ficult, as they are very frequently liable to be affefted by the air, and to deepen too much while drying. This happens when alumed in the common way, which is too much; but this inconvenience may be avoided, if inftead of aluming as for other Yellows, a feparate liquor is prepared, or even without any particular pre- paration, only a little alum put' into the liquor of the weld. Remarks on Tellows. TN manufa<5lories where they cannot eafily pro- •■■ cure weld, they make ufe of the grains of Avignon, and precifely in the fame mannerj but it gives a lefs permanent colour. There are two fpecies of weld : the baftard or wild kind, which grows naturally in the fields, is rather higher than the other and the flalks much thicker. » The D Y I N G S I L K. 299 The cultivated weld on the contrary, is the more efteemed in proportion as their ftalks are Ihorter and finer. The Dyers give it the prefe- rence as it produces more dye than the baftard, and are always careful to choofe it very ripe and yellow. It fometimes comes from Spain, and is very good J but the Parifian Dyers ufe that which grows in the environs of Pontoife, Chantilly, and other neighbouring places, where they fow it in the month of March and gather it in June the following year: it therefore remains all the winter in the ground. Sandy foils are the pro- pereft for this plant. When ripe, it is gathered and dried, and then tied in bunches. The Dyers boil the bunches entire, becaufe every part is produdive of colour. Raw filk to be dyed yellow, is preferable in proportion to its natural whitenefs : it need not however be fo very white as for blues. Aurora, Orange, Mordore, Gold Colour, and Chamois, OCOU, the ingredient producing thefe various colours on filk, is of the nature of thofe plants whofe colouring particles refide in their refinous fubftance. It is therefore dif- folved by an alkaline fait, as we fhall prefently mention j nor is there any neceffity for the filk to be impregnated with alum; becaufe in gene- ral this 'aftringent is only requifitc for obtaining and confirming the extradive colours, which arc naturally foluble in water. To R 30» THEARTOF To prepare the rocou, it is neceflary to have a large copper cullender about eight or ten inches deep, and half as wide, full of holes on all fides about as large as the fmall holes of a fkimmer, with two copper or iron handles. It is repre- fented in F. Plate II. fig. 2. A copper of a convenient fize, with either river or any other foft water, proper for difTolv- ing the foap is heated. While the water is heating, the rocou is cut into bits and put into the cullender juft defcribed, called the rocou--^o\:. The whole is then plunged into the water, by means of a wooden peftel G. Plate II. fig. 2. it is diflblved and pafied through the cullender. When the rocou is entirely pafTed, feme pearl afhes are put in the fame cullender and undergo the fame operation. The liquor is then ftirred with a rod, fuffered to boil once or twice, and then immediately checked with cold water; when the fire is taken from under the copper to prevent jt from boiling any longer. You may diflblve as much rocou as you think proper; but for every pound of rocou there muft be twelve ounces or one pound of aflies: with lefs, the colour would not be fufficiently folid, but would change into a brick or tile colour, called tiling. As the afhes are not always of an equal ftrength, the Dyer muft judge of the quantity requifite to produce the defired cfFe(5t on the rocou. The effeft of the aflies ufed in diffolving the rccoUj is to deftroy the brick colour, to make it take a beautiful bright yellow, and to render this colour more durable. If D Y I N G S I L K. 301 If when ufing the rocou the colour appears to have too much of the brick colour, fhewing that it wants more afhes, it will be then necefTary to make an addition, giving it another boil and checking with cold water as in the firft operation: it is then ftirred with a ftidk and left to fettle. Rocou diflblved in this manner will keep without fpoiling as long as you pleafe, provided care to be taken to keep it clean* Silks intended for Aurora or Orange colour require only the ufual boiling — twenty pounds to one hundred pounds of foap. When thefe have been wafhed and the foap beat out they are drained on the pole, put on the rods in large hanks, and while difpofed in this manner, a copper half full of river water is made hot; fome of the rocou folution is then put into it, and the whole heated to fuch a degree that vou cannot bear to put your hand into it j but not ready to boil, that is, between hot and boiling; and then having ftirred the liquor in order to mix the rocou and water perfectly, the filks are re- turned. When they appear even, one of the hanks is taken out, wafhed and twice beetled, and then once wrung on the peg to try whether the co- lour be fufficiently full j if not, fome more roucoti is added, the liquor ftirred, and the filk again returned till equal to expefbation. When finiftied, the whole is waftied and twice beat at the river, which is abfolutely neceflary to difcharge the fuperfluous rocouy otherwife the filk is liable to fmear, and always lefs beautiful. The 302 THEARTOF The Aurora ferves as a ground to another colour called Mordore. When the fiJk has taken the Aurora, been walhed and alumed as ufual, it is then cooled at the river and a frefh liquor prepared, rather hot, to which is added fome decodtion of fuftic, and a little of the logwood decoflion. The filk is returned in this liquor; but if apparently too red, by throwing in a fmall quantity of the folution of copperas you make it fufficiently yellow. The firft fhades of this colour require nothing more than a little copperas and fuftic, which makes them precifeiy one fhade above the Aurora. The alum folution given to the filk after the rocoti ground is neceflary to extract and fix the dye of the fuftic and logwood ufed in the Alor- dore, the dye of thefe woods refiding in their extraflive particles. To dye raw filk Aurora, it fliould be chofen for the natural whitenefs of its colour, as for yellow; having foaked it you fhould give the ;c^(7/niquor but juft warm, or even cold, other- wife the afhes by which the rccou was diflblved would deftroy the natural and neceflary elafticity of the filk. For the Oranges and Mordores, the opera- tion is continued precifeiy in the fame manner as for boiled filk. When you have but a fmall parcel of filk to dye, diflfolve a proportionable quantity of rocoti ; havingcooled theliquorwith fre(h water, it Ihould ftand till the grounds fmk to the bottom of the copper before the fiik is dipped. jL What D Y I N G S I L K. 303 What we have hitherto faid concerns the filk defigned for the Aurora (hadej but to produce the Orange, a fliade much redder than the Aurora, it is necefiary after the rocou dye, to redden the filk with vinegar, alum, or lemon juice. Thefe acids in faturating the alkali ufed in diflblving and preparing the rocou, deftroy the yellow fhade given by this alkali, refloring its natural fhade which is much redder. Vinegar or lemon juice will fuffice to give the orange (hade if not very deep; but, for the ex- tream dark, it is the cuftom at Paris to dip in a folution of alum, which greatly reddens the the rocou'i and when ftill deficient in colour to dip in a weak decodtion of Brafil wood. At Lyons they frequently make ufe of their old liquors as a ground for their fafFron colours. Wlien the Oranges are reddened with alum, they fhould be wafhed at the riverj but there is no neceflity for beetling unlefs the colour be too red. The rocou liquor which had been ufed for the Auroras, is yet fufficiently ftrong to give the ground for the firft Ihade to the fire colours (of which hereafter) to brighten the deep yellows, and for the Gold and ChamoiSy or goat colours. Thefe fhades may be made after the Aurora without any difficulty, the rocou being of itfelf fufficient. Neverthelefs the redder fhades of the goat-colour require reddening as for Orange*, unlefs you choofe rather to prepare your rocou on purpole, which is done in the following manner: Having dilTolved the rocou as above-men- tioned, it fhould boil, but without any pearl-afh. When 304 THEARTOP When the liquor fubfides, a part of it is added to the alkaline folution of the rocou, which, for thefe goat colours, lufficiently reddens the liquor J nor is there any neceffity for putting nauch pearl-afh in the folution of the rocou. Thefe goat colours require to be once beetled when wafhed at the river. The rocou is generally brought us In lumps of about two or three pounds, wrapped in large leaves, and fometimes in great lumps •without any wrappers. It makes however no difference, as the Dyers are only attentive to its being of a good flelh colour and free from black veins. The rocou colours are not very folid, changing after fome time to a brickilh hue and very weaki but it is hardly poffible to produce thefe fhades with the ingredients of the lefTer dye; becaufe the madder and weld producing Auroras and Oranges on wool, has not the fame effeft on filk; befides the rocou colours are very beautiful, and therefore prefa- rable, as in filk-dying beauty is preferable to folidity. Red. Fine Crimjon, THE colour extrafted from cochineal is called Fine Crimfon, becaufe of its beauty and folidity: it refides in the extraftive matter, is very foluble in water, and upon that account requires the common aftringent, which is alum. Silk intended for the crimfon of cochineal, Ihould have only twenty pounds of foap to a hundred pounds of fUk, and no azure 5 becaufe the DYING SILK. 305 the little natural yellow ftill remaining in the filk, after only this quantity of foap, is favour- able to the colour. Having walhed and beetled the filk at the river to difcharge it well of the foap, it is put in a very ftrong folution of alum, where it lliould remain generally from night till the next morning, about feven or eight hours. The filk is then waflied and twice beetled at the river, during which time the following liquor is thus prepared : You fill a long boiler about one-half or two- thirds full of river waterj when this water boils you throw in fome white nutgalls pounded, let- ting it boil a little longer, about a quar- ter of an ounce to two ounces for every pound of filk. If the nutgalls are well pounded and fifted they may be put in at the fame time with the cochineal. The filk being waflied, beetled, and diftributed upon the rods, you throw into the liquor the cochineal, carefully pounded and fifted j it muft be then well fi:irred with a flick and ■efterwards boiled. You may put from two to three ounces for every pound of filk, ac- cording to the fiiade required. For the moft common crimfon colours, two ounces and a half, is fufiicient it being feldom neceflfary to ufe three ounces except for fome particular match. When the cochineal has boiled, you add to the liquor, for every pound of cochineal, about an ounce of the folution of tin in aqua-regia ; it X is 3«>6 THEARTOF is called compofjionj and made in the following manner. One pound of the fpirit of nitre, two ounces of fal-ammoniac, and fix ounces of fine tin in grains : the two lad are put into an earthen pot of a proper fize; twelve ounces of water is then poured on it, the fpirit of nitre afterwards added, and the whole left to diflblve. This compofjion contains much more tin and fal- ammoniac than is ufed for the fcarlet of cochineal on wool; it is however abfolutely neceffary. This quantity of the compofition fhould be •well mixed and ftirred in the liquor, and the copper then filled with cold water, about eight or ten quarts to every pound of fine filk ; coarfe filk requiring lefs, as it occupies lefs fpace. The liquor is then fit to receive the filk which is immerfed, and returned till it appears uniform, generally requiring about five or fix returns: The fire is then ftirred, and whilft the liquor is boiling, which it fiiould do for two hours, the filk is returned from time to time. The fire is then taken from under the copper, and the filk put to foak in the fame manner as foraluming. It fhould remain for five or fix hours or even if the liquor be ready at night, till the next morning. It is then taken out, wafhed at the river, twice beetled, wrung as ufual and put on the perches to dry. To fadden the grain fcarlets the filk when taken out of the cochineal liquor, is wafhed and twice beetled at the river; the Water liquor is then prepared^ in fummer as it is DYING SILK. 307 is, but in winter a little warmed, adding a folution of copperas, more or lefs according to the darknefs of the fhade required. The filk fhould be returned in this liquor, in fmall hanks, till it becomes very even, and when the Iliade is equal to expeftation, Ihould be taken out, wrung and put to dry- without v/alliing if you like, becaufe the cop- peras liquor is little more than clean water. The copperas gives the cochineal a violet tinft, depriving it of its yellow. If however it fhould appear to lofe too much of its yellow, it may be preferved by adding to the copperas liquor a little of the decodion of fufiic. Nothing but copperas will fadden grain fcarlets j the logwood being quite ufelefs for this purpofe ; copperas alone will fuffice, as it darkens greatly with the nutgalls ufed in grain fcarlets. Remarks on grain Crimfon, 'T^HE procefs juft related for producing this ■■' colour is the moft in ufe at prefent, as it gives a more beautiful fhade than can be ob- tained by any other method. Neverthelefs as many Dyers proceed in the old way, we fhall defcribe it here. For thefe grain fcarlets the rocou pafle as imported from the Indies, is added in the boiling of the filk. When the foap boils, about an ounce of rocou is bruifed in the cullender, in the fame manner as defcribed for orange colours. It fliould be pounded as fine as pofTible left any lumps fhould remain, and flick to the filk. X 2 This 3o8 THEARTOF This fmall quantity of rocou, in the boiling of the filk, gives it an IJahella colour, tolerably permanent, and has the fanne effedt as the compofition, yellowing a little. The rennain- der, of this procefs is juft the fame as the pre- ceding ; but without the addition of either com- pofition or tartar. The filk Dyers are accuftomed to ufe only the fineft cochineal, and even always prefer the prepared cochineal, which is cleanfed from all its impurities, fifted and picked. This is cer- tainly commendable, confidering that the cochi- neal not prepared being lefs pure, the more of it muft be added, and that the dregs remaining in the liquor may injure the colour. The white tartar ufed in grain fcarlets, ferves to exalt and yellow the colour of the cochineal, producing this efFedt by its acidity, all acids having the fame effe£b : we muft however ob- ferve that tartar is preferable, as it gives a more beautiful tinft. But notwithftanding the quality of the tartar, it is ftill incapable of exalting the colour of the cochineal fufficient to produce a grain fcarler, whatever quantity may be added if employed by itfelf, for if the dofe of this ingredient be mode- rate, it will not yellow enough, and if too large it deftroys and degrades the colour, without any good efFecb. In order to aflift the tartar, it will be neceflary to add fome of the compofition, which, as we have feen, is nothing more than a folution of tin in aqua-regia. This folution with cochineal, when ufed for dying of worfled, has a confider- 5 able DYING SILK. 309 able effect, changing it from a crimfon its natural colour, to a prodigious bright fire colour, produces only a crimfon when applied to filk : but it gives this colour a very beautiful tindt i for uniting with the tartar it augments the effeft, without impoverifhing the colour ; faving the rocou ground as we have before obferved. As to nutgalls they produce no good efFedlwith regard to colour. On the contrary, if you ufe too much, they tarnifh to a degree, entirely fpoiling the colour ; neverthelefs it is always the cullom to put the quantity we have fpecified. One might probably conjedure from the intro- duflion of this pradlice, that fcarlets were for- merly produced with cochineal, without either tartar or compofition, yellowing only with rocou ; filk dyed in this manner however would have no ruftling, fo that it could not be diftinguiflied from filk dyed with brafil wood. Nutgalls on account of their concealed acid, having the property of giving the filk a great ruftling, is therefore aided with cochineal i by which means thefe fcarlets are diftinguilhed by the feel from the fcarlet of brafil wood : for we muft obferve that the brafil dye cannot ftand the adion of the nutgalls, by which it is entirely deftroyed. But befides giving this ruftling to the filk, it has at the fame time the fingular and very remarkable quality of adding to its weight very confiderably, fo that by putting one ounce of nutgalls to every pound of filk, you add two, pr two and a half per cent, to the weights X 3 by 310 THEARTOF by this means fome filk dyers add ev^n feven or eight per Cent. They are -fo much a'ccLiftomed to this advantage in weight, owing to the nutgalls, that even when this drug becomes iifelefsj by the addition of the tartar and compofition, which produces the fame ruftling, they make it flill necefTary on account of the weight, which is not propor- tionably increafed by the other acids. White nutgalls are always preferable to the black, as they injure the colours much lefs,. We may however hence conclude that for grain fcarlets, nutgalls are not only ufelefs but very prejudicial, and ferving only as an impofition, is a blameable practice, injurious to commerce, and there- fore that in cafe of any new regulation in the art of dying filk, it is to be hoped that this drug in the produdlion of fine fcarlets, may be abfolutely prohibited. The filk is thus fuffered to remain in the liquor, in order to make it wholly imbibe the cochineal j during this repofe, it takes a good halffhade, and the colour yellowing in proportion, gives it a much finer call. One would be apt to believe that leaving the filk to boil in the liquor for a longer time would bave the fame efl^eft ; but experience proves the contrary ; befides it would be more expenfive confidering that it would be necefTary to continue the fire. The cochineal leaves on the filk, v/hen taken ©ut of the liquor, a kind of fcale, or rather the fkin of the infe<^, which always contains a por- tion of the colouring juice* In order therefore to cleanfe DYING SILK. 3ir cleanfe tbe filk perfedly from this kind of bran, it is twice beetled when waihed at the river. By this means the colour becomes more brilliant, clearer and fuller. The two beetlings before dying are neceflary becaufe the filk having been ftrongly alumed for this colour, and intended to boil in the dying liquor for a great while, would without this precaution, yield a certain quantity of the alum, which not only injures the colour, but likewife prevents the perfe(n; extradion of the' cochineal ; for generally all neutral falts added tp the dying liquor, have more or lefs this incon- venience. The grain, or cochineal crimfon, fuch as defcribed, is not only a very beautiful, but may be confidered as a moit excellent colour : it is the moft permanent of all dyes for filk. It per- fetlly refills the boiling with foap, and evidently fuffers no alteration from either the fun or the air. Silk fluffs of this colour, commonly ufed in furniture, are fooner worn out than faded. It is frequently feen that the colour of this grain crimfon in furniture, though more than fixty years old, is fcarce impaired. The only obferv- able difference occafioned by time is, that by lofing the yellow cafl it becomes rather darker, approaching nearer to the violet. Good judges need only handle grain crimfon, to diftinguifh it from the falfe dye of the brafii wood, of which hereafter ; for this laft colour not bearing the acids, the filk cannot Iiave that ruftling and firmnefs given by the acids xifed in grain crimfon. When the fiik is fabri- X 4 is 312 THE ART OF cated into ftufF, and the buyers are doubtful concerning the dye, let thenn try it with f inegar : If dyed with cochineal it will fland the teflr, but if with brafil, it inftantly fpots yellow and the colour is deftroyed. OfFalJe Crirfljon or the red of BrafilWood. ''T^HIS wood furnifhes an extra6tive dye in "*' great abundance, and tolerably beautiful, though evidently inferior to the cochineal. It is called falfe crinnfon on account of its little foli- dity, compared with the grain crimfon; but being infinitely cheaper, is conlequently very much ufed. Silk intended for the brafil red, fliould in the boiling, have twenty pounds of foap to every hundred weight of lilki it fhould be alumed as ufual, but there is no occafion to make the aluming fo ftrong as for grain crimfon ; when the filk is alumed it fhould be wrung and cooled at the river. During the time of wafhing, fome water is heated in a copper j m.ean while a trough is prepared with a ftrong decodtion of brafil wood, about half a bucket to every pound of fiik, more or lefs according to the ftrength of the decodion, and the (hade required : a proper quantity of warm "water is then poured into the trough. The filk is afterwards dipped and then returned, as the yellows J in this liquor it takes a red, which if hard water has been ufed is generally of the crimfon fhadej but if foft water, this red is yellower than the crimfon of cochineal, which it is always meant to imitate as much as pofDblp. For DYING SILK 313 For this purpofe it always requires faddenng which is done in the following manner. A fmall quantity of pearl-afh fhould be djf-- folved in warm water, one pound may fuffice for every thirty or forty pounds offilk; the filk is then wafhed at the river, once beetled and the lixivium of the kelp put into a frefh trough and filled with cold water j in this water the filk is .dipped J it immediately takes a beautiful grain tindlj leaving in the water a little of its dye; After this the filk is walhed at the river, then wrung and put on the rods to dry. In fome manufaftories, inflead of ufing pearl- afli in faddening, the filk is dipped in hot water only, till it has acquired the proper fhade, but this operation is a grc;.t deal more tedious and more extravagant, confidering the confumption of the woodi it has therefore no advantage over the preceding ; efpecially as it necelTarily re- quires more dye, the warm water greatly dif- charging the colour. In others, it is the cuftom to crimfon jn the fame liquor in which it was dyed, by adding to it a little of the lixivium ; this is by much the ihorteft method, though not often ufed, becaufe it requires more aflies, and the fcarlet done in this manner is never fo han4- fome. It is v/ell known that for pale fhadcs nothings^ more is required than to put lefs of .the brafil de- coftion to the liquor, but this is feldom pra6lifed, fcecaufethe colours are not beautiful. J^marks 314 THE ART OF Remarks on the Red or Crimjon of BrafJ wood, THIS colour is not difficult, neither is it attended with ''.mbaraflrnent. The filk- dyers are always provici<:d with the decoflion of brafil which is made in the following manner. The wood is cut into fmail chipsj about a hundred and fifty pounds of thefe chips are put into a copper, containing about ^fixty buckets. The copper is then filled, and the chips boiled for three hours, fupplying the water as it evaporates. Some of the decoction is then tunned into a barrel, and as much moj'C clean water poured on the chips, which are fuffered to boil three hours longer, and this repeated till it has had in all four boilings, after which the wood is exhaufted of colour. It is a cuftom with fome dyers to preferve thefe different boilings fepartcly j the firft is the llrongefl: but not often the moft beautiful, becaufe loaded with the impurities of the wood. The lad is generally the cleareft and weakeft j it has been found however, that by mixing them together they make a homogeneous liquor that is very ufeful. Probably, by wafliing the v/ood in hot water previoufly, a juice might be obtained that would give rather a finer colour; but this would beof too little importance to warrant fo much trouble and fo many precautions. It is ncverthclefs proper to take off the black fkim that is upon the furface of each deco(5lion ; the colour will be (iiuch the more beautiful. This DYING SILK. 315 This Brafil decoction is commonly kept a fortnight or three wfeks before it is ufed, becaufe it has been obferv^d that it undergoes a kind of filent fermentation, which greatly improves the colour. It is even the cuftom with fome dyers, to leave it ftand four or five months, till it be- comes fat and oily; but it has never been obferved, at Icaft v/ith regard to filk, that it is better for keeping fo long. A fortnight or three weeks, as we have already faid, is quite fufficient to give it all its quality. If ufed when newly made, it gives a more rofey colour and a greater quantity is neceffary, becaufe then the dye is much weaker. With regard to the deco<5lion of the brafil ■wood, it may be made either with river or well water. The only perceptible advantage in the ufe of well-water, either in the decodtion of the wood or in the liquor, is that the red does not require to be crimfoned with thepearl-afhes; we mufthowcverobfcrve that the reds made with river water, and afterwards faddened with afhes, have a more pleafingeffedl to the eye. Under the general denomination of brafil wood are comprehended a variety of fpecies, which though all apparently producing the fame colour, are neverthelefs very different, both in refpedl of the beauty and goodnefs of the colour. The moft beautiful, and for filk the bed, is called farnamhoKc, This wood is alfo the deareft, very heavy, imported with the bark, and is extremely brown. When firft cut down, it is more yellow than red at the infide, jjut by being expofed to the air, it gradually becomes 3i6 THE ART OF becomes redder. Its colour however is never very deep. The cleaned freefl from knots and the higheft in colour is the beil. Silk-dyers feldom make ufe of the wood of St. Mariha, which differs from the preceding by being redder and deeper -, it may never- thelefs be ufed with advantage for very dark colours. They certainly make great ufe of it for callicoes and cottons. There is befides another wood more like the Farnambouc called Japon wood or brefillety but as it gives lefs colour, it is only ufed for the lighter fhades. The Farnamhouc however may be ufed with more advantage even for thofe fhades, the colour of the Japon being extrafled with great difficulty. This wood may be eafijy diflinguiihed from Farnamhouc, being much paler, and the logs not fo large, it is a little pithy at the infide. Browns and falfe reds are commonly called brown reds, becaufe in the dye houfes crimfons are called falfe reds. In making thefe Ihades, when the filk has imbibed the brafil to a fufficient degree, fome decoflion of logwood is added to the liquor, more or lefs according to the fhade required. If deficient in the violet tinge, a little of the lixivium may be added to the water, as for falfe crimfon. To dye this falfe colour in the raw, the filk fhould be naturally as white as for yellow. When foaked and alumed, the procefs is the fame as for boiled filk. Of DYING SILK. 317 Of Scarlet, Orange Red^ and Cherry colour. '"T^HESE colours are a variety of lively reds, -'' heightened by a tin6t yellower than crimfon. They are eafily yellowed on wool, or vivified with the compofition, or folution of tin. Upon this fubftance it produces great brightnefs and folidity, the cochineal from which it is extrafted, being an ingredient eflentially good. But it is far from producing the fame efFeft upon filk, this fubftance abiblutely refufing to take thefe Ihades from cochineal; hitherto at leaft, nothing has been publillied to this effeft. \_Ahout ten or twelve years ago, a "Dyer "produced on velvet a fire colour, as he /aid, dyed with cochineal. All we can learn of their fecret is, that he gave it a flrong rocou ground, and that after wafhing he gave it the cochineal liquor, adding a fmall quantity of the folution of tin'\ Silk when dipped in a cochineal liquor and exalted by the tin compofition, capable of producing on wool the brighteft fire colour, imbibes only a weak onion fliade, tarnifhed and properly Ipeaking a wretched daubing. It therefore becomes neceflary to make ufc of another drug, or the flowers of a plant called Carthamus hafiardfaffron or faffranum. This flower contains two fort of dyes very diftindl and different from each other both in colour and property. The one is a kind of yellow of an extradive nature, confequently foluble in water; the other a fine ftrong red, much yellower than fcarlet, the natural fhade being 3i8 THE ART OF being an extreair. lively and agreeable cherry colour. The-fe lafl colouring particles of the Cariharmis being decidedly of a refmous nature, will not diffolve in water only, as we Ihall prefently fee. Though the natural fhade of the refinous red of the Cartha?nii5 not being yellow enough, re- quires a yellow ground to imitate the fiery fcarlet of cochineal on wool ; yet the yellow cxtrad is ufelefs, not being fufficiently fine, nor of a proper colour j it is therefore neceffary to begin by feparating the extradlive yellow from the refinous red, which, on account of the different nature of thefe two dyes, is by no means difficult. For this purpofe, it requires only to dilTolve and difcharge the extraflive yel- low by a fufficient quantity of water: what remains afterwards is the refinous red, and muft, in order to render it capable of dying, be difTolved by means of an alkaline fait, as we fhall fee in the following detail: Preparation of the Carthamus or Baftard Saffron, 'Tp' HI S Carthamus J about fifty or lixty pounds -^ at a time, is inclofed in ftrong linen facks and carried to the river, choofing a good bottom, free from (tones. The facks are put into the water, and to prevent them from being carried away, are carefully tied at one end with a cord, which cord is fattened to a flake. A man then gets upon the top of the fack, ta- king a long flick in his hand byway of fupport, and keeps continually treading with his feet. ^ If DYING SILK. 319 If it be warm weather and no great quantity of the Carthamus to wafh, the operation may be done with naked legs and wooden flioesj but if cold weather and a great quantity to wafh, it will be neceffary to have ftrong leather boots, fufficient to refift the water. By this means a great quantity of the yellow is carried off by the water, the man ftill continu- ing to tread the facks till the water is no longer coloured. This is a tedious operation, generally requir- ing a man for two days to waili one fack of fixty pounds. If it happens that you have good running or well-water within reach, it would fave the trouble of wafhing at the river, and may be done in troughs, as follows: Troughs for this purpofe, marked A. Plate VI. fig. I. are made of good planks, commonly fix feet long and three feet and a half broad, that the facks may be put in and removed with cafe. When the fack is put in, it is opened at the end, and kept open with a crofs piece of wood, fee B. ibid. fig. 2. or by fome other method. One of the cocks, C, in the J. .^-houfe is let let run into this opening, and as foon as the Jafframim is fufficiently foaked, a man provided with boots, as we have already faid, holding a rope fattened to the ceiling, treads it with his feet till the yellow colour is difcharged from the faffron. See this manoeuvre at D. ibid. When the water is very yellow, it is let out by means of a cock or bung hole near the bot- tonn 320 T H £ A R T O F tom of the trough, which fhould flant fo as to let the water run off more eafily, as may be feen at E. ibid. Fre(h water is then put to it, when it is again preiTed, and the water again let out, and fo continued till the fafFranum is entirely wafhed and no longer colours the water. This method of wafliing t\\tjnffranum is much more convenient than the other, and there-^ fore practiced wherever there is a good fpring or well-water within reach, particularly at Lyons, where there is water and dye-houfcs proper for this work. The facks ufed in the wafhing are always dyed a cherry colour; becaufe the extra6tive yellow is diffolved, and with it exudes a fmall portion of the refinous red of th^faffranum. When this fubftance is thus freed of its yellow, it is prepared for dying in the following manner: It is put into a trough made of deal, fuch as thofe ufed for dying; but as the carthamus is in lumps, thefe lumps are divided and broken with a peftle. When perfeftly feperated it is ftrewed over at different times, and well mixed with pearl or kelp afhes, pounded or fifted— about fix pounds for every hundred of faffranum, as in F. ihid. It is then collected in one corner of the trough, prefiing it by fmall parcels with the feet, and throwing it behind to the other end of the trough. See G. ihid. The faff'ranum is then put into a long fmall trough, called a grate, becaufe the bottom is formed like a kind of trelis with wooden bars DYING SILK. 321 bars, about two fingers breadth from each other, which is the breadth of the bar. The infide of this trough is lined with a linen cloth ftretched and filled with laffraniim j this trough is then placed in a larger trough, and cold water thrown over it. This water impregnated with the falts, retains in folution the colouring fubftance of thefafFron, v/hich fritters into the larger trouo-h or receiver. See this apparatus marked H. ibid, fig. I and 2. You continue thus to pour on frefli water, ftirring from time to time till the under trough is full ; the Jaffranum is then car- ried to another trough, more water poured on it till it begins to take no more colour. A little of the alhes is then re- added, and more water till it has ftill lefs colour. This manoeu- vre is continued till th^ Jaffranum is entirely deprived of its red, retaining only the yel- low, when it is ^ood for nothino-. Silks intended for poppy or fine fire colour, fhould be previoufly boiled as for white ; they fhould then have a rocou ground three or four degrees under the Ihade called aurora, as explained in the article upon oranges. There is no occafion for aluming, thofe filks being intended only to take the refinous colour. When the filks are wafhed, well drained, and the hanks diftributed on the rods, fome lemon juice is added to the liquor, till the colour, wjiich was before a reddilli yellow, becomes a beautiful cherry colour: this is called turning the liquor. The whole is then well llirred, the filks put in and returned till they have taken the colour. Y It 322 THEARTOP* It is neceflary to obferve that the poppy is the fulleft colour which baftard fafFron is capable of producing^ and that when the filk apparently imbibes no more colour, it is taken out and wrung with the hand over the liquor, drained on the pegs, and plunged into a frefh liquor as (Irong as the firft. This procefs is the fame as the former; it is taken out, wafhed, wrung, and fpread on the rods to dry. When dry it is again dipped in frefh liquor as at firfl, and this is continued in the fame manner, walliing and drying between every frefh liquor till it has acquired the fuU- nefs you defire. It generally requires four or five liquors before it obtains the fire or poppy colour; this however depends on the ftrength of the liquor, and if the faffranum lixivium be weak, it will be neceffary to dip oftenerj but however ftrong it may be, you can hardly produce this colour under three or four liquors. The filk having acquired fufficient fulnefs, it mud be finifhed in the following manner: Some water being heated till ready to boil, is then put into a trough, and fome lemon juice added j (the quantity about half a pint for every bucket of water) the poppy colours are then returned in this brifkening liquor, which at the fame time ferves for walliing, by which means they become brighter and more gay; they are tlien wrung and dried as ufual. The procefs for dark oranges and deep cherry colours is precifely the fame as for poppies, only tJiat it is unneceiTary to give the rocou ground, and that the liquor ufed for the poppy will do DYING SILK. 323 do for thefe colours till entirely exhaufted. No frefh liquors are made for thefe colours but when you have none of the liquors ufed for poppies ready. Light cherry colours, rofe colours of various diades, and flefh colours, require only the fecond or laft liquors that were drained from off the faffron, which are the weakeft; thefe colours are however worked and brightened in the fame manner as the poppies, dipping always the deepeft firll after the poppies. Flefh colour is the lightefl of thefe fliades, and'fo extremely delicate that a little of the foap water ufed for boiling the filk is added to the liquor. The foap foftens and prevents the filk from taking the colour too quick and uneven. They are wafhed and then brightened in the fame liquor that had been ufed for the darker colours. Thefe liquors require to be immediately worked, and always as quick as poffible, as by keeping they lole their colour, and after a certain time are entirely fpoilt. They are always ufed cold; becaufe the faffranum, reddened by the lemon juice, will not bear heat. To fave thtfoffranumy it has been the cuflom for fome time paft, for poppies and deep co- lours, to ufe the herb-archil j about five or fix buckets of this archil liquor added to the thirty buckets of the firft or fecond faffron liquor, making about a fifteenth part of the whole. When we come to fpeak of archil, we Ihall give the method of extrafting its colour. Y 2 To 524' THEARTOF To produce the Jaffranum colours on raw filk, the whiteft is preferable, and is treated exa6lly in the fame manner as the boiled, with this difference only, that the 'poppies, oranges, and cherry colours, in the raw are generally dipped in liquors that were ufed for the fame colours for boiled filk j thefe liquors being Itill fufficiently ftrong for dying raw filk, which, as we have already faid, rifes in colour with lefs difficulty, and even in general requires lefs dye than the boiled. Remarks on the dye of CarthamuSj or Bajiard Saffron. 1X7 HEN the Carthamus is divefted of all its ' ' extrafbive yellow, the refinous red ftill remaining requires a particular folvent : fixed alkaline falts we know by experience are the fittell for this purpofe. A kind of lixivium therefore confifling of kelp or pearl afhes, is the necefTary folvent for reducing the refinous red of Carthamus into a proper folution for dying; but this alkali, at the fame time that it diffolves the refinous red, greatly diminifhes the intenfuy of the colour, giving it a yellow call as we have ittw with regard to the rocou. This incon- venience is however entirely prevented by adding the acid of lemon juice to the liquor, which fe- parating the colouring refinous particles from the alkali, eftablifliesthe colour in its original beauty. The refinous red is in fa6t no longer in a Hate of folution, but is rather a kind of precipitate. This precipitate however is fo fine and fo divided as to be equal to a folution. It mud however be obferved, that when the filk remains in this ■ D Y I N G S I L K. 325 this dye, for any time, it ceafes to imbibe the colour, even though the liquor fhould ftill retain a large quantity; this is doubtlefs occafioned by the avidity with which the filk imbibes the finer particles, the other being too grofs, efpe- cially when the filk is faturated to a certain degree. All acids are capable of giving the proper degree of colour to an alkalized Carthamus liquor. Mineral acids are certainly much cheaper than lemon juice; neverthelefs the latter has been always preferred, as evidently producing a better cfFedt. The poppy colours are entirely produced without archil; being fufficiently fupplied with the red of Carthamus only, and when in its higheft perfeftion is a colour very bright and beautiful. It will not however bear to be compared with the fine fcarlet of cochineal upon woolens: the aftonifhing brightnefs of the latter muft always make it appear weak and faded. Poppy colours refill vinegar; they are much more expenfive, more beautiful, and more permanent than the bad fire colour of Brafil wood, called falfe poppy. They are, for this reafon, confidered by moft of the filk Dyers and manufadurers as a fire colour of the beft dye; but they by no means deferve to be ranked with firm and permanent dyes. Twenty-four hours expofure to the fun and open air is fufficient to degrade the fined of thofe poppies by three or four fhades; and if for fome days days expofed, fcarce a veftige of the colour Y 3 remains 326 T H E A R T O F remains. Deep oranges, cherries, and role colours, being lefs charged with the Caribamus red, are ftill fooner degraded and dellroyed by the air. The red of Caribamus being of a nature truely refinous, is therefore foluble in fpirit of winej this folvent inftantly difcharges the colour. Of tbe Falfe Poppy ^ or Fire colour y produced witb Brqfil wood. 'TpHE Brafil wood produces a kind of fire -*' colour, called Ratine or falfe poppy j infinitely cheaper, lefs beautiful, and ftill lefs pernnanent than that of the Carthamus or Jaffra- num. This colour is produced on boiled filks as for common colours. It Ihould have the rocou ground of a tolerable fhade, ftronger than for the fine poppy, becaufe the red of the Brafil wood is yellower than that of the Jaffranum\ the fhade given by this ground is almoft: a demi- aurora. It is however advifable, as well for the falfe as folid poppy, when a proper ground is obtained, to keep a fkein by way of pattern, which fkein may ferve as a future guide. This Ratine, or falfe poppy, is obtained without much difficulty. Having boiled, as before exprefifed, wafhed and given the rocou ground, again wafhed and once or twice beetled at the river, it is then alumed as for all extrac- tive colours, the Brafil being of that number. Afterwards it is cooled at the river, and then drefied as ufual. The Brafil decoclion is then prepared -vyith hot water^ and a little of the foap DYING SILK. 327 foap water whicli had been kept on pnrpofe, is then added to the liquor, abdut four or five quarts to a trough containing five-and-twenty or thirty pounds of filk. The whole is then flirred and the filk put into it. If after a certain number of returns, the co- lour appears ftill faint, a little of the Brafil decoftion is then added. When the colour is even, you leave it to imbibe the dye, returning the filk from time to time till it has acquired the proper fhade. When finifhed and waflied at the river, if apparently deficient in red, it may be once beetled J but it is firft necefllary to obferve whether, as is generally the cafe, the water rouzes the red of the Brafil. If it has not this property, inftead of beetling the filk, more of the Brafil decodion fhould be added till it has acquired fufficient colour. By this method ratine colours are produced ftill browner, and totally different from the fire colour fiiade. In order to brown when the Brafil liquor is ex- haufted, a part of it is thrown away, and another portion of the Brafil decodlion re-added ; after- wards a decoftion of the logwood, which browns more or lefs according to the quantity added. Thefe are the truly brown ratine colours, for fome time paft called by the name of mor- dore^ — a name however not applicable, and ap- pertaining to the colour mentioned under the article Aurora. Thefe ratine browns, as well as the red browns, under the article Falfe Scarlets, ferve to com- Y 4 pletQ 328 THEARTOF plete the various fhades of the poppies and oranges which cannot be obtained from the Jcffra-num, We have nothing to add to what we have already faid, when fpeaking of fcarlets, with regard to the Brafil liquor. This decodion is neceffary for every colour where the Brafil is ufed, nor is there any difference but in the 'manner of ufing it. For inftance, the foap added to the Brafil liquor, in order to produce the ratine or falfe poppy, is defigned to render the filk foft and pliant, and to deprive it of the fliffnefs which it would otherwife have without this precaution i the aluming given upon a rocou ground producing this fliffnefs. Some Dyers inftead of the foap, throw in a fmall hand- ful of nutgalls powdered i they fancy that it produces the fame effeft, and even adds to the brightnefs of the colour^ but the greater number prefer foap. For the ratine in the raw, you take the whiteft as for yellow i having foaked and given the rocou ground only warm, or even cold, not to ungumthe filkj this colour is afterwards finifhed as boiled filk. Falfe Rofe colour. TT is by no means the cuftom to make falfe "*■ orange or cherry colours 3 becaufe the colours produced in this manner are too dull and ugly. Falfe rofe colours only are obtained by boiling as for poppies i afterwards aluming, and then dipping in a very light brafil liquor without any other addition 5 but as this colour is very DYING SILK. 329 grey, and abfolutcly deficient in brightnefs, it is but feldom ufed. To dye this fhade in the raw, it is neceflary as for all delicate colours, to chufe the whiteftj when Ibaked it is dyed in the lame manner as the boiled. Of Green, 'T^HIS colour, compofed of blue and yellow, -*■ is with difficulty produced on filk, becaufe the blue vat is liable to fpot and to give a party colour, an inconvenience more perceptible in green than blue. Greens are produced in the following manner. The boiling of the filk for this colour is the fame as for common colours. Silk dyers diitinguilh a multitude of green fhades j we fhall however mention only the principal, and of thefe, no more than is necef- fary. We fhall firfl fpeak of the fea-green, or l^our- ville-greetij confiding of twenty five or thirty gradations, from the weakeft called pijla- chio green, to the deeped fliade, called terrajfe green. To produce thefe greens, after boiling, the filk is drongly alumed j it is then cooled at the river and didributed into hanks of about four or five ounces. This precaution is neceflary for giving the yellow ground to all filk intended for green i becaufe thus didributed in fmaller hanks, the filk is more equally dyed ; which with regard to green is of the greated confe- quence 330 THE ART OF quence. The weld is then boiled, as in the article upon yellow. The weld having boiled, a liquor of it is pre- pared with clean water ftrong enough to give a good lemon ground. The filk fhould be then returned in this liquor with great care; becaufe an uneven ground would be very difcernable in the green. When the ground feems nearly full enough, feme threads of the filks are dipped in the blue vat to try whether the colour of the ground be fufficiently full for the llaade : If not, fome of the weld decodion is added and again tried. When the colour comes good, the filk is cooled at the river, and if you will, once beetled i it is then wrung, and formed into hanks convenient for dipping in the vat. Being dipped Ikein by fkein, as for blues, it is wrung with equal care and quicknefs. The fifteen or fixteen lighter {hades of this green, require only to be dipped in the vat to be compleatly finilhed. As to the pijiachio green, if the vat be yet too ftrong, as foon as taken out, it fhould be carfully opened and aired, but not waflied. It is then worked in the hands j that is, held with one hand and ftruck with the other, by which means the filk being difintangled and aired, the colour becomes equally clear. A few threads are then rinced, and if the colour be right the whole is wafiied. For the dark lliades, when the weld is exhaufted, a little logwood is added to the liquor. For the darkeft fhades it is even neceflary to add fome decoclion of fuftic ,• the filk is- afterwards wafiied and beetled as before, and 4 then D Y I N G S I L K. 331 then dipped in the vat, always remembering to vvafh and dry quickly. There are many other lliades, differing from the fea-green, becaufe they have a yellow caft ; they are however produced by the fame ingre- dients; for example the willow green. Thefe greens are dipped in a very ftrong weld liquor, and when exhaufted the fuftic or rocou is added to the fame liquor in order to compleat the'fliadej If the colour requires darkening, a little logwood may be added after the fuftic or rocou i they are afterwards dipped in the vat. The fecond fhade of green is the meadow or emerald green. Thefe are alumed as for fea greens; after having cooled at the river it is dipped and returned in the weld liquor, which had been previoufly ufed for the fea green. When the colour feems even, fome threads are put into the vat to try the effect of the ground ; if the green be too blue, it is again put into a frefli decodion of the weld. The vat is theri ftirred, and the filk again put in, till by making a frelli eflay on the vat, you find the ground proper to the fliade required. The only difference between the meadow and emerald grounds is, that the firft is rather the darkeft. In manufadlories where favory is eafily procured, it is ufed for thefe kind of fhades, in preference to the weld, the favory natu- rally yielding more juice than the weld, or rather becaufe the fluff when dry, retains the fame colour which it had taken in the liquor; whilft on the contrary, the colour of the weld 332 THE ART OF ■weld always grows yellower and redder in the drying. In cafe of necefTity genejirole may be fubftituted for favory, having the fame effed as the weld, with this difference only, that as it is lefs pro- ductive more of it muft be ufed. Thefe colours fhould be always waflied and dryed as quick as pofiible, as Hiould all greens and blues in general. The third Ihade is the duck green, and pro- duced with the weld, favory or genejirole^ by giving a good ground of thefe ingredients, and when the colour is exhaufled it may be darkened by adding feme logwood to the fame liquor s it is afterwards dipped in the vat. The oeilet green is produced in the fame manner as the meadow and emerald green, with this difference only, that the gradations or fhades are made by dividing the ground, that is, by giving the ground more or lefs flrength accord- ing to the different fhades, whereas of the emerald and grafs green, there are no grada- tions. The duck-wing fhades are darkened by an addition of logwood as in the preceding fhades. The celadon, requires much lefs ground than the other fhades becaufe it has a great deal more blue. The darkeft fliades of this colour are produced by the help of logwood. Apple green is the precife intermediate fhade between the oeilet and the fca- green and requires the fame procefs. The various green grounds hitherto mentioned, except fea- green, fhould be given in liquors that had been already ufed. D Y I N G S I L K. 333 but which contain neither logwood nor fuftic. The old liquors Ihould therefore be carefully preferved. Remarks. THE efFeds of the weld ^nd genejlrok being as we have already obferved, nearly fimilar, are almoft indifferently ufed, and even fome- times mixed together. With regard to the favory it is certainly preferable for green Ihades, to the other two, except for thofe where it is neceflary to add either logwood, fuftic, or rocou. Befides thefe greens, there are a multitude of others all under the denomination of thofe already mentioned. We fhall therefore only remark that for the very dark fhades approaching to black, copperas may be ufed after the other ingredients are exhaufted. For the very clear Ihades of the celadon, and other light greens, the filk Ihould boil twice, as for light blues, thefe light fliades being thereby rendered much more lively and tranfparent. Of Olives. QlLKS for this colour require only the *^ common boiling. When ftrongly alumcd, .and cooled at the river, they are then dipped in a very ftrong liquor of the weld, in the fame manner as for yellows, adding to this liquor when exhaufted, fome logwood, and when the loQ-wood is exhaufted a little of the lixivium o of pearl-a(h. This alkali greens the liquor, giving it an olive caft, The filk is again dipped 334 THEARTOF dipped in this liquor and, when of a proper colour, taken out, wafhed and put on the rods to dry. There are two fhades of olive. One the green olive above mentioned, the other is a reddifb and rufty olive. For this fecond fliade having given the weld, fome fuftic and logwood may be added, but without the pearl-afhes. If the colour be too red, the logwood only (hould be added, and alfo without pearl-afli. For the clear fhades of thefe colours, you divide or diminifh the logwood; that is, allowing lefs for the cleareil and more for the darkeft fhade. Remarks, THOUGH the olive be a fpecies of green, it is not however the cuftom to give it the blue vat, becaufe the colour would then be too green. The logwood which naturally gives a violet, by the addition of pearl-alh becomes blue, and this blue when combined with the yel- low of the weld, gives the green neceflary for producing this Ihade. Fuftic gives a colour commonly called drab- ohe, becaufe generally made to match with olive in cloth, which has generally more red than the preceding. Having alumed as ufual, the filk is then dipped, in a fuftic liquor, with the addition of copperas and logwood. "When this liquor is ex- haufted it is thrown away, and a frefli one made fimilar to the firft, remembering only to redify the quantities of the ingredients. If the colour b« DYING WOOL. 335 be deficient in fome parts, it is again dipped as at firfl, till the ihade is properly full. Both liquors fhould be of a moderate heat. The green dye for raw nik, is in the manner as for boiled -, the whiteft, as for yellows, are thebefl: : having prepared and alumed, the remainder of the procefs is the fame as foi boiled. 0/ Violet. 'f/'IOLET is a compofition of red and blue, the blue of all violets is obtained from indigo; the red from cochineal, befides fevcral other ingredients from which it may be ex- tracted. When the red is obtained from cochineal, it is a good dye, and is called fine violet, but if from any other drug, particularly archil, the colour has but little folidity and is called falfe violet. Of fine Violet or Violet in grain, JpOR this colour the common boiling is ufed; ■*^ the filk is then alumed as for fine fcarlet, and when wafhed at the river fliouJd be twice beetled. The filk thus prepared, is cochinealed as for for crimfon, with this difi^erence however, that neither tartar nor compofition is added to the liquor; thefc acids being ufed in crimfon only to exalt the colour of the cochineal, by giving it a yellow caft. For violet, on the contrar>^, the natural colour of the cochineal is befl, having agreat deal more of the violet, more purple and more 336 THEARTOF more of the gilly-flower colour, and therefore more or kfs of the cochineal is required, accord- ing to the intenfity of the fhadc. The common quantity is two ounces for every pound of filk In making the cochineal liquor, the copper defigned for it fhould be half filled with water, in which the cochineal fhould boil for about a quarter of an hour. Mean while the filk is pafled on the rods in fmall hanks, the fame as for giving the ground for greens i the copper is then filled with cold water becaufe the liquor fhould be but juft warm: the fjlk is then re- turned in the liquor with care and great accuracy, and if twenty rods or more, it will be neceffary to keep two men in returning the filk, that the colour may be more perfedl and more equally imbibed. As foon as the filk appears fufficiently even, the fire fhould be flirred to make the liquor boil, and then one man is fufficient to return, which fhould be continued with accuracy to the end of the liquor, which generally lafhs about two hours, as for fine crimfons. If after two hours boiling it appears that the liquor is not yet fufficiently exhaufted, the filk mjay be put into an alkali during five or fix hours, as before directed when fpeaking of crimfons; the filk is afterwards wafhed at the river and twice beetled; it is then dreffed and dipped in the vat, more or lefs ftrong, in proportion to the fhade of the violet colour required. Wartiing and drying are ufually done in the fame manner as for blues and greens, and in general for all colours dipped in the vat. Thf DYING SILK. 337 The Dyers are accuftomed to ufe a little archil iin the produdion of thefe fliades, in order to give them (Irength and beauty. It is added to the cochineal liquor, after it is exhaufted, what quantity you think proper, according to the Ihade required. Having boiled for about a quarter of an hour, it fhould be then fufFered. to ftand till the archil finks to the bottonn, and then the filks are returned in the liquor. This method is however blameable, becaufe the colour procured from the archil is a falfe dye, and Ihould not therefore be ranked with a fine colour and good dye, fuch as the violet of pure cochineal. The cuflom of uniting archil with the cochi- neal in the production of fine violets has crepe in by degrees, becaufe the red of the cochineal in thefe colours is much lefs beautiful to the eye ; or rather becaufe the merchants and manu- fafturers of filk fluffs, giving the preference to brightnefs and beauty, the dyers are partial to this manoeuvre ; befides the archil being much cheaper than the cochineal, many dyers infen- fibly increafe the quantity of this falfe ingredient, proportionably diminifhing the cochineal, in fuch a manner that their pretended fine violets, and fold as fuch, are really no more than a fpecies of falfe violet. This is become a fhameful abufe, and certainly ought to be difcouraged. Neverthelefs the admiflion of archil feems indifpenfably necef- fary in weak fhades, efpecially light violets, as the colour imparted by the cochineal is infupporta- bly tarnifhed and dull. They are therefore under the neceflity of producing light fliades with ar- Z chil 33? THEARTOF chll, which always imparts a very beautiful though a very perifliable colour. It has been already oblerved in the article on blue, that it is impofiible to produce the darkeft of thefe Ihades by the help of indigo alone, and therefore that it is neceflary to join it with fome dark red j this red may be extracted from the cochineal, and the dark blues darkened by this ingredient are termed f.ne hlues^ to diftinguifh them from the blue darkened with archil, a drug of falfe tinft : thefe dark blues are evi- dently rather a fpecies of violet. The fine blue is alumed in the fame man- lier as the fine violet, in like manner wafhed at the river, twice beetled, afterwards allumed, and the quantity of the cochineal is one ounce, or an ounce and a half, in proportion to the fliade required ; remembring to divide the filk into fmall hanks as for violet : they are then walbed and twice beetled i after which they re- quire nothing more than to be dipped in a frefb vat. Of fcdje and common Violets or Lilac, T?ALSE violets are procured in various ways **- and from different kinds of ingredients, of which in their proper order. The finefl: and moft in ufe are procured from archil. This ingredient is of the mofs and lichen kind, an herb, in its natural ftate, imparting no colour to water. It is therefore neceflary, in order to render it of any ufe, to open and dilTolve its colouring principle by means of digeftion and a kind of fermentation, afTifled by DYING SILK. 3^9 by a mixture of urine and lime. The method of preparing archil for dying is very clearly and exactly related by M. Hellot in the foregoing treatife on dying wool. The colouring particles of this drug feem of a refinous nature, not dif- folving in water, but through the medium of an alkali ; therefore fubftances to be dyed with archil require no aluming. The following is the procefs for dying with this ingredient. A copper is boiled with a quantity of the ar- chil in proportion to the colour required ; a full and dark violet requires a larger quantity, fometimes two, three, or even four times the weight of the filk, according to the goodnefs of the archil and the fulnefs of the colour. During the preparation of the archil liquor, the filk is taken out of the foap, cleanfed and afterwards drained and drefTed by hanks as for fine violet. The hot archil liquor is then taken off clear, leaving the grounds at the bottom, carried and put into a trough of a convenient fize in which the filk is returned with the greateft accuray. When the colour is come to, you make a tryal of the vat, to try if it be fufficiently full for a very dark violeti if too light, it is again dipped in the archil liquor, adding frefh archil if necefiTary; when it is of a proper colour it is twice beetled at the river, and then dipped in the vat as for fine violets. The wafhing and drying of this colour is the fame as for all colours dipped in the vat. The different fhades of violets are diftinguifhed by different names : thofe above defcribed Z 2 -are 340 THE ART OF are called violei of Holland. And are the fullefl, the richeft, and mod beautiful colours. The hijhofs violet which is the lecond fhade, has alfo a full ground ; but lefs of the vat, by which it preferves a redder caft. As giving the blue in lilac requires great management, and that the vats are generally too ftrong, it is the cuftom in order to be matter of thefe fhades, to mix a little of the new vat with fome pearl-afh in clean water, to prepare a liquor on purpofe, by which the lilacs may be blued or reddened at pleafure. For this purpofe it is neceflary to take a new vat in all its vigour, be- caufe thofe which have been already worked and tired give no more, even though a quantity be added, than a greyifh colour, and that not permanent. When the vat is added to this liquor, and immediately raked, the mixture becomes of a green colour, which diminifhes infenfibly. The filks are not dipped till the liquor begins to lofc a little of this previous green, and inclines to the colour of indigo, becaufe if dipped before, they would be expofed to take an uneven colour J for when this liquor is in all its green, confequently in all its vigour, the firft portion of the filk dipped in it, feizes the colour with avidity, by which means the liquor is fo much exhaufted of its green, that the filks afterwards dipped, have a vat incapable of giving a ftrong blue. The pearl-alh added to this liquor, helps in blueing the archil, becaufe the general efFed: of all alkalies is to render all reds violet. It is not DYING SILK. 34r not therefore added to the archil liquor, be- caufe in boiling together it would injure and in part deftroy the effeft of the colour. We have already prefcribed a warm liquor for red- dening and blueing, as water too hot would be alone fufficient to weaken the archil ground, and with more reafon would produce this effeft when aided by an alkali ; but in cafe of neceflity warm water may be ufed for this operation, Thefe colours, when finifhed, are wruns: over the liquor, and afterwards on the peg, but without wafhing, becaufe the greater part of the blue would be loft in the wafhing. The filk is afterwards put to dry in a covered place, the a6lion of the air being alone fufficient to change them confiderably j particularly the violets and lilacs of archil, efpecially when made of the beft kind, growing in the Canaries, called herb-archil, which, though more beau- tiful, is at the fame time the leaft permanent of all the various colours in dying. Acids deftroy them, and they fo quickly fade, that to keep filks of this colour, if you would preferve them frefti, it is neceflary to keep them as much as poflible from the air. Of the Violet of Logwood. 'TpO dye violet with logwood, the filk Ihould -*- be boiled, alumed, and waftied as ufual. The logwood is cut into chips, and boiled in water as already defcribed with regard to the Brafil wood. The decotlion when made is put into a barrel to be ready upon occafion. Z t When 343 THEARTOF When ufed for dying, it is put into a trough with a quantity of cold water, in proportion to the quantity of filks to be dyed; to which is added and well mixed fome of the deco6lion of the logwood, more or lefs according to the Ihade required; the filks are returned in thi« cold liquor till they have obtained the colour you would have. This liquor gives a lefs beau- tiful fhade than the archil, and a little dull. Remarks. THE natural colour of the logwood or cam- peachcy is a very brown red. The higheft co- loured, the foundeft, and the lead loaded with fap, is the beft. It makes a dark brown-red decodlion. The filk for this dye fhould be alumed, without which it would be only daubed with a reddifh colour, and would not even bear wafhing, the dye of this wood being of an extractive nature. But when alumed, the filk in this dye takes a tolerable good violet, a little lefs durable than that of the archil ; but will in. fome degree (land the foap, which gives it a blue caft. This dye fliould be ufed cold ; for when hot it gives a rough colour, very uneven, more tarnifhed, and lefs beautiful. For this feafon the decoction fliould be made two or three days before it is wanted. It is how- ever neceffary to obferve, that the logwood decodlion will not keep fo long as that of the Brafil wood, as it changes by time, taking a fawn, tinge, which fpoils it, and therefore no more of \t Ihould be made than may be wanted ip the courfe of three weeks or a month, Viola DYING SILK. 343 Violet of Logwood and Verdicts. A Violet may alfo be obtained from logwood and verdigris, as follows: The filk is wafhed from the foap, and drained on the peg, &c. You then difiblve, in cold water, about one ounce of verdigris, for every pound of filkj when it is well mixed in the water, the "filk is immerfed, and may remain in this liquor for an hour, or till it is well impregnated wich the verdigris. This gives no perceptible colour. The filk is after this wrung, and again put on the rods. A logwood liquor is then made, as for the preceding violet ; the filk is dipped in it, and takes a blue colour fufficiently dark. The filk is then taken out, and when dipped in a clear folution of alum, made either with the liquor or clean water, acquires a red that on the previous blue produces violet. The quantity of alum thus added is undeter- mined ; but the more alum the redder the violet. The filk having acquired the colour you wifli, is wrung over the liquor, wafhed, and again mode- rately wrung on the peg, that the colour may re- main even in the drying, which when wrung hard is not the cafej for then the part mod fqueezed is lighter than the other parts, which arc dark and coppery 3 an inconvenience to which log- wood colours are moft liable. Violets with logwood only, without verdigris, require the fame atten,tion. Thefe logwood violets, with verdigris, have neither more beauty nor more folidicy than Z 4 violets 344 THEARTOF violets without this ingredient. We mufl: however obferve, that the verdigris with which the filk is impregnated, ferves as an aluming preparation towards receiving the logwood dyej befides, this colour being abfolutely blue, the alum afterwards added ferves only to give that rednefs peculiar to violet. Hence it is evident that a colour truly blue may be obtained from verdigris and logwood j this however is a very falfe colour, and by no means comparable to the blue of the vat, either in beauty or folidity. Violets of Brafil wood and Logwood, QILK for thefe violets muft be alumed and ^ cooled as ufual ; it is then dipped in a liquor of the Brafil wood of the common heat; when it has imbibed this liquor, a decoftion of logwood is added, and the colour being properly full, is then changed by adding fome lixivium of pearl-afh; it is afterwards wafhed, wrung, and dried as ufual. Remarks, THE violet produced by the Brafil and logwood, is much redder and more beautiful than that obtained from the logwood only, though not moredurablci it is even more ealily injured by foap. Though this violet is produced by two ingre- dients, it is neverthelefs neceffary to ufe them one after another; becaufe if mixed, the colour would be uneven. Neither is it a matter of indifference which of thofe liquors fliould be firft applied. Begin therefore DYING SILK. 345 therefore with the Brafil, remembring our former obfervation, that the filk when impreg- nated with the logwood dye, talves the Brafil with more difficulty, probably proceeding from the avidity with which the logwood feifes the alum, not leaving fufficient for the Brafil. It is befides necefiary, if you begin with the log- v/ood, to give it cold, becaufe of its inequality when hot. The combination of thefe two woods only, produces a violet; neverthelefs you add to its brightnefs by the pearl-afli, which greatly enlivens the colour, making it more purple. Inftead however of adding the pearl-afh, it is fometimes more advifable to make a clear liquor for this change. This praflice Ihould be more efpecially obferved when particular fhades are to be matched, efpecially when you are ap- prehenfive that the filk is overcharged by remain- ing too long in the dye. It is generally thought fufficient only to wafli thefe fhades at the river without beating; it may however be necefiary to beetle when wafh- ing, particularly if the colour appears dark or dull, as by this means all impurities are carried off and the colour brightened. Violets from Brafil wood and ArchiL Tj^OR this violet, as for the preceding, hav- -*■ ing boiled and alumed the filk, it is dipped in a clear liquor of Brafil wood, or in a liquor that had been ufed for reds ; it is then beetled at the river and dipped in the archil to ^11 the colour. It is afterwards wafhed a fecond time 346 THEARTOF time and again beetled. After this it is dipped in the vat, wrung, and dried with the fame ac- curacy as greens and blues. This laft refembles the fine Holland violet, made with the archil and the vat only. The Brafil previouOy given helps to fave the archil; but as thefe violets are always inferior to the Holland, this procefs is never praftifed except for the darker fhades, which can be obtained by no other means. The dye of the Brafil begins to give the filk a ftrong ground; never- thelefs it is no impediment to the effed of the archil afterwards. Thefe violets are prevented from having the brightnefs and beauty of the Hollands by the aluming neceffarily required for extracting the Brafil, the alum hence acquiring the property of making the archil rufty, or of giving it a yellow caft unfavourable to this colour. To dye violets in the rav;^, the filk fliould be as white as for yellow. When dipped the pro- cefs is the fame as for boiled filk, each according to the fhade required. The fine violet is not ufually pradlifed on the raw. Of Purple J Gillyflower J and of fine Cochineal or Purple. •^ t HE filk for thefe coloyrs is boiled as ufual, •*■ and alumed as for fine violets : the cochi- nealing alfo in the fame manner: — the common quantity of cochineal, is two ounces, more or lefs according to the Ihade required. The filk having boiled for two hours in the cochineal liquor, is taken out, waflied, and beetled at the river. If a purple violet inclining to blue, is D Y I N G S 1 L K. 347 18 wanted, it requires only to be dipped in a weak vat- In this cafe, as we have before obferved, it is neceflary to wringand dry with all poITible expedi- tion, this precaution being abfolutely necelTary for all colours dipped in the vat ; there is however no necefllty for dipping in the vat, except for purples and thedarker fhades, the others requiring only to be dipped in cold water with a little of the liquor of the vat, as they always acquire too niuch blue when dipped in the vat, though ever fo much exhaufted. To afTift the turning of thefe colours, a little arfenic may be added to the cochineal liquor, about half an ounce to every pound of filk. The light fhades are done in the fame manner, remembring to put lefs cochineal; the fhades under purple are thofe called gillyflower and grijdelin\ thofe under ^r//'"^c'//;2 are called peach- blollbm. The gillyflower requires no turnings nor even the other fliades if not too red, in which cafe they may be turned with a little of the liquor of the vat. Of Falfe Purple, 'T^HESE falfe purples are alumed as for the -*• common Brafil colours ; when given a flight Brafil liquor, the filk is once beetled at the river, and afterwards dipped in the archil liquor, ftronger or weaker according to the ihade. The Brafil given before the archil is neceflTary, becaufe the colour of the archil alone would be too violet. For browning the dark fhades, logwood is ufed, either in the Brafil liquor if required very tl^rk, or if not quite fo dark, in the archil. The 348 THEARTOF The lighteft of thofe (hades may be produced with Brafil only, and afterwards turned with clean water with the addition of fome pearl- afhj but as this method rather hardens the filk, it were more advifeable to give them a little of the archil liquor after the Brafil; neverthelefs if the colour be too violet it may be reddened with a little clean water and a little vinegar, or lemon juice. The falfe gillyflower may be produced by the archil only, omitting the previous dye' of the brafil, as for purples, and therefore there is no neceffity for aluming. If not violet enough you give it a little pearl-afh; the light ihades are produced in the fame manner, only with weaker liquors. Fine purples, or fine gillyflowers, are not cufliomary in the raw; but with regard to falfc Ihades the filk fliould be of the whiteft, as for common colours. After foaking it Ihould be treated as boiled filks. Of Marones, Cinnamons j end Wine Lees. 'T^HESE colours are obtained from logwood, ■*' brafil, and fufiic. For cinnamon colours the filk is boiled as ufual, then alumed, and then a decoflion of thefe three woods made feparately. Tne fuftic decoftion makes the bafe of the liquor, to which is added about a quarter of the Brafil decoftion, and about an eighteenth of the decoflion of logwood. This liquor fliould be of a temperate heat; the filk is then returned, and when the liquor isi D Y I N G S I L K. 349 Is exliaufted and the colour equal, it Is wrung in the hand; it is then put on the rods and a fecond liquor made, in which thefe three colour- ing ingredients are proportioned according to their efFefts in producing the fhade required. Fuftic evidently gives the yellow j brafil the red, and logwood the darker fnades, of which thefe colours are coinpofed. Marones are produced in the fame manner precifely, except that thefe latter fhades being darker and lefs red, the logwood fhould pre- dominate over the Brafil, remembring always to keep a juft proportion of the fuftic, which gives the ground to each of thefe colours. The plumb juicey wine leesy &c. fhould be done in the fame manner and with the fame in- gredients, altering only the proportion as occa^ fion requires. Remarks, THE fuftic deco6tion fhould be made as it is wanted only, becaufe it very foon changes and fpoils, becoming flimy, tarnifhed, getting an olive caft, and no longer producing the de- fired eftefl. This decoction, however, though thus changed, may be almoft entirely reftored by re-heating, and then may do well enough for thefe colours. Many Dyers wafti the filk, out of the alum- ing, at the river before it is dipped, and then by one liquor produce thefe feveral colours; but the following method feems better; becaufe the firft liquor being a fufliclent wafti, and the filk retaining more of the alum takes the dye better 350 THE ART or better. Befides as it is impoflible to pfodirce thefe ihades but by perpetual handling, the fecond liquor may be ufeful in reclifying the defeds of the firft, and in finilhing the colour, efpecially the fuftic ground, which requires the alum to aflift it in roufmg fufficiently. The marones and cinnamons may be obtained by a different method. When the filk is boiled, the grounds of the rocou fliould be again dif- folved in the fame foap which had been ufed for the boiling, by ftraining it, as before defcribed, through the rocou-pot; and when boiled for about a quarter of an hour, it fliould be lefc to fettle J the filk is then returned in this liquor without having been wafhed, which gives it a yellow ground. It is afterwards wafhed and beetled at the river, and then alumed as ufual. After this, the fuftic, Brafil, and logwood liquors are given for the cinnamon j but for the marone, the Brafil is omitted unlefs they feem to want red, remembring that the aluming confiderably reddens the rocou. If they are too red, though "without the Brafil, a little of the folution of copperas added to the liquor will check the red, give it a greenifh colour, and at the fame time darken it fufHciently, particularly if it has had any quantity of the logwood; it is therefore ne- cefTary to be fparing of the logwood, that you may be able, by means of the copperas, to correft the too great rednefs of the rocou. This methpd may be more advantageous than the firil, confidering that the rocou, reddened with alum, is much more folid than the red of Brafil D Y I N G S I L K. 351 Brafil. A little, rocou however may be added without foapp as for ratines. For marones and other browns in the' raw, the filk may be ufed in its qatural colour, becaufe the yellow is no way prejudicial to thefe fhadcs; on the contrary, it may anfwer the purpofe of a ground. Having dipped as ufual, the procefs is the fame as for boiled filk, each ac- cording to its fliade. OfNut-Creys, Thorn-Grey Sy Black and Iron-Greys, and others of thefarae/pecies. ALL thefe colours, except black-grey, ara produced without aluming. The filk being wafhed from the foap and drained on the peg, a liquor is made of fufiic, logwood, ar- chil, and copperas. Fuftic gives the ground; ' archil the red J logwood darkens j and the cop- peras foftens all thefe colours, turns them grey, and at the fame time ferves indead of alum in extradling thefe feveral colours. As there is an infinite variety of greys without any pofitive names, and produced by the fame methods, it would be endlefs to enter into a detail that would prolong this treatife to fo little purpofe. Suffice it to rem.ark here, that in producing a reddifh grey the archil Ihould predominate ; for thofe more grey, the logwood; and for thofe (till more rufty and rather greenifh, fufiic. In general, when obliged to complete the colour with logwood, it fliould be ufed rather iparingly, becaufe it is apt in drying to darken too much, differing in this particular from all gther colours. To 352 THEART'OF To give an example of the manner of pro- ducing thefe colours we fiiall take the nut- The fuftic deco6lion, archil and a little logwood is put into water modrately hot. The filk is then returned, and when the liquor is ex- haufted it is taken out, and to foften the colour the copperas folution is added. Son-:e dyers for this purpofe add the black waili inftead of the copperas; the filk is again returned, and if the colour does not appear fufficiently even, fom^ red fpots Hill remaining, it may be concluded that it requires a little more copperas. It muft alfo be remembered, that as copperas is the general bafe of all greys, if deficient in quantity, the colour will be apt to change in drying, and to become rough and uneven. To try if the colour be fufficiently foftened, it fhould be examined, and if it wetseafily, after having been wrung on the peg it wants copperas, but if on the contrary it foaks with a little difficulty, the colour is enough foftened. On the other hand, too much copperas (lifFens the filk confiderably, making it harffi, and even depriving it of a great part of its luftre. To remedy this, the filk when taken out of the liquor fhould be wrung on the peg, and then immediately wafhed at the river, which carries off the fuperfluous copperas. The black greys, becaufe alumed and welded, make a feparate clafs. When the filk is alumed and cooled at the river, and the weld liquor prepared as for yellows, the filk is returned, and when the liquor is exhaufted a part of it is thrown away D Y I N G S I L K. 353 away> and the logwood deco6tion fubftituted in its place. The filk is again returned in this liquor, and when the logwood is exhaufted, fome copperas may be added in a fufficient quantity to blacken the colour. The filk is then wafhed, Wrungj and finilhed as ufual. For iron grey, it is neceflfary to boil the fame as for blues, this colour is much more beautiful when laid on a very white ground. It is more ufed in the manufafluring of ftockings than any other colour, therefore generally wrought in Ihades j that is many different fhades made at the the fame time. When the filk is wafhed and prepared as ufual, you make the liquor of river or well water> no matter which j but either muft be cold. If river water, the logwood deco6lion made with river water is added, fufficient to produce the dark ihade required; the filk is then dipped and when finifhed, it is wrung and hung up. A part of the liquor is then thrown away and re- plenifhed with water for the following fhades, and fo on to the lighteil, carefully dividing; that is, preferving an equal diftance between the Ihades. When all is finifhed with the logwood, the dark Ihades are put again on the rods, to be dipped in a new liquor with the addition of copperas ; the remaining lighter fhades are then dipped in the fame liquor, but without the copperas addition: if however the fecond fhade is not enough fofcened, a little copperas muft be added. This defe(5t is eafily perceived in the dipping, as we have before obfervcd. When arrived at the lighteft Ihades, care fhould be taken that the liquor be not overcharged with A a copperas 354 THE ART OF copperas, which is eafily perceived by its having a rcddifh caft, in which cafe fome of the liquor lliould be thrown away, and replenilhing with water, too much copperas producing the fame effeft with regard to thcfe fhades as the pre- cedino;. When the liquor is made with well-water, the logwood deco6tion Pnould alfo be made of of \yell-water. This being added to the liquor, the darkeft fhades are firft dipped as in the pre- ccceding procefs. When the filk has fufficiently drawn it is taken out, and the following fliades are then dipped, but without replenifhing, the colour being much better and clearer without the river water. When all the fhades are compleat, you foften with copperas, in the fame manner as above defcribed i the filk is afterwards waflied, and if neceflary beetled. To difcharge greys, as well as marones and cinnamon, &:c. that is when the fliades are too dark and too full, you put fome tartar pounded in a mortar and fifted into a bucket or fmall trough; you then pour over it fome boiling water. The cleared of this liquor is afterwards put in a trough, and the filks returned in it, by which operation, a part of the colour is immediately difcharged. If the filk does not inftantly take an equal colour, a little more tartar muft be added, as above mentioned. The filk thus difcharged of its fuperf^uous colour is once beetled at the river, and after- wards dipped in hoc water, without any other addition bYlNG SILK. 355 iaddition. This laft operation reftores in part what it had loft by the tartar; but to try the colour it fhould be wrung on the peg. The tartar always deftroying fome part of this colour, it fhould be reftored with a frefh liquor made for the purpofe^ and then foftened with copperas as ufual. If the filk has been alumed then the hot Nvater may be omitted after the beetling; the hot water is however always of ufe in removing the harflinefs occafioned by the tartar. To difcharge iron greys, when too dark, they fhould be fulphured, afterwards beetled at the river, and then again dipped in a frefh liquor fimilar to the firft. This method of difcharging iron greys is pre- ferable to either tartar or lemon juice, thefe ingredients giving them a ground that does not cafily yield even to the boiling with foap, which confequently fpoils the colour; whereas the fulphuring almoft intirely v/hitens the filk by totally deftroying the logwood. For greys in the raw, the filk fhould be as white as for common colours, except the black grey, for which the natural yellow would be no difadvantage. Having foaktd the raw filk the procefs is then the fame for producing thefe fhades, as on boiled filk. A a 2 Of 356 THE ART OF Of Black, BLACK is rather adifficult dye on filk : we have at lead reafon to think fo, confidering the numberlefs experiments and enquiries that have been found neceffary in the attainn^ent of a eood blacks and if v^e may judge frorn the multitude of ingredients that are admitted into the compofition of this colour. , , ^ , The bafe or foundation of the black dye, is generally compofed of ingredients commonly ufed in making of ink, "Siz. iron diffolved by acids and precipitated by a vegetable aftringent. Different manufadories have different methods of producing this colour, though all agree in nearly the fame bafe or foundation. We ftiaU however defcribe the procefs, as pradifed m xnanv refpeftable dye-houfes, and in which wc Zfelves^ave been very fuccefsful, notwith- ftanding its many apparently fuperfluous ingrc- dients. . ^ • ^_ . Twentv quarts of ftrong vinegar are put into a trough with one pound of black nutgalls pounded and fifted, and five pounds of frefh iron filings While the infufion is making, you clean out the copper in which you put the black ground, with the following drugs pounded. Viz. 8 fe of black natgdh 8 — of Cummia ^ of Sumach 12 __ of Poragranate rind ^ — of bitKt apple 3 ft of Agaric 2 of C(jf//^ de Levtva lo — of Buckthora 6 — of liafecd The D Y I N G S I L K. 357 Thefe feveial drugs are put into a copper, containing half the'quantity of the veflel ufed for the black ground, and filled with water. Twenty pounds of Campeachy or logwood chips are after- wards inclofed in a linen bag, for the conveniency of taking them out of the liquor, unlefs you. chufe to take them out with a pierced ladle, or any other means, becaufe thefe mufl boil a fecond time as well as the other drugs When the logv/ood has boiled for about a quarter of an hour, it is then taken out and properly prefcrved. The above mentioned drugs are then put into the logwood decodion, and alfo boiled for about a quarter of an hour, care- fully checking with cold water as often as it feems ready to boil over. This operation being finilhed, the liquor is drained through a linen drainer into a trough, and then left to fettle, carefully preferving the grounds which mufl: be again boiled. The cold infufion of the vinegar with the nutgalls and iron filings is then put into the copper, intended for the black ground. The fire is afterwards put under it, and the foUowino- ingredients immediately added. Viz. 20 lb of Gum Arabic pounded 3 — of PvCalgar or red arfenic — of Sal-ammoniac — of Sal. gem. — of Mineral cryftal — of White arfenic pounded T— of Corrofive fubliajate 2 }fe of green copperas 2 — ofthe(kumofSugarCap,dj 10 — of Powder Sugar 4 — of Litharge pounded 5 — of Antimony 2 — of Orpimcnt z — of Plumba go Aa3 Thefa 35S THEARTOF Thefe feveral drugs fhould be pounded and fifted except the gum arable, which is only- broken. Inftead of gunn-arabic the native gums may- be ufed, and diffolved in the following manner. Some of the logwood decodbion is put into a boiler; when hot, you put into it a copper ftrainer, made in the Ihapc of an egg, and open at the largeft end. See this utenfil in F, Plate VI. fig. 2. The gum is put into this ftrainer, and diflblves as the liquor heats; it muft be ftirred with a wooden peftel that it may pafs through the holes. When it is intirely paffed you introduce another copper ftrainer, with holes ftill fmaller than the former. To prevent the impurities of the gum from efcaping. The liquor of the gum already diffolved is poured into this ftrainer and again paffed as before, by the help of the peftel. This operation is made more eafy, by now and then taking out the ftrainer and refting it on a crofs llielf or plank, fufpended on the peg over the copper ufed for wringing the black. The gum muft be fqueezed pretty hard with the peftel to force it through the holes of the ftrainer. The gum would diffolve with more facility, if previoully fteeped for three or four days in the logwood deco6tion, efpecially if you are careful to pour it on very hot. When the above ingredients are put into the black ground, you muft remember to keep the liquor hot enough to diffolve the gum and the falts, but it ftiould never be fuffered to boil ; and when it is therefore fufficiently hot, the fire is D Y I N G S I L K. 359 IS taken away and the frefh iron filings fprinkled over it, in a [iroper quantity to cover the liquor. The next morning the fire is again put under the copper, the drugs boiled and the logwod z fecond time boiled. It is then taken out and the following drugs added to this fecond dc- co6lion. Fiz. 2 Jfe of black Nutgalls pounded 4 — of Sumach 4 — of Cummin 5 — of Buckthorn berries 6 — of Pomgranate rinds pounded 1 Jd of bitter Apple 2 — of Agaric pounded 2 — of Coque de Levant 5 — of Linfeed Thefe drugs are boiled, the liquor drained and poured on the black ground as we have already faid, and the grounds preferved. You then put a little fire under the copper as at firfl:, and the following drugs are immediately added Viz. % oz. of Litharge pounded 8 — of Antimony pounded 8 — of Plumb de }Her, alfo pounded S — of White Arfenic pounded S — of Chryftal-mineral 8 oz. of Rock fait 8 — of Fenugrek 8 — of Corrofu e fublimate 8 ife of Copperas 20 — of Gum-Arabic, prepared as above When the liquor is hot enough, you take away the fire j flrewing over the liquor, with the iron filings and letting it ftand for three or four days. Two pounds of verdigris are then pounded and diflblved with fix quarts of vinegar, in an earthen pot, adding to it about an ounce of cream of tartar. The whole fliould boil for a full hour A a 4 taking 36o THE ART OF taking care to check the boiling, with cold vinegar that it may may not boil over ; this pre- paration fliould be kept ready to be added to the black ground, when you are going to dye. For the black dye the filk is boiled as ufual, having walhed and beetled according to cuflom^^ you give the gall liquor for heavy blacks twice^^ but for light blacks only once. Thefe two blacks are alike both in beauty and Ihade, differing only in the weight of the filk : the light black has however rather more luftre. The nutgall liquor is made as follows: For every pound of filk you muft have three quar- ters of a pound of light nutgalls, adding the fame quantity of aleppo. Thefe galls are pounded together, and boiled for two hours, in a quantity of water fufRcient for the whole of the filk to be galled. As the liquor waftes a great deal in !'the boiling, it is, after the firfl" hour, filled again, and after two hours the fire is taken away ; the liquor is then left to depofite, and the galls taken out with a pierced ladle j about an hour afterwards the filk is put into it, prepared in the following manner. During this operation, the filk is drained on the peg, put on the cords as for boiling, and only very lightly fqueezed : it is then immerfed in the gall liquor, on cords one above another, taking care to keep it near the furface of the li- quor, but fufliciently covered. In this manner it Ihould remain twelve or fifteen hours ; it is then taken out, wallied at the river, and if in- tended fpr heavy black, is a fecond time galled in a frefh galling, like the firiti the grounds ar« DYING SILK, 36f are generally iifed for the firfl: galling ; but for the fecond a liquor of frefh drugs. Some Dyers gall the heavy blacks but once, by boiling the old grounds, taking them out immediately, and afterwards adding frefh galls ; for every pound of filk, a pound of light crall, and half a pound of fine Aleppo. The frelb galls they boil for two hours or more, and when the grounds are taken out, they put the filk in the frefli gall liquor, where they let it remain a day ^nd a night. This method, they fay, is the beflr, becaufe were the gall grounds to remain in the liquor, they would re-imbibe part of the fubftance which they had before given to the water. When the filk is galled a little fire is put under the black ground j while it is heating the filk is wrung out of the galling and beetled at the river. When wafhed it is drained on the pegs, pafTing a thread round every hank, each hank as large as for common colours : it is then immediately put on the rods. While the black liquor is heating, it fhould be ftirred with an iron rake, or paddle, to prevent the grounds from flicking to the bottom of the copper. You then diflblve fome French gum by the method above dcfcribed, till it rifes on the top in a kind of fkum covering the furface of the liquor ; afterwards, you throw into it two or three handfuls of linfeed. You then add half of the vinegar and verdigris preparation yi'ith about four or five pounds of copperas ; thii 36b THEARTOF this lliould be pundlually repeated at every heating. Care lliould be taken whilft the fire is under the copper to rake, and to try if it be hot enough the rake is moved round at the bottom of the copper; if the gum flicks to the rake, and that the liquor does not appear through the middle of the gummy fcum, it Ihews that it is hot enough ; the fire is then taken away, becaufe, as we have before obferved, it fhould not boil. The rake is then alfo taken out, and the liquor covered with the iron filings in the fame manner as before ; after this it is fufFercd to fubfide for about an hour, when the furface of the liquor is again ftirred, in order to precipitate the filings to the bottom. Before we explain the manner of dipping filk in the black liquor, it is proper to obferve that Silk Dyers never dye black but by coppers, that is when they have a fufficient quantity of filk for three dips, if for heavy black ; but if light black only two dips, which is done in the following manner. If heavy black, a third of the filk is put upon the rods, and three times returned in the black ground; it is afterwards wrung on the peg over the copper; this is done by giving it three twifts J in this manner three hanks may be wruncy at once, becaufe it fhould be done gen- tly, and only to drain ; it is "again put on the rods, and fufpended between two perches to air. While the firfl filk is airing, the fecond third part is dipped in the fame manner, and after- wards the third third part, always in the fame manner DYING SILK, 363 rnanner. It muft be remembered that while the filk is on the rods, it fhould be turned from time CO time to give it air. When the laft third part is wrung, the firfl: part is put in, and then the two others fuccef- fively for three times, always airing at each time. This is commonly called giving the three wrino-s, and thefe three wrings are called one fire or heating. The light blacks fhould alfo have three wrings to one fire. After each fire the black ground is again heated, adding copperas and gum as before. This opera- tion is thrice done for the heavy blacks, thatis three fires^ each fire confiding of three wrings; but for light blacks only twice, each alfo confifting of three wrings. It muft be obferved that -at every reheating it is requifite to change the order of dipping, in fuch a manner that each may in its turn have the firft of the liquor. If the black dye is ftrong and good^ the heavy blacks may be done with two fires only ; and for the light blacks one wringing lefs may do for each heating. When blacks are finifhed they are returned in a trough of cold water by dips one after another, called by the French Dyers dijhrcder or rincino-; they are then twice or thrice beetled at the river. When waflied you put them on the cords, only taking care not to prefs them too much. Of 364 THE ART OF Softening of Black, 'T^HE filk when taken out of the black dye •*• is extremely harfh, which is by no means wonderful, confidering the number of acids and corrofives in the compofition. It is there- fore necefiary to foften in the following manner; DiiTolve about five pounds of foap in two buckets of water, and while the foap is diffolv- ing, throw in a handful of anifeed or any other aromatick plant. It fhould boil till the foap is entirely difTolved. In the mean time a trough Ihould be provided full of cold water, and large enough to dip all the filk at the fame time. The foap- water fhould be {trained through linen, the whole mixed well together, and the filk put in, where it fhould remain a full quarter of an hour. It is then taken out, wrung on the peg, and dried as ufual. As the quantity of foap can do no harm, too much is better than too little. This foftening is very necefl^ary, in order to diveft the filk of that ruftling and llifFnefs fo prejudicial in the manufacture of black goods. Black in the raw. ''T~^0 dye black in the raw, the filk Ihould be •^ galled in a cold liquor of frefh galls, which had been previofly ufed for the boiled (ilk. The natural yellow of the filk is prefer rable for this dye, becaufe the white takes a lefs beautiful caft. Having untied the filk and divided it into hanks of the common fize, it is dipped with tht DYING SILK. 365 the hands into the gall liquor. When foaked and a little fqueezed, it is ftrung on cords, eight or ten hanks together. They are afterwards put into the cold gall- liquor, one above another, letting even the cords fink in the liquor, where they may remain for fix or feven days. They are then taken out and once beetled at the river. As to time, it Ihould remain in the galling according to the ftrength of the liquor and the quantity of the filk puc into it J but however ftrong it may be, and however fmall the quantity of filk, it Ihould remain two or three days at leall. When the filk is wafhed, it is again ftrung on the cotds and left to drain, after which the cords are put one over the other into the rincing or black wafli, which is of itfelf fufficient to dye ; it will however require more or lefs time accord- ing to the ftrength of the rincing wafti, gene- rally about three or four days. Whilft the fillc is thus immerfed in the rincing water, it fhould be raifed with fticks three or four times a day; it is then drained over the liquor, and when drained put on the ground in a proper place, where it is fpread and aired, but not dried. This is abfolutely neceflary to produce the black ; elfe the filk might take a black- grey j this grey would however blacken in the air, neverthelefs you are thereby enabled to judge how much of the colour it has taken, and how much it may ftill want. Should the filk be fufFered to dry, it muft be again wet- ted before it is re-dipped, which would be an additional and unneceftary trouble. This ope- ration 356 THE AkT 01^ ration of wafhing and djying rrluft be fuccef- lively continued till the filk is fufficiently black. The filk in this fituation is carried to tht river, and twice beetled, after which it is drained on the cords and then put on the perches to dry, without wringing, which would fofteri it too much J for as this kind of filk is defigned for gauzes and black lace, care fhould be taken to preferve its natural ftiffnefs as much a^ pofTible. To produce black in the raw in the quickeft manner, the filk when wafhed from its galling Ihould be put on the rods and three times re- turned in the blacking ground j it is then taken out, and put to drain over the Veflel containing the black liquor, and then cooled on the rods. When drained, it is again twice dipped in the black liquor, drained, and each time cooled as at firft. When drained it is again wafhed, and the procedure is then the fame as for thofe •which had been dyed in the rincing. This h not however the ufual method of dying black in the raw; becaufe it confumes the black liquor too foon, confidering with what avidity the raw filk takes any colour whatever; and befides that a good dijbrodurey or rincing, is fufficiently ftrong for dying this colour. The black dye is weakened and becomes ex- hauftcd in proportion to the filk it has dyed; it is therefore neceflary to flrengthen and re- plenifh, from time to time, by an addition of proper drugs, which is called giving the brevet, or compofttion. This compofition is made by putting four or five buckets of water into a copper, and then boiling THEARTOF 36; boiling it with abbut four pounds of logwood chips. The logwood is then taken out, and four pounds of black buckthorn berries is added with two pounds of ponngranate rind, two pounds of fumach, two pounds of Coque ds Levant, two pounds of coliquinte, two pounds of linfeed, aad four pounds of cummin. Thefe drugs are boiled together for about three quarters of an hour; the fire is then put under the black liquor; when a little more than half boiled, and whilfl hot the following drugs are added. Viz. I fo of White arfenick 2 fe of Realgar 4 — of Antimony I — of Gold Litharge I — of Silver Litharse 1 — of Sal-ammoniac I — of Rock fait I — of Chriftal mineral I — of Corrofive fublimatc I — of Orpiment I — of Powder fugar o I — of Funegrck 4 — of Copperas Thefe drugs, when all pounded, are thrown into the black ground, remembring to ftir. When the compofition is fufficiently boiled it is drained in a trough and left to fetde; the grounds having fubfided, the clear part is added to the black ground. The fame grounds are again boiled and preferved for fome other time. The compofition being added to the black liquor, and fufficiently hot, the fire is taken away. The liquor is then ftrewed over with the iron filing, and left to fettle for two days. When the black ground has had a certain number of, additions, and a quantity of fediment collefted at the bottom, part of the grounds fhould be taken out in order to clear the liquor. Thus frequently repleniiliing, the foundation 368 THEARTOF is always preferved, fo that the liquor Is never entirely newj but having been once fet in a dye-houfe is fet for ever. Thefe liquors are never liable to putrefadlion, owing to the great quantity of nutgalls and martial vitriol in th« compofition, two of the moll powerful antifep- Cicks known. Remarks on Black, IT has been already remarked, that amongft the numberlefs drugs in the compofition of this colour, we may reafonably fuppofe that feveral of them are ufelefs. This however may be eafily afcertained by a comparifon with the fol- lowing procefs for Genoa black. The mofl: material obfervation concerning the black dye is, that in general it greatly injures the goods, in fuch a manner that fluffs of this colour, though not inferior in other refpefts, wear out much fooner than thofe of any other. This defed may be attributed to the vitriolic acid of the copperas, which is but imperfedly faturated with the iron. Iron combined with any, even vegetable, acid, is capable of producing black with vegetable aftringents. It is therefore moflprobablethat this inconvenience might pofTi- bly be removed, by ftubflituting other combina- tions of this metal for the copperas, if it were however worth while to make the attempt. From whas has been faid concerning the pro- cefs of dying black, it is very evident that great care fhould be taken to dip the filk in the black at three different times, and to open and air it between every dip. This infinitely 3 contributes D Y I N G S I L K. 369 contributes to the beauty of the black, fo dif- ferent in this particular from all other colour3 which lofe a great part of their intenfity in dry- ing. It is a well-known fa6b that good writing ink improves by the air ; and that it is never fo black when frefli and firft ufed as it appears afterwards. So with regard to the black dye; for filk, though no more than a greyifh black after the firft dip, acquires a beautiful black on being expofed to the air. The blue vat is an additional inftance of the efFe6b of air on colours, as the filk, though green when dipped, becomes almoft immediately blue on being ex- pofed to the air. PARTICULAR PROCESSES Communicated by M. Hellot*. ACCORDING to the letters of M. Grange, correfpondent of the Royal Society, who died at Schiras in Perfia, June 1737, the Dyers of the city of Damas dyed their crimfon colour, fo beautiful and fo much efteemed in the Eaft, in the following manner: Take ten rottes (a rotte weighs five pounds) of filk in fkeinsj wafh it well in warm water; then let it foak in a fufficicnt quantity of hot water during half an hour; fqueeze out the water; dip it afterwards, but once only, in a hot lixivium, made with a fufficient quantity of •None of the following proceffes were publifhed; they were taken from the manufcripts of M, Hellot, and never before communicated to the public. B b water. 370 THEARTOF water, half a rotte of kelp allies for every rotts of filk, which is immediately drained on rods, taking care not to leave the filk longer m the lixivium than is neceflary for its being well foaked, left the alkali fhcruid corrode it. Whilft the filk drains they prepare another liquor cold, with ten ounces of the pulp of yellow melon, very ripe, which is uniformly diffufed in a fufficient quantity of water. They fteep in this liquor the ten rottes of filk for twenty-four hours ; they increafe or diminifh the quantity of the above drugs in proportion to the quan- tity of the filk to be dyed. The filk having remained one day in this niclon liquor, is feveral times wafhed in frefti water till it becomes per- fedly clean ; they then hang it to dry. Mean while the workmen fill a large pan of water, adding a half rotte of alum powdered for every rotte of filk. The pan is then fufpended over a hot furnace, and the liquor boiled during twenty minutesj after which the fire is taken from the furnace. The filk is then dipped in I this alum folution, moderately hot, and again taken out as foon as it is perfedily wet. They then put it into another pan, pouring over it the alum folution, in which it remains four or five hours but no longer. It is then taken out and feveral times wafhed in frefli water. Whilft the filk is walhing, a workman fills a large pan with water, adding an ounce of baijcnge (a fungus) finely powdered, for every rotte of filk; when this new deco6lion has boiled for half an hour, they add ten ounces of oudez (cochineal) DYING SILK. ^i (cochineal) very finely powdered, for every rotte of filk ; that is, fix pounds four ounces of cochineal for ten rottes of filk. As foon as this cochineal is added the fire is taken from the furnace. The liquor is then gently ftirred round with a flick, and when the mixture is perfectly made, they pour gently and by inclination a little frefh water into the middle of the pan. The water thus added not only cools the dye but makes it much more lively. They then imme- diately dip the filk four or five times, wringing after every dip. This tinfture is afterwards boiled again for about a quarter of an hour, and the fire is then taken from the furnace as before. When the liquor is a little cool they dip the filk, ftill obferving to wring after every dip. This done, they put the filk into an empty kettle, pouring over it the remainder of the dye, in which it is left to foak for four-and- twenty hours. It is then well wafhed in clean water, dryed in the fhade, and when very dry wove into fluffs. This crimfon is much fupe- rior to all the French and Italian crimfons ; becaufe the filk was never boiled in the dye. The Dyers of Damas and Diarbequir fay, that they could not accomplilh this dye without the pulp of the yellow melon in the preparation, or without tlie baifonge ufed with the cochineal in the dye. According to M. Grainge, we have this melon in France j but he doubts con- cerning the baifongey which is a fpecies of fungus growing on trees in fome parts of Perfia, from whence it is brought to Damas, and might alfo be fent into France, by the way of Aleppo, B b 2 were 372 THE ART OF were we defiroiis of imitating this excellence in the crimfon dye. To avoid nniftakes in the quantity of the different ingredients employed in this proccfs, it may be neceffary to repeat, that a rotte of filk weighs five French pounds, and that the ten rottes of filk, produced as an example in this memoir, fhould alfo ferve as a ftandard with regard to the quantities of the other ingredients. As to the water neceflJary for the prreparation of the filk, with the kelp, melon, and the alum for the dye, it requires no more than a fufficient quantity for wetting the filk, namely, about a fingers breadth over it, differing froni the tin6lure, which as the fKeins are dipped in this liquor at leaft ten or a dbzen times, fhotild be fuller in the kettle. The kali ufed in the preparation of the filk is nothing more than the afhes of a plant, called by the Arabs kailou. Thefe are preferable to the afhes made from the rouquet^ or thofc made in Egypt. The frames ufed for thefe filks are fimilar to the frames ufed at Lyons. Genoa Crimjony a procefs proved in May 17 43' AT Genoa the filks defigned for crimfon are boiled in a much lefs quantity of foap than thofe intended for any other colour; eighteen or twenty pounds ferving for a hundred pounds of filk in the crimfon dyej for any other colour, the Genoefe ufe forty or fifty. When the filk is boiled, it is dipped in the alum liquor, and to a quantity of raw filk, 4 weighing DYING SILK. 373 weighing feventy-two pounds, they put from fixteen to eighteen pounds of roch alum, finely powdered, into a copper full of cold water. When the alum is perfeflly diflblved, the filk is put to foak in it for near four hours j it may remain longer without any inconvenience; filk intended for crimfon requiring more alum than for any other colour. When taken out of the alum liquor it is lliook and drefled on the pegs, but without wringing. One of the Dyers being queftioned why the filk was not wrung when taken out of the liquor, anfwered, that it would purge it too much from an impreg- nation To abfolutely neceffary for its taking the crimfon dye. Of the feventy-two pounds of filk already mentioned, thirty-two pounds is organzine^ and the remaining woof. At Genoa it is the CLiIlom to allow two ounces of cochineal to twelve of organzine, if defigned for the warp of damaflc furniture, and for the fame filk an ounce and three quarters of cochineal for twelve ounces of the woof, fuppofing it ncceflary to the beauty of the filk, that the warp fhould be fuller than the woof i and to bring the colour of the damafk to ftiJl more perfc6tion, they add to the crganzine a quarter of an ounce of cochi- neal, that is, inftead of two ounces they add two ounces and a quarter, adding no more to the woof than one ounce and three quarters. As the above thirty-two pounds of organzine Ihould be of the fineft; colour, they allow two ounces and a quarter of cochineal to every |)0und of filk, fo that upon the whole they £ b 3 life 374- THEARTOF ufe one hundred and forty-two ounces of cochi- neal, or eleven pounds ten ounces, Genoa weight, namely, thirty-two pounds of organ- zine to two ounces and a quarter of 'cochineal, making feventy-two ounces: forty pounds of woof to one ounce and three quarters, making feventy ounces-r-total 142 ounces. In order to dye: this feventy-two pounds of filk, alumed as above, they make ufe of an oval copper containing, when full, two hundred quarts of water; they fill this copper two- thirds full of clean fountain water, adding afterwards the following drugs pounded and fifted. Two ounces ot tartar, two ounces of Jaffranum, and two pounds and a half of the Levant 2:alls. They wait till the drugs have boiled two minutes in this liquor; after which they add the eleven pounds ten ounces of cochineal finely powdered and fifted; and whilft one of the workmen by degrees makes it fink to the bottom, another keeps violently ftirring the liquor with a ftick to promote the folution. This done, they fill the vefiel with clean water to about a foot of the edge, immediately afterwards dipping the thirty-two pounds of crganzme divided on fourteen rods. They let it remain till the vefiel which they fill with clean water, and under which they put a large fire, is ready to boil j they then, to make the filk take the colour more evenly, raife the rods without ceafing, one after another, that each may alternately reach the bottom of the copper, which being but two-thirds full, the upper pvc DYING SILK. 375 of the filk would elfe remain out of the liquor, the rods being fupported on the edge of the copper. When the liquor was ready to boil, the forty pounds of woof, divided on eighteen rods, wer« dipped. They ftill continuing to raife the rods, one after another for half an hour, both organzine the and the woof, that each may alternately reach the bottom, fo that when the workman came to the laft he returned to the firft, and fo on fuccefiively. After the firft half-hour, they flopped for a quar- ter of an hour between every operation, the work- men ftill raifmg the rods from the firft to laft, five or fix times repeated in the fpace of an hour and halfj all the time keeping a good fire under the copper. The organzine was then fteeped in this liquor two hours and a quarter, and the woof only two hours. The fire was then taken from under the copper, and the workman taking out one dip of the organzine and another of the woof, he wrung and dryed them as much as he could to fee if the colour was what he wifhed; if not fufEciently deep for the purpofe, he let them both remain in the liquor fomethinglefs-than half an hour whilft the liquor was growing cold. He then took out all the filk, wrung it on the peg, then wafhed it feveral times in clean water, changing the water every time. This done he wrung it again on the pegs, and fo finifhcd the operation. It muft be obferved with regard to the organ- xine and woof, that though dyed in the fame liquor, they were not however of the fame B b 4. /hade 376 THEARTOF Ihade at the conclufion of the operation; the organzine was deeper, having been a quarter of an hour longer in the cochineal liquor, during which time it was impregnated with the more fubtle colouring particles of the cochineal. At Genoa it is not the cuftom to wafh the filk out of the cochineal v/ith foap water; on the contrary, they are perfuaded that this prac- tice dulls the brightnefs of the colour, and that the water, both for the cochineal liquor and for wafhing afterwards, fhould be the fineft fpring water ; for they remark that the crimJon dyed in fummer with ciftern water, is by no means fo bright as the crimfons dyed at other feafons when the fountains are full. According to the Dyers of Genoa, there is a kind of cochineal which though apparently beautiful, is not fo in effed:-, that in ufing this cochineal it is neceflary to alum the fiik as much] as pofTible, and to add to it more tartar than before mentioned. It is however im- pofUble to give any certain rules concering this matter; the Dyer himfelf will judge of the quality of the cochineal fit for ufe. He fhould however ufe the befl ; for were it even a faft that the inferior kind, with the afTiftance of a greater quantity of alum and tartar, gives a colour equal to the befl, the filk thus weakened by alum would neceffarily be always lefs perfeft. The Genocfe manufadurers are fo well convinced of this, that they themfelves furnifh their dyers "with cochineal in proportion to the fiik given to be dyed. riokf DYING SILK. 377 Violet Crimfon of Italy > 'TT^HE filk being alumed as for red- crimfon, -*- take it out of tlie alunning, and dye it with cochineal. For this purpofe, difTolve two ounces of gum arabic in the copperj for every pound of filk two ounces of cochineal, a third of an ounce of jigaricy and as much Turmeric. Mix and pour them into your copper j when they begin to boil and that the gum is perfectly dif- folved, arrange your filk on the rods, immerge in the copper; let it boil for two hours and it is then dyed. Let it grow cold, wafh and wring it on the peg. Wafh it afterwards lightly. To make it violet, plunge it into the blue vat till it has taken a fine violet. Wafli it in clear fountain water, wring it and dry it in the Ihade^ opening and fpreading well. Half Violet. FOR one pound of filk take a pound and a half of archil, mix it well in the liquor; make it boil for a quarter of an hour, dip the filk quickly i let it cool j wafli at the river and you will have a fine half violet or lilac, more or lefs full. Genoa Black for Velvets. 'TpHE filk fliould boil for four hours with a -"- quarter of its weight of white Marfeilks foap and be well waflied. Boil in a copper with five hundred quarts of water, feven pounds of gall. Leave the galls to fettle; draw off the clear, and having thrown away the grounds return 375 THE ART OF return the gall water into the copper. Plunge into the middle of it a pierced pot, containing feven pounds of gum fenegal, feven pounds of Roman vitriol or copperas, and {even pounds of the cleaneft iron filings. The liquor having diffolved thefe drugs extinguifii the fire, and leave it to ferment eight hours. Then heat it again, and when ready to boil, put again the fame cullender into the fame copper, and having made fix parcels, each compofed of the fixteenth part of the gum, copperas and filings intended for the black liquor, in the pro- portion of one pound of each to every ten pounds of filk, difTolve in the cullender this fixteenth part of the whole. The fire is then taken away, and having thrown ten quarts of cold water into the liquor to make it no more than hot enough to bear your hand in it, put your filks on the rods, plunge them into the liquor, where let them remain about ten minutes. Return the hanks four times, and afterwards wring them on the peg over the copper. Frefh filk may be dipped in the fame liquor, proceeding in the fame manner. Begin firft with the woof, then dip the pile, and when the liquor is almoft cold, dip the warp which" is feldom more than a black grey. The whole of the filk having been dipped in this firft liquor, the copper is then reheated, putting into it the fame cullender with another fixteenth of the gum, vitriol and iron filings, "When the liquor is cooled as before, dip the filk as in the firft liquor, obferving at this time to dip the pile firft, then the woof, and always th« DYING SILK. 379 the warp laflr, repeating this procefs fix times. While the filk remained wet the black was excellent, even when compared with that of Tours J but it became different when dry. At Tours, they thought to add to the black liquor, fmall wine, anifeed and other drugs ; but they at laft determined to fend fome of their black filks to Genoa. The following is M. Regni's opinion in writing concerning them. " The Dyers of Genoa, being made acquainted with the procefs in dying the fpecimen fub- mitted to their infpeftion, have no doubt, but that the laft inftru6lions were exadly followed, and that the want of fuccefswas owingi i**. to having ufed Levant galls, which have much more fub- ftance than thofe of Sicily and Romagne and com- monly ufed at Genoa j 2^. that the black liquor could acquire perfecftion only by a frelh dofe of the drugs of which it was compofedj fo that in new and future operations they have only to re- member in galling of the filk to make ufe of the galls o^ Sicily or of Rcmagne or if obliged to ufe the Levant, to allow but one third of a pound for every pound of filk, inftead of a half a pound of the former. The Dyers of Genoa immediately con- ceived, the kind of gall they had ufed in France from M. Regni's report — that a pound of filk weighing twelve ounces, had recovered in the galling what it had loft of its weight in the foaping, whereas it fhould recover only eleven ounces." With regard to the black liquor, it wanted pothing more to make it compleat, than an addi- ^ tiojial 38o THE ART OF tional frefh dofe of gum, iron-filings, and vitriol of each an equal quantity, which Ihould be added in fmall dofes till the filk had acquired a proper colour; remembering that thefe drugs Jhould be added to the old liquor, there being no occafion to make a frefh, fince the old acquires perfe<5lion in proportion as it is ufed. This Genofe having dipped the pattern fix times in his black dye, the black became much finer. The fame dyer, a man enriched by his profefTion, writes that abfolutely no other drug fhould enter into the compofition of the black liquor, than thofe mentioned in the laft inflrudions preceding this, and that the wine and anifeed can be of no ufe but to fpoil the black liquor. In confequence of this letter they afterwards dyed very good black at Tours. The following procefs was pradifed in the manufaclory of the late M.Hardion. For every hundred pounds of filk, they boil during an hour twenty pounds of aleppo galls powdered, in a fufficient quantity of water, the liquor is then fuffered to fubfide, and when the nutgalls fall to the bottom they are taken out. They afterwards add two pounds and a half of Englifh vitriol, twelve pounds of iron filings, and twenty pounds of native gum, either plumb or cherry, &c. which is put into a kind of pot with two handles and full of holes ; this cullender is fufpendcd in the copper, fo as not to fall to the bottom. The gum is left to dif- folve for an hour, flirring it lightly from time to time with a ftick. If after an hour, the gum remains in the pot, it Ihews that the liquor is fufEciently faturated^ if, on the contrary, all DYING SILK. 3S1 all the gum is diflblved, tliey add three or four pounds more. The cullender remains conti- nually fufpended in the liquor, except when they want to dye, and is immediately afterwards replaced. During all thefe preparations, the copper is kept hot, but not boiling. The galling is done with one third Aleppo galls. The filk is left in it for fix hours, then for twelve, and the remainder of the jproccCs fecmdum Artem^ PART III. THE ART OF DYING COTTON AND LINEN THREAD; TOGETHER WITH THE METHOD OF STAMPING SILKS, COTTONS, &c. TRANSLATED FROM THE FRENCH OF M. LE PILEUR D'APLIGNY. OF DYING IN GENERAL. DYING is the art of developing and extrafting the coloured particles of any fubftance whatever, and of uniting them afterwards to fluffs, fo as apparently to conftitute but one body. The objedt of dying is colour, as it is alfo the mechanichal part of painting, differing only in the mode of operation. The operation of both arts is expreffed by the word colouring y a term authorifed by cuflom, however improper : for neither the Painter nor the Dyer do actually colour fubflances. To do this they muft totally alter the configuration of their pores, which gives them the property of refiedling and abforbing in different degrees, the rays of light by which their different colours are produced. The Dyer indeed may enlarge the pores, and thereby produce white, in giving admiflion to a greater number of luminous rays; but quite otherwife in dying, fince by filling the pores he prevents the admiflion of thofe rays ; and by filling them with coloured bodies, it does not follow that he produces colours; but on the con- trary, that thcfe colours are pre-exifting in the fubflances employed. Some philofophers admit of only three pri- mitive colours, yellow, red, and blue. Black and white properly fpeaking are indeed no colours, white being nothing more than the reflection of C c all 386 THE ART OF all the rays of light, and black only a privation of* light. Neverthelefs as black and white bodies cxift in nature ; as it would be a very defirable thing to difcover any black drug, capable of pro- ducing this colour permanently, and as whitening is an operation which in fome refpedls belong to dying and is neceflary to the dyer, 1 prefume I may be juftified in diftinguifhing relative to this art, five primitive or fundamental colours, which combined ad infinitum may produce all pofliblc fhades. ^ Juft as paintings in water colours which eafily fade, are diftinguifhed from thofe in oyl, which are permanent, in like manner the Dyers diftin- guifh the great from the lejfer dye. But this laft does not confill as fome imagine, in de- pofiting extraneous fubftances on the furface of bodies only, or within pores not fufficiently capacious for their reception. Subftances of this nature have never been employed even in the , lefler dye, as walhing alone would carry them ofF. The lefler dye confifts in introducing into the pores of the fubftance to be dyed, matters "whofe particles are too much dilated for the capacity of the pores, and which are deprived of the gluten necelTary for their retention j or if retained are of a nature eafily altered by the aftion of the air, which changes their texture, and confequently their mode of refleflion. The great or good dye confifts in introducing into the pores of the fubftance to be dyed, certain colouring particles, which by the eflence and combination of their principles, are affer\, I neverthelefs believe that the operation indi- cated by the terms xaxEp^rat and cyj(ptTaiy was independent of aluming, and that it is more analogous to that cuftom of our Dyers in ufing for fome colours fumach, agaric, galls, and other aftringents. Their adion indeed confifts in crifping and contrafling the fibres of the fubjeft to which they are applied; hence it follows that the folid particles of thefe fibres are approximated, and the force of their cohefion confiderably augmented. The fub- ftance of the body thus a61:ed upon muft necefla- rily become more firm and compa6l, and there- fore more capable of refifting the adion of the air and of the {d\t%y by which thofe falts, already inclofed, might be difcompofed. This operation was alfo pradifed in the time of the Romans, bv whom it was called colorem alHzare, D d 2 For 404 THEARTOF For this purpofe their Dyers ufed a fpecies of fticus^ to which Pliny afcribes the property of fixing the colours on wool fo effed:ually as never to be renaovcd. Many of our fucus's are abundantly fupplied with phlogifton, the combination of which, with the falts, might produce this eifefb. The fucus growing on the coaft of England, analifed by M. Home, feems to be of this nature. It contains, fays this chymifl, more fait than any plant I know; but it contains alfo another fubftance (doubt- lefs phlogifton) that makes it incapable of whitening, efpecially fine linen, though already tolerably white. Bleachers have remarked that it communicates to linen a yellow colour. The fame author obferves, that having dried, burnt, and kept this fu£us in fufion for more than two hours, he obtained from the quantity burnt three ounces and a half of afbes, which when wafhed in three pints of cold water, pro- duced by evaporation five drachms and forty- fix grains of cryflalifed fait, containing marine fait, fulphur, and alkali. The liquor being entirely evaporated, there remained four drachms and a half of a yellow fait, which appeared to be a very Itrong alkali; He made an infufion of the fame afhes in warm water, boiled it, and during the evaporation, a piece of white linen which he had put into it for half an hour, contrafted a colour that he could never afterwards remove. This liquor when evapo- rated, gave him four drachms of a black bitter fait. From thefe refults he concluded that thefe ?ifiies contained fomething kfs than one-fourth of DYING COTTON. 405 of .flilphur [phlogijion united to marine Jalty and not Julphiir\ the fame quantity of marine fait, about a fourth of alkaline fait, and a little more than a fourth of earth. From thefe obfervations we may conclude, firft, that the burning of this fea-weed might be attended with greater advantage, and which may doubtlefs be found on the coafts of Britany and Normandy. Thefe alhes are fold in Eng- land for one pound fterling the thoufand weight. Secondly, that the fixed colour, with which the phlogifton contained in thefe aflies pene- trates the linen, might be a better and more efficacious preparation for dying than the nut- galls ufed in the black dye for wool and filk, and for dying of cotton. The phlogifton con- tained in the nutgalls being lefs adhefive becaufe of its oily nature, and I make no doubt that it will be almoft univerfally allowed that this fucus is the true alga which Pliny alTerts to be fo ufeful in the fixing of dyes. JJlringents, UNDER the denomination of aftrlngents, I comprehend all faks that are dilTolved in water for the impregnation of ftuffs, which folutions the Dyers call boilings. Thefe are principally alum, lime, marine fait, nitre, fal-ammonjac, tartar, fixed and volatile alkalies, and the various metallic falts. The utility of lime in dying has been long known, though we are ftill ignorant of its liature. It was ufed by Dyers in Pliny's time, P d 3 under 4o6 T H E A R T O F under the name of Lapis Phrygius \_See Pliny^ L. 36, Cap. 19, Se5f. ^^^ andDioJc L. 5, Cap. 41.] It is mod commonly ufed in the paftel and indigo vats intended for dying cold; but it extends to many other operations in the hands of thofe who are acquainted with its efFefts. It feems deftined by the author of nature for binding and uniting together two of the greateft oppofites, falts and earth. Fire makes it foluble in water, and therefore eafily ufed; but it again becomes indifibluble by the contadl and influence of the air. Thefe properties render it capable of forming, when united to other matter, an unalterable cement. We know feveral mixtures of this nature of which lime is the balls, and that in confequence of thefe properties, it confirms the folidity of many colours. If lime has the power of fixing colours, alum has, befides that, the property of attrafting the colouring particles. This property was not unknown to the ancients, [JeePl. L. 35, Se5}. 15,] "vrho ufed alum in their dying. Whether we are indebted to chance for the difcovery, or whether to rational enquiry, which having found in alum or in the earth of alum, the property of imbibing colouring principles with more avidity than calcarious earth, I am igno- rant. It is, however, certain that what they called Creta argentaria^ Salunifia, anulariay were fpecies of marl of the nature of argillacious earth, fuch as the earth of alum. Thefe fub- fiances were coloured with different matters, as we find by Pliny and Vitruvius^ by (leeping theni DYING COTTON. 407 them in coloured infufions, with which they became much fooner faturated than wool, [fee Pliny.'] We may prefume that this obfervation was the firfl ftep towards perfeftion in the art, as it put them upon feeking the means of intro- ducing the particles of this earth into the pores of the wool, and thereby difpofing it to imbibe the colour more readily. Alum, the acid of which holds this earth in folution, furniflied the means of afFefling it. They diftinguifh two kinds, roch and Roman alum. The firft being the cheapeft, is always ufed for blues and the colours inclining to black, but this being liable to contain fome particles of iron, the Roman alum is preferred for lively colours, becaufc it contains nothing that can tarnifh their brightnefs. The whitenefs of its earth renders the colours more bright, and its tenacity, produced by a certain unduofity with which it is combined, more folid. The plaftic quality of this earth makes it take the form of the pores of the fubje(5t to be dyed : a greater permanency of colour muft neceflarily enfue. They alfo in dying ufe nitre, marine fait, fal-ammoniac, and tartar, not indeed as aftrin- gents, but as alterants. The three firft cer- tainly fadden the reds, giving them a crimfon tinge; the tartar and other acids produce an effed quite contrary; they enliven by inclining the colour to orange. Neutral falts, with a metallic bafis, ferve lefs to produce folidity than to give flrength to the colour J for it is known that colouring D d 4 fubftances 4o8 THEARTOF fubflances vary their Ihadc according to the nature of the metallic earths by which they are attracted. The earth of alum poileffes this qua- lity for no other reafon perhaps than becaufe of its metallic nature. Tvv^o amongfl the neu- tral falts having a metallic bafis, unite with an aflringent quality that of an alterant, and are moft commonly ufed; thefe are 'copperas or vitriol of Mars, and blue vitriol or vitriol of copper j they feem to owe this to their aftringency. theory of dying fluffs prepared with alum, "Vk/V Macquer obferves \_Mem. de UAcad. des -*-^-*-* Sciences^ 1762] that as foon as the earth of alum is moiftened, it greedily imbibes all the oily, and confequently colouring, parti- cles of the bodies in conta6t. This property indicates, in this fpecies of earth, a ftrong difpofition to combine with the principle of inflammability and to retain it moft forcibly. The earth of alum therefore pofTefles the property of attrading the colouring particles. The caufe of this attraction we do not knows but fince the efFefl is certain let us confine ourfelve^ to that confideration, regardlefs of the caufe. Suffice it therefore, in our explanation of the theory of dyes wherein alum is ufed as ain aftringent, to explain the conditions neceflary to the attradlion of bodies. It is requifite, firft, that the power of attraflion be reciprocal in both bodies : fecondly, that they fhould be placed at a diftance from each other propor- tioned to their force of attraftion: thirdly, that 3 this DYING COTTON. 409 this force be fuperior to that with which one pf the bodies is attraded by the fluid in which it is fupended. It is therefore necelTary for dying of fluffs, that the dye fhould confift of corpufcules fuf- pended in a liquid, in {\ich a manner that they may be feparated by a fubflance which has 4 greater affinity, than the water, with thefe minute bodies. Earth of alum is this fubftance for the colouring particles in the good dye. There are colouring fubftances which the earth of alum does not attradV, but which have ftill lefs affinity with water than thofe requiring the aftringency of alum, fo that they enter the pores of the fluffs without its affiflancej but of this I fliall fpeak hereafter. Concerning the colouring particles of the good dye, and which require the Huffs to be alumed, thei^ particles fix to the earth of alum by the power of attradlion, and at the fame time the acid of the alum is fcftened by its combination with the principle^ of thefe particles, this acid having ferved merely as a vehicle for dillributing equally into all the pores of the fluff that earth which it held in a^ jl:ate of the greatell poffible divifibility. In my examination of various colouring fubftances I developed this theory, which I hope to demonflrate, and which I think preferable to the fyitems of my predeceffors en this fubjedt. Notwithftanding the deference diw to their opinion in every refped, I could never con- ceive that falts however hard, fuch as vitri^ olated or crude tartar, could maintain their liability in the pores of the fluffi however fmall 4-10 THE ART OF fmall the quantity foluble in water, it would be difficult to prevent wafhing from carrying off a great portion of the fait, and confequently of the colour, or to prevent it from being injured by the decompofition of thefe falts: whereas fixed earth, fuch as that of lime and alum, which from its nature obflinately re- taining the phlogiftic principles of all co- ours, muft neceffarily produce colours incapa- ble of being deftroyed but by the ftrongeft acids. Of colouring Jul fiances, NO one is ignorant at prefent that colours depend on phlogifton; that from its diffe- rent modification and various mixtures with oils, earths, and falts, and from the quality and quantity of thefe three principles, refults the diverfity of colours. It is alfo known that by the fimple addition of any fait to an oily, vege- table, colouring fubftance, you may change or totally expel its colour; becaufe any fait, fimple or compound, deftroying by the laws of affinity the combination then fubfifting, the rays of light are diff'erently reflefbed. Sub- fiances, the colour of which cannot be altered by any fait, are therefore moll probably thofe where phlogifton is in perfefl combination with the other principles. A perfcfl knowledge of this combination would doubtlefs guide us, by an analyfis of the colouring fubftances for the good dye, to artificial compofitions, in like manner as we make artificial cinnabar, for example, in confequence of our knowledge of the principles of DYING COTTON. 411 of native cinnabarj we fhoiild then have more hopes than we now have of bringing drugs, yielding the falfe tind, to be equally durable with thofe of the good dye. But though we know, even to a certainty, the effefbs produced by falts on certain oils; that we can deconnpofe fome colouring fubftances and feparate their principles, it remains to be known, in what manner thefe principles are combined, and con- fequently we are reduced to the neceffity of endeavouring to improve thofe given us by nature. Our want of knowledge in this parti- cular fiiould not be regretted, fince the drugs for the good dye are fisch only, becaufe they are incapable of decompofition, and that the end propofed in the fixing of colours, is an- fwered only by combining them with other principles, in fuch a manner as to render a de- compofition impofiible. The various colours exifting in vegetable and animal fubfrances, are fome of them vifible in the body by which they are furnifhed, and others concealed and manifeftcd only by the adlion of various falts. The manner of deve- loping thefe colours conftitutes a part of the art of dying; neverthelefs Dyers do not always take this trouble, whether becaufe the compo- fition be infufficient to make it worth while, or whether becaufe the fubftances furnilhing thefe colours are exoticks. The Dyers therefore buy all their colours developed; chiefly the blue drug called indigo, that extrafted from the Ricincides, known by the pame of Tournfbl i the red colour, produced by various 412 THEARTOF various fpecies of lychnis with which the archil pafle is made, &c. The number of thefc colouring fecula might doubtlefs be confide- rably augmented. We fhall mention by way of example the milky juice of the wild lettuce with prickly fides, and that of the fweet and thorny fow-thiftle, which with a lixivium gives a fire or carnation colour, very lively, but which foon degenerates into a fixed yellow. Secondly, the juice of wild Patience or Dragons blood, the crimfon colour of which turns to a blue that may be fixed. Thirdly, the common caterpiller of the white thorn, by means of a lixivium gives a purple colour. Fourthly, the amber colourtdi Jcolopandriumy gives an azure colour tolerably fixed. Fifthly, the purple ex- tracted in Sweden from the wild marjoram. Sixthly, feveral fpecies of lychnis's furnilh yellow colours, &c. &c. I mention thefe fub- ftances for thofe only who, having leifure and curiofity to make thefe experiments, may find the means of extracting their colours with ad- vantage. The arts can arrive at no perfeflioa but by adding new difcoveries to thofe that were made before us i Nunquam invemunlur, ft content i fiiermus invent is. Sen. Ep. 23* The concealed colours, which the Dyers are in the habit of extracting themfelves, are the blue colour of woad, that extracted from log- v/ood, the fimple infufion of which is a dark purple, the red colour of the root of madder, that of the flowers of baftard faffron, &c. Every colour necelTarily fuppofes a folid body of which it is a modification. For water whicl> makes DYING COTTON. 413 makes a principal part of the juices of roots, leaves, flowers, fruits of certain plants, of animal fluids, fuch as urine, blood, bile, &c. this water I fay, is in itfelf not fufceptible of any colour, only in as much as it holds in a ftate of emulfion the colouring particles, infi- nitely divided. Pliny tells us, that our ancient Gauls extra<5led from thefe juices the colours which the Romans fought for at the bottom of the fea, and in fad we find in this author the names of many plants which are no longer ufed in dying. A great number may alfo be found in botanical authors, ancient and modern. The perufal of thefe works excites the curiofity of thofe who are but little converfant in the principles of dying. Seduced by the beauty and brightnefs of the colours of thefe plants, they fancy they have made fome difcovery, and infert it in the peri- odical journals^ without refleding that thefe juices were difcontinued in confequence of better knowledge, when our anceftors, enlightened by their intercourfe with other nations, difcovered fubflances imparting more folid dyes. Pliny obferves with reafon, that the dye of thefe vegetables will not (land the wafhing [Tr^^«^/«i? Gallia Her bi Tyrium at que conchy Hum tingii omnefq-y^ alios color es— 'Jed culpa, non ahluiuju, PL L. 22, Se£f. 3.] Their juices are in fa6t nothing more than a liquid coloured with eflfential oils, and converted into a kind of foap either by an alkali Of a neutral fait. They are therefore incapable of giving more than the falfe dye, becaufe thefe foapy compofitions always retain their charade- riftick 414 THE ART OF rifteric of folubility in water j for their colour is foon loft by the effefl of the air, owing to the volatile principle of the eflential oil. If even my hypothefis on the nature of thefe juices be re- je£led, the volatility of their colours will effec- tually prohibit their ufe, fince neither alum nor any other matter can fix them. We muft not be furprifed at it; but on feeing thefe colouring juices, one would be apt to fay that the fluid itfelf was coloured, fo exceedingly minute are the colouring particles therein fuf- pcnded, and confequently fo great their affinity with it. This affinity being fuperior to the force with which the colouring particles and the earth of alum mutually change each other, the attrac- tion between them cannot take effccft. Thus we fee that the dyes extracted from thefe juices acquire no degree of {lability by previoufly aluming the fluffs; becaufe the earth of the alum remains colourlefs within the pores, together with the colouring particles ; but without uniting with them. Or, if even the alum were coloured, water would immmediately wafh off the colouring particles. I do not fay that there is no poflible method of rendering thefe drugs more permanent; for ex- ample, by introducing abforbent earths within the pores of the ftuff, or by adding acids to the colouring juices, which would decompofe the foap, and facilitate the union of the colouring particles with the earth. But it may happen that this decompofiton would entirely deftroy the colour or change it to another. Such experi- ments have been hitherto neglefted, in confe- quence DYING COTTON. 415 quence of the facility of extradling the fame colours from fubftances requiring lefs trouble; the uncertainty of fuccefs, and the little advan- tage that might refult from fuch experiments. Animals furnifli but few of the colourino' juices, and if they did, it is eafy to perceive by an examination of the bile and blood, that they would be no better than the vegetable juices juft mentioned. Since therefore neither vegetable juices nor animal fluids are capable of giving us permanent dyes, let us endeavour to obtain them from folid colouring fubftances — namely from thofe animals who are endued with colour, or from fuch par- ticles as had previoufly conftitutcd fome part of the texture of different plants. Thus with regard to ingredients for colouring, thofe ufed by the dyer are of the fame nature as thofe ufed by the Painter, differing only in the manner of operation, as it is fufficient for the painter, if the colourino- particles be depofited on the furface of his fubjedt j but with regard to the Dyer, they mufl be inclofed within the pores of his. They flill refemble each other in their attention to preferve their colours from the injuries of the air, though by different means. Painting has neverthelefs great advantage over Dying, which is deprived of many of the colour- ing fubftances ufed in the former, fuch as Ultramarine, Zafire, Cinnabar, the various fpecies of Ocre, and in general all the colours taken from the mineral kingdom. The colour- ing particles compofing thefe bodies, minute as they feem, are neverthelefs incapable of being attracted 4i6 THE A kT OF attracted by the earth of alum, becaufc they are naturally dry, and that alum attracts only undtu- ous matters; neitheh could they be ufed more fuc- cefsfully without aliimi becaufe though introduced within the pores of the fubject, they never would adhere on account of their drynefs, but would efcape with as much facility as they had en- tered i Vegetable and animal fubftances of the good dye, are fuch only, becaufe they are provided^ notwithftanding their deficcation,with a tenacious gluten, produced by a mucilage in the one, and by a glutinous matter in the other, combined with either a vegetable or animal oil. In the dying liquor, thefe principles forma gluten, which in proportion as they are attrafted by the alum, enter the pores of the fubje6l, giving the par- ticles the property of attaching themfelves ftrongly to the alum which had previoufly entered the fame pores, and forming together a real maftic. Now the earth of the aiurrl entering thefe pores was, as I have already faid, in the greateft degree of divifibility. The acid in the compofiiioii exerting its whole power on thd gelatinous oil, and the mucilage forms a cement, which is deftroyed -with difficulty iri proportion to the nature of the different colouring particles; the atoms of the alum, enlarged by this addition, cannot efcape fronri the pores, into which they had been introduced. This cement is, I fay, with difficulty deftroyed, according to the nature of the different particles, becaufe on the different principles of which thofe are compofed,- depends the degree of their (lability, and chiefly on DYING COTTON. 417 ort the quantity and quality of the oil which they contain. The difference occafioned by this neceffarily makes a difference in the nature of the cement, which, as it is more or lefs flrong, refills in a greater or Icfs degree the aftion of the fun. Of Cochineal and other Colouring InJeEis^ COCHINEAL is an infed found in Mexico, on a fpecies of the fig-tree, called Opuntia, It is alfo found on many others, and I have obferved it particularly on a tree called Ambrofia Peruviana, which is cultivated in the king's gar- dens. But this yields only a reddifh colour, we may therefore conclude that the fcarlet of the cochineal is owing to the juice of the Opuntia upon which the infeft feeds, and whofe-. prin- ciples combining with thofc of the animal, con- ftitute together but one and the fame fubftance. Animals being compofcd of oil, earth, and vola- tile alkali, the fame principles are alfo extrafted from the cochineal. \^I have my/elf extrafled a pretty confiderahle quantity of oil from the cochineal , and flilt more from the kermes. Should any one doubt concerning my operation, he need only apply to M, M. Geoffry and Margraaff. See Mem. of the Acad. ofSciences'\ It is therefore eafy to conceive why its colour is of the befl dye, the fluffs being previoufly alumed. The volatile alkali of the cochineal, renders the colour bright; the animal oil united to the folid and mucilaginous particles of the infe<5t, produce the firft ingredients of a maftic, which, being com- pleated by the alum, prefervcs the colour from the influence of the air or fun. Hence the E c permanency 4rS THE ART OF permanenq^ of this colour, which, with regard to the crimfon extrafted from cochineal, is undoubted, becaufe it is the natural colour of the infcjfl J the greater therefore the deviation from this l^ade. by alterants, the more it lofes of its fixity. As the colour depends onth« fhape or figure of the confhituent particles of the colouring bodies, the fliade may be varied by changing their figure, but theperminancy of the colour is at the fame time diminiflied, becaufe it is impoflible ta produce this change without altering the principles to which they owe their permanency j this is the cafe with the cochineal. Acids and alkalies eafily vary the fliades of its colour, Thefe fhades are faddened by volatile alkalies more than by any other, but thefe are feldom ufed on account of their price. Fixed alkalies alfo fadden, inclining them topurplein proportion to the quantity ufed. Thefe falts produce tliis efFe6^, becaufe they are the natural folvents of animal iubftances; which however they are inca- pable of difiblving without combin-ation caufing only a decompofition without the diffipa- t ion of any principle. This combination gives to the colouring particles a degree of denfity, which they had not, incling them to black, oc- eafioned by a- greater refradion of the rays o£- light. Acids on the contrary, and efpecially mineral acid, burn the oil, and abforb the phlo- gifton, which is the principle of colours : by the violence of their adbion, a part of the phlogiftoa. and volatile alkali, evaporates j the colouring; matter becomes more rarified, and refleding a. greater DYING COTTON. 419 greater number of the rays of light, it necelTa- rily acquires a colour nearly yellow, and even ?f more be added quite yellow, which is of all colours the neareft to white or tranfparency. It is not therefore the cuflom to ufe fixed alkali in the cochineal liquor when dying with this fubftance. It would make too great an alteration in its confiftence, and, by mixing with the animal oil, form a foap that would fender the colour mifcible in water, confequently of the falfe tint j becaufe, not then capable of forming a maftic, the oil, occupied by the alkali, being no longer at liberty to combine with the earth of alum j it may however be ufed with advantage, arid without danger after the ftuffs ai'e dyed, becaufe then the maftick being already formed, this menftruum has not fufficicnt power to deftroy it, unlefs by putting too large a ijukntity. The aflion of acids is more deflruftive than that of the alkalies j vitriolic acid, v/hen for- rtierlyufed in the cochinealliquor, laddened rather than brightened; becaufe the common oil of vitriol, which is feldom free from fome particles of iron, formed in the liquor a kind of Prufliari blue, which, mixing with the red particles com- municated a purple tinge. [^Cochineal hoiled with Kxiater in an iron vejfelj 'will have a purple tinge. "^ Spirit of nitre has been fince ufed, but the the aftion of this acid on oils and phlogillon being much ftronger than the firft, it was judged proper to give it a bafis on which it might in fart exhauft itfelf, and by communicating part E e 2 of 420 THEARTOF of its phlogifton, render it lefs greedy of the cochineal. This bafis is tin: it was formerly diflblved by fpirit of nitre, but fince by aqua-regia, which was found to diflblve it more completely. This folution is not ufed in the fame manner as that of alum, by diluting in water and then dipping the fluffs previous to their being dyed. This preparation would not be fufficient, for by diluting in a great quantity of water, a part of the calx of tin would precipitate and be reduced to atoms larger than when difTolved in acids, efpecially if ufed alone and feparate from the dycj the acid in that cafe not adling on the colour fufficiently to enliven it: Only part of this folution therefore is added to the cochineal liquor, and the acid then aban- doning the tin and combining with the oil of the cochineal, the calx of the metal feizes the colouring particles whilfl precipitating, and together, as M. Helot obferves, forms a kind of lacker which infinuates into the pores of the iluff, and is there retained by a gluten given by the ftarch which was added to the dying liquor. From this explication it is cafy to com- prehend why the fcarlet dye is much lefs folid than the crimfon. The lacker being much dryer than the fimple colouring particles of the cochineal, is, in this ftate, nearer to the nature of the mineral colours. The oil and the ani- mal gluten, which in the crimfon dye form with the earth of alum a maflic, are deflroyed by the acid, and the flarch then added is an infufficient fubftitute. What DYING COTTON. 421 What I have here faid of the caufe of the fixity of cochineal after the ftufFs have been prcvioufly alumed, applies equally to gum- lac and kermes, the conftituent parts of which are found by analyfis to be the fame. The kermes has even the advantage of being corn- pofed of ftill finer particles, which more eafily penetrate the pores of the fluff, as I have ex- perienced in filk and cotton. It is well known that filk, on account of the fmallnefs of its pores, takes up only a part of the cochineal, but from the kermes it extracts the whole of the colouring particles, which is alfo more fixed, probably becaufe the fhrub on which the infedt is nourilhed communicates its aftringency or that it contains a greater quantity of oil. Cot- ton, into the pores of which cochineal cannot penetrate, may be dyed with kermes. It is to be lamented that the ufe of kermes is abolifhed. It is fuppofed to be fcarce, becaufe it is ufcd only in medicine; it is dearer than it ought to be owing to the fmall quantity col- lefled. But if it were again brought into gene- ral ufe for dying, the price would be conliderably reduced, as the Ihrub on which it feeds requires no cultivation. Other infeds were formerly ufcd in dying, but thefe it is unnecefTary to enumerate, as their principles are probably the fame; they are no longer in ufe. About two years ago, in the Gazette de France was announced, a fccret which confided in extracting a red colour from a fpecies of bug. This pretended difcovery re- minds me of an obfervation of Lifter's, commu- E c 3 nicated 422 7 If E Ail T OF nicated about one hundred years ago to the Royal Society of London, concerning a red colour that might be obtained from a red infeJG. COTTON. 1223 tdecifive experiments. But how can we prefLime to hope this, whilft we Iiave the cochineal im- ported to us from foreign countries and at a great cxpence, notwithftanding that its dye » lefs permanent than our kermes. Man, naxu- rally idle, fleeps in the midft of enjoyment, and is waked only by the calls of neccffity. When, therefore, at fome revolution, we fhall be prohibited from the wfe of cochineal, or when it becomes dear, we fliall then have re- courfe to the eggs of M. Reaumur, or the henbane bugs, -or rather rcfume the ufe of the kermes, of th« dye of which we are fo well aflured, though too lightly abandoned. The invifible hand of Providence, who preferved the madder in our hedges, which we had ceafed to cultivate will preferve for our ufe, the Ikx aculeata and the infed it nourilhes. Of Maddin ^T^HERE are feveral fpecies -of madder; that ■*- brought from Zealand, called in Latin Ruhia Un^orum^ is the moft in ufe. The Romans, according to Pliny, called it Erj'throdamus, which proves that it was known to give a red colour, and was much ufed by the Greeks. It was ufed in his time for dying wooll and flcins. The Italian madder was the moft eftecmed, par- ticularly that grown in the environs of Rome, and in great quantities in all the provinces of the Roman empire. They diftinguilhed two forts, one wild and the ether cultivated; the iaft was fown in the fame manner as peas. It E e 4 vvas ^44 THEARTOF was afterwards called Verantia or Varantia, pro- bably on account of the permanency of its colour, whence originated the word Garance. The ufe of this plant, as we perceive, was very ancient in Italy, fince Pliny lived in the firft century, and it is highly probable that it was equally known in Gaul, which was then under the dominion of the Romans. It is therefore contrary to all reafon, that the author of the Nouvelijie Economique ^ Literaire printed at the Hague, fays that it is fome centuries ago fince it was brought from the Indies into Perfia, from that country to Venice, and from thence by the way of France and Spain, into the united Pro- vinces. It would be difficult to determine whether the fpecies mentioned by Pliny, be the fame which we call Ruhia I'm^orum, efpecially as there are many kinds, and that the roots of feveral Ijpecies of Gallium and in general of all the Rubi- acisc yield a red dye ; the only difference is as they yield more or lefs. Diofcorides, when fpeaking of this plant, gives the preference to that of Ravenna, and fays that it was fown in the field amongft the olives. If this be the plant defcribed by Ray \_Rubia Sylvejiari fifperay Ravennencis Zannoni] after*- Zannoni, it appears to be a different genus from any we know, The root of this plant is flender, and about eighteen inches long, its rind is thick, and adhering to the interior part. It fhoots feveral ftraight ftalks, firm, round at the begin- ning, and of a dark colour, which foon take a fquare form and green colour, a little higher at the place where the ieaves are produced j thefe ftalk? DYING COTTON. 425 ftalks are hollow, furrowed, and from fpace to fpace, furnifhed with knots round which grow the leaves, difpofed in whirls to the number of four, five or fix, an inch long, and two lines broad. Leaves are fmooth at firft, but afterwards become a little downy. Pedicles of the leaves brittle, and red- difli underneath. Flowers compofed of a green calix, with five leaves, and a corolla having five petals of the fame colour. Stamina yellow j root much fpreading, fibres capillary of a dark red colour j thefe fibres throw out yellow and tranf- parent (hoots, producing new plants. It is found near Ravenna in the foreft of Pines. This plant evidently differs from all our known madders. Some years ago I wrote to M. Ginanni, a patri- cian of Ravenna to procure me fome of the feed, withdefign to cultivate it in this country. I hoped that he would have obliged me as he was a member of the fociety of Agriculture at Paris j but I received no anfwer. There is another fpecies of madder, different from our RubiaceaSj but common in the Ifle of Candia. Its flowers are in form of a fpike. Bota- nifts have therefore called it Ruhia Spicata. In the Indies they make ufe of various kinds of Rubiaceas, in dying thread or cotton — fuch as the chat de Perfe, the Morinda, the Hedyotisy the Rojocj the Chaive. We have imported the roots of this laft, which has great fimilitude to our Synanchine or to the Gallium flore albo. The Eaft-India company, fome years ago, imported a root which they c2\\t^MongiJlery of the fizeof aquill, equal throughout its length, about fix feet or longer, in other refpedts refembling madder 42b THt ART OF madder j they faid it came from the Weft-Indies. The root of the Gallium hitemny obfervcd by M, Guettard on the coaft of Poictou, exactly re- fembled it in form, length and breadth, fo that it is moft probable the Mongijler is a root of the fame plant. The blue flowered Gallium ^ and the madder of the Alps, known by the name of Ruhia l^jis ^aurinenfium gave the moll beautiful red to M. TAbbe' Mazeas, in his experiments on the dying of cotton. The common madder cer- tainly yields a greater abundance of colour; but in many manufadories they prefer quality to quantity, the difference however would be of little confequence to the cultivator of any one of thofe plants. It were therefore to be wiihed that we did not, as at prefent, confine ourfelves to the culture of the Dutch and Levant m.adder only. The latter yields a different fhade from that ufed in the Indies, which is rather more crimfon. By cultivating various fpecies of Rubiacea, we might hope to procure a diverfity of fhades: befides the foil, though inimical to one, may agree with another. The root of the befl madder has a lively colour, and when powdered and put on blue paper inftantly adheres. Madder when powderecj Should be pafty and unfluous, like that which is imported from Smyrna, Tripoli, and Cyprus, &c. differing only in confequence of fome diffe-r rence in the foil. The Cyprus madder has the moft aromatic fmell, and feels refinous. Its colour is more fixed, darker, but lefs pleafing than that of the others. Madder when ground generally DYING COTTON, 427 g€in€rally lofes its uiiftuofity in drying, and there- ^re the bed is only good for a year, after which it begins to decline. The madder root feems to contain two parts mixed together, though of a different xiatuf-e i the one fubtle and penetrating, fuppofed l)y Hoffman to be of a faline fulphurous nature, ^nd the other earthy and aftringent. Thefe two parts are not intimately combined, in confe- quence of which, like the conftituent parts of jhubarb, they ad feparately. It feems not there- fore accurate to fay, that the colouring principle of the madder is merely of a foapy extractive pature. The faline fulphurous pare is indeed, by nature, foluble in water, and there retains the red particles in a flate of emullion j thefe two parts are however very diftind, and are united only as aggregates. This their effed; in dyingfuf- ^ciently evinces : a fawn colour may be dyed by the epidermis and the heart of the root, which contain the greatell quantity of faline matters on the other hand, the parenchyma alone gives a beautiful red colourj but it is neceffary, in order to render it ftill more pure to deftroy the fawn tinge by which the red is Aillied and from which even the parenchyma is pot exempt. Some experiments which I made on this root confirm this opinion. I took fpme of the roots of the madder gathered in the environs of Paris; I dried it in the Ihade and reduced it to powder. A quarter of a pound of this powder I put into a glafs bowl, adding half a ounce of fait of tartar, di/Tolvcd 'm twelve gunces of river water. I \^h the whole infufing 4*8 THE ART OF infufing for three days, frequently ftirring with a flick to facilitate the extrafkion of the colour. I then philtered the red liquor ; I poured it into another bowl, adding water, foured with leven, in a fmall quantity. I covered the liquor, but in fuch a manner as to have a little communica- tion with the external air. The fermentation took place by degrees, and at the end of fix days the liquor which was fawn colour, became tolera- rably clear; a dark red fcdiment remained at the bottom, but very beautiful, having the con- fiftance of a thick balfam. Attempting to wafh it, I perceiveed that it was much inclined to re-diflbve in water, doubtlefs occafioned by a fait with which it remained united. I was then de- termined to pour off by inclination as much of the water as I could. The refiduum which I dried, became of a red brown and of a very hard confidence, fo that when I wanted to ufe it, it was infoluble even in boiling water. I there- fore concluded that the red particles of the madder root were of a rcfinous or bituminous nature. To determine which, I took fome frefh roots reduced to powder, pouring on it fome fpirit of wine as high as my two fingers, carefully ftirring the fubftance feveral times during the day. The next day I decanted the red liquor, pouring on it fome frefti fpirit of wine, and ftirring as at firft. I continued to decant and to re-add frefh fpirit, till it was no longer coloured. I then mixed all the coloured liquors together, in order to diftill them per Balneum Man it is then carefully wafhed at the river to diveft it intirely of the oil, without which the aluming. would not take effeft; having been wafhed, it fliould be as white as if it had been bleached. When dry, you proceed in the aluming, which is done twice fuccelTively, but it is needlefs to give a detail of what has been fufficiently ex- plained in the article upon madder red. It is enough in this place^ to fay, that the galls, about a quarter of a pound to every pound of cotton, fhould be pulverized j that fix ounces of alum fhouid be put to the firft aluming ; for the fecond four ounces, and at laft, that an equal quantity of the lixivium be added to the alum water. We muft alfo qbferve, that it were befl to make an interval of three or four days between each aluming, and that no other aftringent be added, all metallic falts being in general injurious to the beauty of the colour* Some days after the laft aluming, you proceed to dying, in the fame manner as above, on- ly ufing two pounds of lizary in powder, for H h eveiy 466 THE ART OF every pound of cotton, and before you dye, adding to the liquor about twenty pounds of liquid fheeps blood: it ftiould be well ftruck into the liquor, which Ihould be carefully fkim- med. In order to brighten the colour, the cotton is dipped in a lixiviunn of frefli wood alhes, dif- folving in it five pounds of the bed white Mar- feilles foap, the water fhould be v/arm before the foap is put into it. In this mixture the hundred pounds of dyed cotton is immerfed, and worked till it becomes perfedlly penetrated. Six hundred quarts of water are then put into another copper, and when warm, the cotton without fqueezing it out of the firft, is put into the fecond, and boiled for three, four, five, or fix hours, over a very flow fire, but as equal as poITible, carefully covering the liquor to keep in the vapour, that none may efcape but what pafles through a funnel of fmall reeds. Some pieces of the cotton are taken out from time to time, and when fufficiently revived and wafhed thoroughly, the red is perfe6l. The Cotton may be alfo brightned in the follow- ing manner: when wafhed and dryed imme- diately after dying it fhould be foaked in the Sickiou. for an hour, well fqueezed and alfo dried. "When dry, you difTolve for every hundred pounds of cotton, five pounds of foap in a quantity of water fulficient to cover the cotton. When the water is warm, the cotton is immerfed, and having well imbibed, is put into a copper with fix hundred quarts of water j the whole is boiled very flowly during four or five hours, keeping the DYING COTTON. 467 the copper covered to prevent the (leam from going off. This fecond method makes the red much brighter than the fined Adrianople car- nation. Ohfervations on this Dye. ^npHE procefs I have jufl: defcribed was prao- -■• tifed at Darnetal, and in other manu- fadlories of France, according to inftruc- tions communicated by a perfon who had ^cqi\ this procefs in Turkey. But whether his obfervations were inaccurate, whether he con- cealed a part of the myftery, or whether the fuccefs of the operation depended on the con- curring circumllanccs, accompanying the va- rious mixtures, I know not. Few however by clofely obferving this procefs, have hitherto obtained a red, either fo permanent or fo beau- tiful as the red of Adrianople, and thofe v/ho have fucceeded think it but juil to reap the ad- vantage of their fecret. On this fubjed, how- ever, feveral not unufeful reflexions may be advanced. ^ Firjl, The manner of purging the cotton in- dicates that this procefs is capable of damaging confiderably, and of rendering the cotton very brittle, owing to the Iharpnefs of the lixivium, in which it is deeped i fo burning in its nature as to make holes in the legs of the work- men who tread it with their feet. It is therefore more fimple and lefs dangerous to cleanfc the cotton in fix quarts of lixivium to every pound of fubftance, and containing only fix ounces of kelp for every fix quarts; to boil the flceins in H h 2 it 4&8 THL ART OF it afterwards, inclofed in clean linen pockets, as I have already faid on the article of cleanfing. By this method the cotton would be fufficiently cleanfed without being fpoiled, the kelp may be even reduced to half the quantity, fubftituting in its place double its weight of frefh wood afhes, which would anfwer quite as well. Secondly, That the failure of many Dyers is owing to their not fufficiently diverting the cotton of the oil, which prevents both the galling and aluming from taking effedl. The mixture of the lixivium and oil not being well made, or the lixivium being too weak, the oil forms ■with it but an imperfe6l: combination. This oil therefore, feparating and fwimming on the furface of the lixivium, flicks to the cotton, which it greafes, and, by obftru6ling the pores, prevents the gall from penetrating. Great attention therefore fhould be given to the lixi- vium, in order to extradt all the fait of the kelp, and to ufe quick lime, which is abfolutely necef- fary to render this lixivium coftic, a quality without which the oil cannot poffibly form a combination with the alkali, confequently can make no foap. In Europe the oil of olives is fubHituted inllead of the oil of Sefamunij which is ufed in the Eaft- Indies and in Turkey, but the nature of thefe oils makes no difference in the operation. The oil of Sejamum differs from the oil of olives, only becaufe it is thicker, confequently nearer to the nature of animal fat or wax ; but the con- cKifion refulting from this difference is, that lefs of it may be required than of the oil of olives. 4 Were DYING COTTON. 469 Were the oil of Sefamum abfolutely neceflary, it might have been eafily procured. The Sefa- wum is a fpecies of Fox-glove, that grows in the Indies, but is cultivated in Italy, and efpe- cially in Sicily, v^'here it is called Giurgulena, The fame kind of oil may be obtained from plants analogous, fuch as the GraUole^ the Henbane, &c. but the plant whofc feed refembles it mod is the Convulvulus, or Lizeron. It is certain that the procefs brought from Adrianople might be greatly abridged] but we muft leave the fecret to thofe to whom it belongs, and I am befides convinced that a memoir on this fubjedl will be prcfcnted to the Academy of Sciences, and therefore will not anticipate. With regard to the fheep's dung and intefti- nal liquor, it is of no ufe in fixing the colour. But we know that thefe fubftances contain a large quantity of volatile alkali, quite deve- loped, which has the property of rofing the red colours. If the bones of animals owe to their tenacious gluten the faculty of retaining fo ftrongly the madder colour, the vivacity of this colour may be attributed, as from expe- rience we learn, to their volatile alkali. It were abfurd to imagine that the Europeans only had difcovered this phenomenon, as it may be rationally fuppofed that the Indians, having per- ceived it by accident, fought to imitate what chance had brought to their knowledge. It is certain that in the red dye of the MaroqutrtS, the procefs of which was brought from the Levant, they prepared the goat fkins for dying H h 3 with 470 THEARTOF with dogs' excrement, having found it cffcdlive in exalting the dye of the lac. In the dying of cotton thread, it is common to mix the fheep's dung with a lixivium of "fixed alkali, by which the volatile principle of the dung is retained, and confequently putrefa6lion prevented. By dipping the cotton feveral times in this foapy liquor it is impregnated with the predominating alkaline principle, and we know, by experience, that fubflances, once impreg- nated with volatile alkali, for example chymical veflels iifed in extradting it, for a long time retain a fmell very like the fmell of mufk, evea after having been well fcrubbed with fand, afhes, foap, &c. Every time the cotton is dried when taken out of this liquor, the evaporation of the aqueous particles (the alkaline principles being changed into earth) produces a ftronger adhefion in the pores of the cotton. From the union of this earth with a portion of the oil employed, a maflic is the refult, which is afterwards com- pleted by the alum, and this in a word is the theory of the fixity of this colour. Linen thread may be dyed in the fame man- ner, only that previous to its being purged like the cotton thread, it is ufual to boil it in water, adding for every pound of thread a quarter of a pound of chopped forrel : oil of vitriol is however more convenient and better than forrel ; but I refer my reader to what I have already faid upon the article of thread, obferving only that by this procefs, the linen thread always takes lefs dye than the cotton, owing to the difff^rence of their pores. Of DYING COTTON. 471 Of Yellow. T?OR this colour the cotton fhould be firft ^ well purged in a lixivium of frefh wood afhes, and afterwards well wafhed and dried. You then prepare another liquor, made by diflblving in the water, when ready to boil, about a quarter the weight of the fubflance to be dyed, of Roman alum. The fkeins are plunged into this alum liquor, returning them on the rods for fome minutes. When equally penetrated throughout, the threads by which the flceins are tied being pafled on the rods, the hanks are laid on the trough containing the alum liquor. The copper or trough is then covered, it being fufficient to keep the liquor hot without boiling. The cotton, having been thus infufed for twenty-four hours, is then dried, but without wafliing. We mufi: obferve that the longer it remains dry the better it takes the colour, and that the wafliing may be even dif- penfed with previous to the yellow dye.. A ftrong v/eld liquor is afterwards prepared, adding for every pound of the fubflance to be dyed a pound and a quarter of weld. The cotton or thread, having been previoufly alumed, is then immerfed; the boiling checked with cold water, and the fubftance worked till ic has taken the fliade required. The whole when died is plunged into a very hot liquor, but not boiling, made of blue vitriol, a quarter of a pound for every pound of the fubftance. When it has remained for about an hour and half, the whole, without wafliing, H h 4 ^ is 47« THEARTOF is thrown into another liquor, compofed of about a quarter of a pound of white foap for every pound of the fubftance. Having been well worked and the threads opened, it fhould boil for three hours, or more if you think pro- per. The foap might be dicoinifhed to half the quantity, but the full proportion does better. This operation finifhed, the whole is well wafhed and dried. If you defire a dark or jonquil yellow, neither the linen nor cotton fliould be alumed j but, for every pound of thread, fliould be added two pounds and a half of weld. When it has been dipped and well worked in this liquor till it has taken the colour equally, it is raifed above the liquor, and half a pint of the kelp lixivium poured into it, made as I have direded in the article upon red. The thread is then returned upon the rods, dipped in this liquor, where having remained for a full quarter of an hour it is taken out, wrung, and dried. The lemon yellow is done after the fame man- ner, only that for every pound of thread you put but one pound of weld, diminifhing the verdigris in proportion, or even omitting it entirely by fubftituting in its place the alum liquor. By this means the yellow (hade may be varied ad infinitum J and without any difficulty s in brighten- ing and fixing the colour, however, the above method mud be always obferved. This method of fixing the colour of the weld, fo accidentally difcovered, is a ftriking example of the ancient operation which they termed coloxis alle^atio. It were to be wilhed, in order to DYING COTTON. 473 to extend the tifc of it to other colours, that it were poflible to difcover why calx of iron and copper has this property. It feems to proceed from the fame caufe which makes both thefe metals foluble in fixed alkali, differing in this particular from all other metals. Mr. Geoffroy luppofed a bituminous matter to exift in iron, which is very probable, as alio in copper. It is very certain that you give fixed alkali the property of diflblving other metals by phlogif- ticating with bullock's blood : does this proceed from phlogifton or from the animal oil, and a certain tenacious gluten which it is extremely difficult to feparate from the Pruffian blue, and different from phlogifton ? Cotton velvet is dyed with the root of a plant called cur cum y or Terra-merita, a fpecies of rufh which comes from the Eaft-Indies. It gives a beautiful yellow colour j but if died in the common manner has but little folidity. I know by experience that this colour may be fixed by dipping the linen or cotton thread in a folution of fulphur of antimony in the lixivium of fixed alkali : it will then perfeflly rcfifb the air, and cotton velvet thus dyed is very pleafing to the eye. Of Green. T I NEN or cotton thread to be dyed green, after having been previoufly cleanfed, Ihould be dyed in the blue vat according to the Ihade required j it fhould then be well rinced in water and dried. It is impoffible to give any pofitive rules concerning the ground of the blue or of the 474 THE ART OF the yellow, as that depends more or lefs on the colour you wifh to predominate, or on the ground for the mixture required. Cuftom and the eye mull be the Dyer/s guide in this par- ticular. Cotton velvets are feldom dyed with weld. To dye green they are yellowed with Terra' merita^ and afterwards greened with a compo- fition of the Saxon blue; nor is it of any con- fcquence whether you begin with the blue or the yellow. Cotton velvets, as well as the Ikeins, may be dyed green in a fingle liquor and by a very limple procefs; but which will produce only green water or apple green. Difiblve two ounces of verdigris in a very fmall quantity of vinegar, then add about half a pint of vinegar, pour the whole into a bottle, cork it well and keep it in a ftove for a fortnight. Four hours before it is ufed, you boil two ounces of pearl-afhes in a quart of water till reduced to half that quantity. Draw it off clear, add- ing it to the verdigris and vinegar mixture, keeping the whole hot. Prepare the thread by dipping it in an alum liquor, about an ounce of alum and five quarts of water for every pound of the fubftance. Moiften it in this liquor as hot as you can bear it to your hand. The thread or velvet is then raifed, the verdi- gris added to the liquor, and the fubftance again dipped and dyed. Of DYING COTTON. 475 Of Violet. 'T^HE moft common method of dying thread •^ and cotton violet is, immediately to give them a blue ground, in a vat proportioned to the fhade required, and then drying. They are afterwards galled in a liquor containing, for every pound of the fubftancc, three ounce-s of galls; they remain twelve or fifteen hours in this gall liquor, when they are taken out, wrung, and again dried. Mean while a logwood liquor is prepared, by boiling for three or four hours, in fifteen or fixteen quarts of water, about half a pound of logwood for every pound of the fubftance. The half of this liquor is afterwards poured into a trough, and the cotton dipped in it till it has equally imbibed the colour, when it is taken out, and for every pound of cotton or thread two drachms of alum and one of verdigris diflblved is added to the liquor. The fkeins are again dipped on the rods, and returned during a full quarter of an hour; they are then taken out, cooled, and again entirely immerfed for another quarter of an hour, when they are taken out and wrung. This dying liquor is at laft emptied out of the trough, and the other half of the logwood liquor poured into it, with the addition of two drachms of alum; the thread is again dipped till it has taken the Hiade required. This fecond logwood liquor, as well as the firft, may be more or lefs ftrong in proportion to the fliade required, in fuch a manner that, if very deep, you double the quantity of the 3 logwood 476 THE ART OF logwood for the fecond liquor onlyj but as one boiling does not extra6t the logwood dye, you may after the firfl dye, by way of oeconomy, pour frefh water on the remainder of the log- wood. It fliould be again boiled, and the weakeft of it may beufed for the firfl: dipping. This violet refifts the air tolerably well, but neverthelefs cannot be deemed of the good dye. Very permanent violets are produced by com- bining the madder dye with aftringents: this has the advantage of being neither tedious nor expenfivej it requires only that the thread fhcruld be impregnated, previous to its being maddered, with an afl:ringent : as the bafis of this aftrin- gent is the fame commonly ufed for black and its various fhades, it may be necefiary in this place to give the compofition. Take a hundred quarts of four wine, bad vinegar, or fmall beer; put to either of thefe liquors twenty, or five-and-twenty pounds of old iron, having expofed it for two nights to the dew. Wet with fome of this beer about twelve pounds of rye-meal, or coarfe bran^ put this mixture into the vefTel containing the hundred quarts of beer ; pour a part of this liquor into a copper, heating it enough to warm the whole when mixed together. Let it afterwards Hand for fix weeks or two months, or more, becaufe the older this compofition the better it is. The veflel fhould be covered with a cloth, and a plank over it, to preferve it from dufl: and infeflsi taking care only to let in air enough to encourage the neceffary fermentation. Cotton D Y I N G C O T T O N. 477 Cotton or thread to be dyed violet, is cleanfed as ufual, preparing at the fame time an aftringent liquor, compofed of, for every pound of the fubftance, two quarts of this black liquor, and four quarts of water put into a boiler over the fire, boiling and fkumming it for half an hour till no more fkum rifes, when it is taken off the fire, poured into a trough, and whilfl no more than warm, four ounces of blue vitriol and one of faltpctre, is diffolved in a part of this liquor. The fkeins are returned in this aftringent either warm or cold, where they are fuffered to remain for ten or twelve hours, and then wrung and dried. When ready for maddering they are well waflied in running water, carefully drained, and then dipped in a liquor of Dutch madder, contain- ing for every pound of the fubftance one pound of madder. By this aftringent it is eafy to procure all the violet ftiades, from the panfy flower up to the lilac and gray violet; but experience is better than rules. If a dark violet be required, it is done by adding to this aftringent two ounces of verdi- gris; or if ftill deeper, by galling the thread more or Icfs, previous to its being dipped, and by omitting the faltpetre. By augmenting the quantity of the latter, and diminifliing that of the blue vitriol, the violet will have more of the lilac, and by adding a little of the red aftrin- gent, more or lefs of the red. In Ihort, diffe- rent quantities of the black liquor and water, and different degrees of galling, will produce fhades without number, and even different browns. 0/ 4 OR The PHILOSOPHICAL COMMERCE OF ARTS. 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